Production & Packing Details

• Manufacturing capacity: 60,000 cans / day

• Cans Per Carton: 12 Pcs

• Cartons Per Pallet: 96 Cartons

• Dimensions: 1200mm x 1000mm (pallet)

Shelf Life: 2 Years

Available in: 400ml/13.53 Oz

(Net Content)
 Page 1/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: MR® 76 S “The
D-Shield Magnetic powder
Ultimate suspension,
Disinfecting Spray”black
valid for all versions
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
· Sector of Use
SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
· Product category
PC14 Metal surface treatment products, including galvanic and electroplating products
· Process category
PROC7 Industrial spraying
PROC8a Transfer of substance or preparation (charging/discharging) from/to vessels/large
containers at non-dedicated facilities
PROC13 Treatment of articles by dipping and pouring
· Environmental release category ERC3 Formulation in materials
· Article category AC7 Metal articles
· Application of the substance / the mixture
Testing material
“The Ultimate for nondestructive
Disinfecting surface
Spray” for crack bacteria,
disinfecting detectionvirus & fungus
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Hersteller:
MR® Chemie GmbH
3AK Chemie Pvt. Ltd.
Nordstr. 61-63
Survey No: 148, 5/B5/1, TSIIC Automotive Park
59427 Unna (Germany)
Kallakal - 502 336, Telangana, India
Tel. +49 (0)2303 95151 0
[email protected]
Fax: +49 (0)2303 95151 10
www.3akchemie.com
[email protected]
+91 97017 00017
www.mr-chemie.de
· Further information obtainable from:
3AK
MR®Chemie
ChemiePvt. Ltd., Tel.:
GmbH, [email protected], +91
0049-(0)2303/95151-0, 97017 00017
[email protected]
· 1.4 Emergency telephone number:
24h- Emergency Contact Phone Number
For Chemical Emergency, Spill, Leak, Fire, Exposure or Accident

Call Day or Night within USA and Canada: 1 800 424 9300
Outside USA and Canada: 001 703 527 3887
In-Country Emergency Number for:

Germany: 0800-181-7059
China: 4001 204937 (Mandarin)
Hong Kong: 800 968 793 (Cantonese)
India: 000 800 100 7141 (Hindi)
South Africa: 0 800 983 611 (English)

(WISAG FMO Cargo Service GmbH & CO.KG)

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.

(Contd. on page 2)
GB

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 Page 2/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 1)

Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.

· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS02

· Signal word Danger

· Hazard-determining components of labelling:
Distillates (petroleum), hydrotreated light
· Hazard statements
H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
· Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P251 Do not pierce or burn, even after use.
P211 Do not spray on an open flame or other ignition source.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
· Additional information:
EUH066 Repeated exposure may cause skin dryness or cracking.
Buildup of explosive mixtures possible without sufficient ventilation.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
EINECS: 265-149-8 Distillates
CAS: 64-17-5 (petroleum), hydrotreated light
Ethyl Alcohol Asp. Tox. 1, H304 50-70%
60-80%
CAS: 74-98-6 propane, butane Flam. Gas 1, H220 10-25%
EINECS:
CAS: 200-827-9
106-97-8 Press. Gas C, H280
CAS: 106-97-8 butane of Disinfectants
Mixture Flam. Gas 1, H220 10-25%
CAS: Proprietory
EINECS: 203-448-7 1-3%
Press. Gas C, H280
· Propellant: Propane-Butane
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation:
Take affected persons into fresh air and keep quiet.
Seek medical treatment in case of complaints.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
(Contd. on page 3)
GB

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 2)
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
Not relevant - aerosol can.
· 4.2 Most important symptoms and effects, both acute and delayed
Headache
Disziness
Unconsciousness
Nausea
Disturbances of the central nervous system
· Information for doctor: With aspiration danger of the pulmonary edema and/or pneumonia.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture
Steams are heavier than air and spread at the soil.
Swims up and can catch fire again.
Carbon dioxide CO2
In case of fire, the following can be released:
Carbon monoxide (CO)
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.
· Additional information Cool endangered receptacles with water spray.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Keep away from ignition sources.
Avoid contact with eyes and skin.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling No special precautions are necessary if used correctly.
· Information about fire - and explosion protection:
Do not spray onto a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C,
e.g. electric lights. Do not pierce or burn, even after use.
(Contd. on page 4)
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 Page 4/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 3)

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurised containers.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Protect from heat and direct sunlight.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
74-98-6 propane
AGW (Germany) Long-term value: 1800 mg/m³, 1000 ppm
4(II);DFG
106-97-8 butane
WEL (Great Britain) Short-term value: 1810 mg/m³, 750 ppm
Long-term value: 1450 mg/m³, 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
AGW (Germany) Long-term value: 2400 mg/m³, 1000 ppm
4(II);DFG
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
· Respiratory protection:
Filter A
For good ventilation provide, this can be achieved by local or space exhaust. If the concentration
lies over the job limit values, then, a certified respirator suitable for this purpose must be used.
· Protection of hands:
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
Fluorocarbon rubber (Viton)
Nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
Supplier for suitable protection gloves:
ASD ArbeitsSicherheit Dortmund
Torstr. 101 - 37355 Niederorschel OT Rüdigershagen
Tel.: 02301 / 919543 - Fax: 02301 / 9453893
E-Mail: [email protected] - http://www.arbeitssicherheitdortmund.de
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Safety glasses
(Contd. on page 5)
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42.0.12
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 4)
· Body protection: Protective work clothing

* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Colour: Suspension with black pigments
Clear
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Not applicable, as aerosol.
· Flash point: -97 °C
Basis: propellant
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: Not determined - aerosol.
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive
air/vapour mixtures are possible.
· Explosion limits:
Lower: 0.5 Vol %
Upper: 10.9 Vol %
· Vapour pressure at 20 °C: 8300 hPa
Basis: propellant
· Spray can internal pressure (20 °C): 4.8 bar
· Spray can internal pressure (50 °C): 7.0 bar
· Density at 20 °C: 0.77 g/cm³
Basis: active substance
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Organic solvents: 44.6 %
VOC (EU) 99.75 %
· 9.2 Other information No further relevant information available.
GB
(Contd. on page 6)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 5)

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
Avoid open flame or electrical ignition.
Danger of bursting of the aerosol can during overheating
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Strong oxidizing agents.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
106-97-8 butane
Inhalative LC50/4 h 658 mg/l (rat)
· Primary irritant effect:
· Skin corrosion/irritation Low, no classification
· Serious eye damage/irritation low, no classification.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard
May be fatal if swallowed and enters airways.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
Distillates (petroleum), hydrotreated light
LC50/96h 2.6 mg/l (Fisch/fish/poissons/peixes) (Ecotoxicological Data, compiled by the US
Environm)
· 12.2 Persistence and degradability
Moderately /partly biodegradable
Halbwertzeit in der Umwelt < 10 Tage
· 12.3 Bioaccumulative potential
May be accumulated in organism
The product swims on the water surface and is only minimum water soluble.
The product is adsorbed by the soil and is not not mobile.
· 12.4 Mobility in soil No further relevant information available.
· Other information: At longer term no harmful effects for water organisms are expected.
· Additional ecological information:
· General notes:
Do not allow product to reach ground water, water course or sewage system.
Water hazard class 1: weakly water-endangering
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 6)
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
· Waste disposal key:
For this product no waste key number can be specified, because only the intended purpose permits
an allocation. The waste key number is to be specified in arrangement with the regional waste
disposal.
· European waste catalogue
07 07 04* other organic solvents, washing liquids and mother liquors
15 01 10* packaging containing residues of or contaminated by dangerous substances
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN1950
· 14.2 UN proper shipping name
· ADR 1950 AEROSOLS
· IMDG AEROSOLS
· IATA Aerosols, flammable
· 14.3 Transport hazard class(es)
· ADR

· Class 2 5F Gases.
· Label 2.1
· IMDG, IATA

· Class 2.1
· Label 2.1
· 14.4 Packing group
· ADR, IMDG, IATA Void
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 7)

· 14.5 Environmental hazards:

· Marine pollutant: No
· 14.6 Special precautions for user Warning: Gases.
· Danger code (Kemler): -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity
of 1 litre: Category A. For AEROSOLS with a
capacity above 1 litre: Category B. For WASTE
AEROSOLS: Category C, Clear of living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of
1 litre: Segregation as for class 9. Stow "separated
f rom " c lass 1 ex cept f or divis ion 1.4. For
AEROSO LS with a c apacity above 1 litre:
Segregation as for the appropriate subdivision of
class 2. For WASTE AEROSOLS: Segregation as
for the appropriate subdivision of class 2.
· 14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN1950, AEROSOLS, 2.1

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
REACH international regime: REGULATION (EC) No 1907/2006 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European
Chemicals Agency, amending Directive 1999/45 / EC and repealing Regulation (EEC) No 793/93
and Regulation (EC) No 1488/94 and Directive 76/769 / EEC and of the Commission 91/155 / EEC
directives 93/67 / EEC , 93/105 / EC and 2000/21 / EC
2. CLP international regime: REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and
packaging of substances and mixtures, amending and repealing Directives
67/548 / EEC and 1999/45 / EC and amending Regulation (EC) No. 1907/2006
3. REGULATION (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of
the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH)
3.a REGULATION (EU) No 830/2015 of 28 May 2015 amending Regulation (EC) No 1907/2006 of
the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH)
(Contd. on page 9)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 8)
4. Domestic regulations on hazardous substances: Act XXV / 2000 on chemical safety and its
amendments
Amendments to Regulation No. 44/2000 (XII.27) EüM the Minister of Health on the detailed rules for
certain procedures and activities, dangerous substances and dangerous preparations related to
5. House Regulation on waste: CLXXXV Act 2012 on waste Government Decree No 98/2001
(VI.15.) One of the conditions of the activities related to hazardous wastes and their changes
72/2013 (VIII. 27) VM Decree on Waste Catalogue
6. Domestic Regulation on Water Pollution: Government Decree No. 220/2004 (VII. 21) and its
amendments
7. House Regulation on Safety and Health: Act XCIII of 1993 on occupational safety, its
amendments and relevant Ministry of Labour and the Ministry of National Economy decrees
8. House regulation on chemical safety of workplaces: Joint Decree No. 25/2000 A. EüM-SzCsM
and its amendments
9. Regulations on aerosol: NGM (Ministry of Economics) Decree No. 34/2014 on the requirements
of the distribution of aerosol products and aerosol packaging
· Directive 2012/18/EU
· Qualifying quantity (tonnes) for the application of lower-tier requirements 150 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
· National regulations:
· Waterhazard class:
W ater hazard class 1: slightly hazardous for water.(In accordance with classification
VwVwS,appendix 4)
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

The data in this safety data sheet are based on our knowledge at the time of the revision.The
information should give you reference points for a safe handling of the product specified in this
safety data sheet. The data are not transferable to other products. If the product specified in this
safety data sheet is mixed or processed with other materials, the data cannot be transferred without
examination.
· Relevant phrases
The wording of the listed risk phrases are those of the individual raw materials.
H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
H304 May be fatal if swallowed and enters airways.
· Recommended restriction of use
Existing national and local laws concerning chemicals are to be considered.
· Department issuing SDS:
MR Chemie
3AK ChemieGmbH, Dep.
Pvt. Ltd., safety data sheets, Tel.:+91
[email protected], +49/(0)2303/95151-38
97017 00017
· Contact:
MR Chemie
3AK ChemieGmbH, Dep.
Pvt. Ltd., safety data sheets, Tel.:+91
[email protected], +49/(0)2303/95151-38,
97017 00017 [email protected]
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Gas 1: Flammable gases, Hazard Category 1
(Contd. on page 10)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.02.2016
20.05.2020 Revision: 11.02.2016
20.05.2020

Trade name: MR® 76 S“The

D-Shield Magnetic powder
Ultimate suspension,
Disinfecting black
Spray”
valid for all versions

(Contd. of page 9)
Aerosol 1: Flammable aerosols, Hazard Category 1
Press. Gas C: Gases under pressure: Compressed gas
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
· * Data compared to the previous version altered.
GB

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