→ Safety Datasheet
Helium (and high purity helium).
MSDS NR : HKO-005G-04/2007/1
Identification of the Product name Helium
substance/ preparation Chemical formula He
and of the company
Company identification See end of each page
Emergency phone Nos (852) 2661 0920
(24 hrs.)
Composition / Substance/ Preparation Substance
information on ingredients Components/ Impurities Contains no other components or impurities which will influence
the classification of the product.
CAS Nr 7440-59-7
Specifications Helium 99.99% min, High Purity Helium 99.995% min
Hazards identification Hazards identification Compressed gas, non toxic
In high concentrations may cause asphyxiation.
First aid measures Inhalation Inhalation in high concentration may cause asphyxiation. Symptoms may include
loss of mobility / consciousness. Victim may not be aware of asphyxiation. Remove
victim to uncontaminated area and inhale fresh air. Rescue personnel should be
equipped with self-contained breathing apparatus. Keep victim warm and rested.
Call a doctor. Apply artificial respiration if breathing stopped.
Ingestion Ingestion is not considered a potential route of exposure.
Fire fighting measures Specific hazards Non flammable
Exposure to fire may cause containers to rupture/explode.
Hazardous combustion None
products
Suitable All known extinguishants can be used.
extinguishing media
Specific methods If possible, stop flow of product. Move container away and cool with water from a
protected position. Inform Fire Services Department
Special protective In confined space, use self-contained breathing apparatus
equipment for fire fighters
Accidental release Personal precautions Evacuate area. Wear self-contained breathing apparatus when entering area
measures unless atmosphere is proved to be safe. Ensure adequate air ventilation.
Environmental Try to stop release.
precautions
Clean up methods Ventilate area.
Handling and storage Handling and storage Use no oil or grease. Cylinders should be stored upright and firmly secured.
Do not heat cylinder.
Suck back of water into the container must be prevented. Do not allow backfeed
into the container. Use only properly specified equipment which is suitable for this
product, its supply pressure and temperature. Keep away from ignition sources
(including static discharges). Refer to supplier’s container handling instructions.
Contact your gas supplier if in doubt.
Keep container below 50°C in a well ventilated place.
Exposure controls/ Personal protection Ensure adequate ventilation
personal protection Wear suitable hand, body and head protection.
Physical and chemical Molecular weight 4
properties Melting point Not applicable
Boiling point -269°C
Critical temperature -268°C
Relative density, gas 0.14 (air=1)
2 of 2
Relative density, liquid Not applicable
Vapour Pressure 20°C Not applicable
Solubility mg/l water 1.5 mg/l
Appearance/Colour Colourless gas
Odour None
Stability and reactivity Stability and Reactivity Stable under normal conditions.
Toxicological information General No known toxicological effects from this product.
Ecological information General No known ecological damage caused by this product
Disposal considerations General To atmosphere in a well ventilated place.
Do not discharge into any place where its accumulation could be dangerous.
Contact supplier if guidance is required.
Transport information Proper Shipping Name Helium, compressed
UN Nr 1046
Class 2.2: non flammable compressed gas
Subsidiary risk Not applicable
ADR/RID Classification code 1 A
ADR/RID Hazard Nr 20
Labelling ADR Label 2 : non flammable non toxic gas
Other transport information · Avoid transport on vehicles where the load space is not separated from the
driver’s compartment.
· Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency.
· Before transporting product containers ensure that they are firmly secured and:
· cylinder valve is closed and not leaking
· valve outlet cap nut or plug (where provided) is correctly fitted
· valve protection device (where provided) is correctly fitted
· adequate ventilation.
· compliance with applicable regulations.
Regulatory information Proper shipping name Helium, compressed
Category Category 2/Class 1: Compressed Gases/Permanent Gases
Risk phrases G3 Warning, contains gas under pressure may explode if heated
Safety phrases S51 Use only in well ventilated areas
National legislation Dangerous Goods Ordinance (Chapter 295)
Other information · Ensure all national / local regulations are observed.
· Asphyxiant in high concentrations.
· Keep container in well ventilated place.
· Do not breathe the gas.
· The hazard of asphyxiation is often overlooked and must be stressed during operator training.
· Use of breathing apparatus must be trained.
· Before use this product in any new process or experiment, a thorough material compatibility and safety study
should be carried out.
· Always leak check cylinders when first collected, delivered or used using an approved leak detection fluid.
· Details given in this document are believed to be correct at the time of going to press. Whilst proper care has
been taken in the preparation of this document, no liability for injury or damage resulting from its use can be
accepted.
Linde HKO Ltd.
12 Chun Yat Street, Tseung Kwan O Industrial Estate, Tseung Kwan O, Kowloon, Hong Kong
Phone +852.2372-2288, Fax +852.2372-2508
