AL/2020/02/T

KOg;gjpg;GupikAilaJ / All Rights Reserved

mwpTWj;jy;fs; :
 ,t;tpdhj;jhs;fs; 6 gf;fq;fspy; 10 gy;Nju;T> 1 mikg;Gf;fl;Liu> 1 fl;Liu tpdhf;fis
nfhz;lJ.
 vy;yh tpdhf;fSf;Fk; tpil jUf.
 jug;gl;Ls;s ,lj;jpy; ckJ Rl;nlz;iz vOJf.
 gFjp-I 1 njhlf;fk; 10 tiuahd tpdhf;fs; xt;nthd;wpYk; (1),(2),(3),(4),(5) vd
,yf;fkplg;gl;l tpilfspy; rupahd my;yJ kpfg; nghUj;jkhd tpilia njupT nra;f.
mfpy thA khwpyp R = 8.314 J K-1mol-1
mtfhjNuh khwpyp NA = 6.022×1023 mol-1
gpshq;fpd; khwpyp h = 6.626×10-34 Js
xspapd; Ntfk; c = 3×108 ms-1

gFjp-I
1. gpd;tUtdtw;Ws; Y}ap %ykhf nraw;glhjJ vJ?
1.H+ 2. NH3 3. I- 4. H2O 5. Cl-

2. C, H, O Mfpatw;iw kl;Lk; nfhz;Ls;s A vDk; Nru;itapd; %yf;$w;Wj;jpzpT

134gmol-1 nrwp H2SO4 Kd;dpiyapy; vjNdhYld; jhf;fk; Gupe;J ngwg;gl;l
Nru;itapd; %yf;$w;Wj;jpzpT 190gmol-1 A MdJ PCl5 cld; jhf;fk; Gupe;J
ngwg;gl;l Nru;itapd; %yf;$w;Wj;jpzpT 189.5 gmol-1 A apYs;s OH $l;lq;fs;
vz;zpf;if
(1) 1 (2) 2 (3) 3 (4) 4 (5) 5

3. maBd; epakpg;gpd; %yk; Copper(II) cg;gpy; mlq;fpAs;s nrg;gpd; rjtPjk; Jzpayhk;

,jw;fhf Copper(II) Sulphate ,d; 0.305g khjpupnahd;W 25cm3 ePupy; fiuj;J gpd;
kpif KI fiury; Nru;f;fg;gl;lJ ,jd; NghJ tpLtpj;j I3-(aq) KOtijAk; epakpf;f
0.1moldm-3 Na2SO3 ,d; 24.50cm3 Njitg;gl;lJ khjpupapYs;s Cu ,d; rjtPjk; ahJ?
(1) 12.75 (2) 25.50 (3) 48.40 (4) 51.0 (5) 64.2

1
AL/2020/02/T
KOg;gjpg;GupikAilaJ / All Rights Reserved

4. gpd;tUk; $w;Wf;fspy; gpioahdJ vJthFk;?

1) H2O2 xl;rpNaw;wpahfTk; jho;j;jpahfTk; njhopw;glty;yJ
2) H2S nkd;dkpy ,ay;Gs;sJ.
3) CO2 ePupy; fiue;J fhNghdpf;fkpyj;ij cUthf;Fk;.
4) SO2, Cl2 Nghd;wit ntspw;Wk; ,ay;Gilait.
5) NH3 xl;rpNaw;wpahf njhopw;glhJ.

5. T ntg;gepiyapy; V fdtsTila tpiwj;j ghj;jpuk; xd;wpy; 1mol P(g) ck; 2mol

Q(g) ck; itf;fg;gl;Ls;sJ. gpd; ghj;jpuj;jpd; ntg;gepiy 2T Mf cau;j;jg;gl;L
njhFjpahdJ gpd;tUk; rkd;gl;bw;F mika rkepiy mila tplg;gl;lJ.
P(g)+Q(g) 2R(g)+S(g)

2T ,y; NkNy jug;gl;l jhf;fj;jpd; rkepiy khwpyp Kp, P apd; $l;lw;gpupif msT 𝛼
vdpd; Kp ,w;fhd Nfhit ahJ?

4𝛼 3 𝑅𝑇
1. 𝐾𝑃 = 2𝛼3 𝑅𝑇 2𝛼 3 𝑅𝑇
(1−𝛼)2 𝑉 2. 𝐾𝑃 = 3. 𝐾𝑃 =
(1−𝛼)2 𝑉 3(1−𝛼)2 𝑉

8𝛼 3 𝑅𝑇 4𝛼3 𝑅𝑇
4. 𝐾𝑃 = 5. 𝐾𝑃 =
(1−𝛼)(2−𝛼)𝑉 (1−𝛼)(2−𝛼)𝑉

6. gpd;tUtdtw;Ws; xNu epwKs;s rpf;fy;fis nfhz;lJ.

1) [Ni(NH3)6]2+, [Cu(H2O)6]2+, [Co(H2O)6]2+
2) [Ni(NH3)6]2+, [Cu(NH3)6]2+, [Ti(H2O)6]3+
3) [Mn(H2O)6]2+,[Co(H2O)6]2+, [CuCl4]2-
4) [FeCl4]2-, [CuCl4]2-, [CoCl4]2-
5) [Ni(NH3)6]2+, [Cu(NH3)4]2+, [CoCl4]2-

7. nkd;dkpyk;> nkd;%yq;fspd; $l;lw;gpupT khwpypfs; KiwNa Ka, Kb MFk;

xt;nthd;wpdJk; Muk;gr;nrwpTfs; C moldm-3 MFk; 25oC ,y; gpd;tUk;
njhlu;GfSs; rupahdit?
1 1
a. 𝑝𝐻 = 2 𝑝𝐾𝑎 − 𝑙𝑜𝑔𝐶 (nkd;fhuj;jpd;)
2
1 1
b. 𝑝𝐻 = 14 − 2 𝑝𝐾𝑎 + 𝑙𝑜𝑔𝐶(nkd;fhuj;jpd;)
2
1 1 1
c. 𝑝𝐻 = 2 𝐾𝑤 + 𝑝𝐾𝑎 + 2 𝑙𝑜𝑔𝐶 (nkd;dkpyj;jpd; cg;G)
2
1 cg;G
d. 𝑝𝐻 = 𝑝𝐾𝑎 − 𝑙𝑜𝑔 mkpyk; (nkd;dkpyk;> nkd;fhuk;)
2

2
AL/2020/02/T
KOg;gjpg;GupikAilaJ / All Rights Reserved

8. gpd;tUk; Nru;it gw;wpa vJ/ vit cz;ikahdJ/ cz;ikahdit?

COCH3

COCH3

a. cyu; AlCl3 cld; GNuhkpNdw;wk; nra;Ak; NghJ cUthFk;

Br
b. Zn/ Hg/ ConHCl cld; jho;j;jg;gLk; NghJ xspapay; gz;Gila %yf;$iw
cUthf;Ffpd;wJ.
c.NaBH4 cld; jho;j;jg;gl;l NghJ xspapay;n;ghl;il cila %yf;$iw tpisthf
cUthf;Ffpd;wd. CHO

d. mkpy KMnO4 cld; xl;rpNaw;Wk; NghJ ,id tpisthf jUk;.

9. $w;W I : XuyF Neuj;jpy; ngwg;gLk; tpisTfspd; msit Cf;fpfs; khw;Wfpd;wd.

$w;W II : Cf;fpfs; jhf;fk; xd;wpd; Vtw;rf;jpia khw;Wfpd;wd.

10. $w;W I : ry;Ngw;Wf;fspd; ePu;f;fiujpwd; $l;lk; II ,y; $l;lj;jpd; topNa fPo;Nehf;fp

mjpfupf;fpwJ.

$w;W II : $l;lk; II ,y; fPo; Nehf;fp nry;y ry;Ngw;Wf;fspd; mad; rpwg;gpay;G

mjpfupf;fpwJ.

3
AL/2020/02/T
KOg;gjpg;GupikAilaJ / All Rights Reserved

mikg;Gf;fl;Liu tpdh
1. (a) N2O eLepiy thAr; Nru;itAk; kw;Wk; rpupg;g+l;Lk; thATk; MFk;. 500K ntg;g
epiyapYk; 1×105Pa mKf;fj;jpYk; N2O thA gpupiff;F cl;gl;L N2 thAitAk; O2
thAitAk; jUfpwJ ntg;gg; gpupifr; nrad;Kiwf;fhd gpd;tUk; gz;Gfis ,f;fw;wy;
nrad;Kiw ntspg;gLj;JfpwJ.

rf;jp kJmol-1
TS1
TS2

80 30

2N2O(g)
2N2O(g)+O(g)+N2(g)

164

O2(g)+N2(g)

jhf;fg;ghij

i. ,j;jhf;fj;jpw;fhd nghwpKiw jhf;fq;fis vOjp mjpy; ,Ue;J xl;Lnkhj;j

jhf;fj;ij vOJf.
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
ii. vJ/vit ,il epiy tpisT/ tpisTfs;
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
iii. ,j;jhf;fj;jpd; ΔH kw;Wk; Ea vd;gtw;wpd; ngWkhdq;fis vOJf.
ΔH ……………………………………………………………………………………………
Ea ……………………………………………………………………………………………
𝑆𝑓𝑜 𝐽𝑚𝑜𝑙 −1 𝐾 −1

N2(g) 192
O2(g) 205
N2O(g) 220

4
AL/2020/02/T
KOg;gjpg;GupikAilaJ / All Rights Reserved

iv. 500K ,y; 2N2O(g) → 2 N2(g) + O2(g) vDk; jhf;fj;jpw;Fupa ΔS I fzpf;Ff.

…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
v. Nkw;gb jhf;fj;jpw;fhd ΔG I fzpf;Ff.
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
vi. Nkw;gb jhf;fj;jpd; RahjPd jd;ik gw;wp tpgupf;Ff.
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
(b) Q vd;gJ Na, S, H, O vd;gtw;iwf;nfhz;l xU ePu; Vw;wg;gl;l cg;ghFk; ,J 18.5% Na,
25.8% S, 4.0% H kw;Wk; kPjp O vd;gtw;iwf; jpzpT tpfpjj;jpy; nfhz;Ls;sJ
nfhz;Ls;sJ ,r;Nrhu;itapy; H MdJ H2O Mf kl;Lk; fhzg;gLfpwJ.
i. Q ,d; mDgt #j;jpuj;ij ngWf. (Na=23 S=32, H=1, O=16)
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
ii. Q ,d; rhu; %yf;$w;Wj;jpzpT 248 vdpd; mjd; Kyf;$w;Wr; #j;jpuj;ijg; ngWf.
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
iii. Q ,d; md;dadpd; tbtj;ij jUf.
…………………………………………………………………………………………………….
iv. 0.5moldm-3, 25.00cm3 cg;G Q tpd; fiury; 0.2moldm-3 KI3 fiurYf;F vjpuhf ,U
Jspfs; khg;nghUs; fhl;b Kd;dpiyapy; epakpf;fg;gl;lJ KbTg;Gs;spapy; KI3
fiurypd; fdtsit fzpf;f.
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….
…………………………………………………………………………………………………….

5
AL/2020/02/T
KOg;gjpg;GupikAilaJ / All Rights Reserved

fl;Liu tpdh
1. (a) xNunahU Muk;gr;Nrjdr;Nru;itahfCH3CH=CH2 Ig; gad;gLj;jp jug;gl;l
gl;baypYs;s ,uhradg;gjhu;jq;fis kl;Lk; gad;gLj;jp fPNo jug;gl;l Nru;itia
njhFg;gjw;fhd jhf;fj;jpl;lnkhd;iw gpNuupf;f. (ckJ jhf;fjpl;lk; 5 gbfSf;F
Nkw;glyhfhJ.)
H H H –
– –

CH3 – C – CH2–N – –
c – C – CH3
CH3 CH3
(b) gpd;tUk; jhf;f jpl;lj;ij g+uzg;gLj;Jtjw;F R1-R6, X1-X3, Y1-Y4 kw;Wk; Nru;it Q
,idAk; ,dk; fhz;f.
O
=

(CH3)2–CH–C–O–CH2–
(1) NaOH
(2)H+

X1 Y1

R1 R3

X2 Y2

R2 R4
X3 Y3

R5

Y4

(CH3)2–CH2–CH=N–CH2 – Cl

O
=

c. i. CH3 – C – CH3 gpuhbapd; Nrhjidg;nghUSldhd jhf;fk; vj;jid gbfspy;

eilngWk;? ,tw;wpy; KjyhtJ gb vt;tif jhf;fj;jpw;FupaJ?
ii. ,j;jhf;fj;jpd; ,Wjpapy; ngwg;gLk; mtjhdk; ahJ?
iii. mjd; fl;likg;ig tiuf.
iv. my;bifl;ilAk; fPw;NwhidAk; NtWgLj;j gadgLj;jf;$ba
Nrhjidg;nghUl;fis jUf.
v. fhgidy; Nru;itfspd; gpuj;jpNafj;jhf;fk; fU ehl;lf;$l;lyhFk; ,jid
fhuzj;Jld; tpsf;Ff.