Handbook

of
Electrochemical Impedance Spectroscopy

0
- Im Z *

uc2 =1T
-1
uc1 =1

0 1 T
Re Z *

CIRCUITS
made of
RESISTORS and INDUCTORS

ER@SE/LEPMI
J.-P. Diard, B. Le Gorrec, C. Montella

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September 6, 2007
2
Contents

1 Circuits containing one L 5

1.1 Circuit (R+L) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.1.1 Impedance . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.1.2 Reduced impedance . . . . . . . . . . . . . . . . . . . . . 5
1.2 Circuit (R/L) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.2.1 Impedance . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.2.2 Reduced impedance . . . . . . . . . . . . . . . . . . . . . 6
1.3 Circuit (R2 +(R1 /L1 )) . . . . . . . . . . . . . . . . . . . . . . . . 7
1.3.1 Impedance . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.3.2 Reduced impedance . . . . . . . . . . . . . . . . . . . . . 7
1.4 Circuit ((R1 +L1 )/R2 ) . . . . . . . . . . . . . . . . . . . . . . . . 8
1.4.1 Impedance . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.4.2 Reduced impedance . . . . . . . . . . . . . . . . . . . . . 8
1.5 Transformation formulae
(R+(R/L)) ↔ ((R+L)/R) . . . . . . . . . . . . . . . . . . . . . 8
1.5.1 Transformation formulae (R+(R/L)) → ((R+L)/R) . . . 8
1.5.2 Transformation formulae ((R+L)/R) → (R+(R/L)) . . . 9
1.6 Circuits containing L vs. circuits containing C . . . . . . . . . . . 9
1.6.1 Transformation formulae circuit 1 ↔ circuit 2
and circuit 3 ↔ circuit 4 . . . . . . . . . . . . . . . . . . 9
1.6.2 Transformation formulae circuit 3 → circuit 1 . . . . . . . 9
1.6.3 Transformation formulae circuit 1 → circuit 3 . . . . . . . 9
1.6.4 Transformation formulae circuit 4 → circuit 1 . . . . . . . 9
1.6.5 Transformation formulae circuit 1 → circuit 4 . . . . . . . 10
1.6.6 Transformation formulae circuit 3 → circuit 2 . . . . . . . 10
1.6.7 Transformation formulae circuit 2 → circuit 3 . . . . . . . 10
1.6.8 Transformation formulae circuit 4 → circuit 2 . . . . . . . 10
1.6.9 Transformation formulae circuit 2 → circuit 4 . . . . . . . 10
1.7 Modified inductance . . . . . . . . . . . . . . . . . . . . . . . . . 10

2 Circuits made of one R

and two Ls 11
2.1 Circuit ((R1 /L1 )+L2 ) . . . . . . . . . . . . . . . . . . . . . . . . 11
2.1.1 Impedance . . . . . . . . . . . . . . . . . . . . . . . . . . 11
2.1.2 Time constants . . . . . . . . . . . . . . . . . . . . . . . . 11
2.1.3 Reduced impedance . . . . . . . . . . . . . . . . . . . . . 12
2.2 Circuit ((R1 +L2 )/L1 ) . . . . . . . . . . . . . . . . . . . . . . . . 12
2.2.1 Impedance . . . . . . . . . . . . . . . . . . . . . . . . . . 13

3
4 CONTENTS

2.2.2 Time constants . . . . . . . . . . . . . . . . . . . . . . . . 13

2.2.3 Reduced impedance . . . . . . . . . . . . . . . . . . . . . 13
2.3 Transformation formulae ((R/L)+L) ↔ ((R+L)/L) . . . . . . . . 13
2.3.1 Transformation formulae ((R/L)+L) → ((R+L)/L) . . . . 13
2.3.2 Transformation formulae ((R+L)/L) → ((R/L)+L) . . . . 13
Chapter 1

Circuits containing one L

1.1 Circuit (R+L)

L
R

Figure 1.1: Circuit (R+L).

1.1.1 Impedance
Z(ω) = R + i L ω , Re Z(ω) = R , Im Z(ω) = L ω

1.1.2 Reduced impedance

Z ∗ (u) = Z/R = 1 + i u , u = ω τ , τ = L/R
Re Z ∗ (u) = 1 , Im Z ∗ (u) = u

0
- Im Z*

Im Y*

-1 uc =1
uc =1

0 1 0 1
Re Z* Re Y*

Figure 1.2: Nyquist diagrams of reduced impedance and admittance (Y ∗ = R Y ) for

the (R+L) circuit.

5
6 CHAPTER 1. CIRCUITS CONTAINING ONE L

1.2 Circuit (R/L)

Figure 1.3: Circuit (R/L).

1.2.1 Impedance
1 iLRω
Z(ω) = =
1 1 R + iLω
+
iωL R
L2 R ω 2 L R2 ω
Re Z(ω) = , Im Z(ω) =
R 2 + L2 ω 2 R 2 + L2 ω 2

1.2.2 Reduced impedance

Z iu
Z ∗ (u) = = , u = ω τ , τ = L/R
R 1 + iu
u2 u
Re Z ∗ (u) = , Im Z ∗ (u) =
1 + u2 1 + u2

0
Im Y*
- Im Z*

-1 uc =1
-0.5
uc =1
0 1 0 1
Re Z* Re Y*

Figure 1.4: Nyquist diagrams of reduced impedance and admittance (Y ∗ = R Y ) for

the (R/L) circuit.
1.3. CIRCUIT (R2 +(R1 /L1 )) 7

1.3 Circuit (R2 +(R1/L1 ))

L1

R2

R1

Figure 1.5: Circuit (R2 +(R1 /L1 )).

1.3.1 Impedance
 
i ω L1 (R1 + R2 )
R2 1 +
1 R1 R2
Z(ω) = R2 + =
1 1 i ω L1
+ 1+
i ω L1 R1 R1
ω 2 L1 2 R1 ω L1 R1 2
Re Z(ω) = + R2 , Im Z(ω) =
ω 2 L1 2 + R1 2 ω 2 L1 2 + R1 2

1.3.2 Reduced impedance

1 + iT u
Z ∗ (u) = Z/R2 = , u = τ1 ω , τ1 = L1 /R1 (1.1)
1 + iu
T = (R1 + R2 )/R2 = 1 + R1 /R2 > 1
1 + T u2 (−1 + T ) u
Re Z ∗ (u) = , Im Z ∗ (u) =
1 + u2 1 + u2
lim Re Z ∗ (u) = 1 , lim Re Z ∗ (u) = T
u→0 u→∞

1T
0 0
- Im Z *

Im Y *

uc2 =1T uc1 =1

-1
uc2 =1T
uc1 =1 -0.5

0 1 T 0 1
Re Z * Re Y *

Figure 1.6: Nyquist diagram of reduced impedance and admittance (Y ∗ = R2 Y ) for

the (R2 +(R1 /L1 )) circuit, plotted for T = 3.
8 CHAPTER 1. CIRCUITS CONTAINING ONE L

1.4 Circuit ((R1 +L1)/R2 )

R2

L1
R1

Figure 1.7: Circuit ((R1 +L1 )/R2 ).

1.4.1 Impedance
 
i ω L1
1+
R1 R2
(i ω L1 + R1 ) R2 R1
Z(ω) = =  
i ω L1 + R1 + R2 i ω L1
(R1 + R2 ) 1 +
R1 + R2
2


2
R2 ω L1 + R1 (R1 + R2 ) ω L1 R2 2
Re Z(ω) = 2 , Im Z(ω) = 2
ω 2 L1 2 + (R1 + R2 ) ω 2 L1 2 + (R1 + R2 )

1.4.2 Reduced impedance

Z (R1 + R2 ) 1 + iT u
Z ∗ (u) = = , u = τ1 ω , τ1 = L1 /(R1 + R2 )
R1 R2 1 + iu
T = τ2 /τ1 , τ2 = L1 /R1 , T = 1 + R2 /R1 > 1
cf. § 1.3.2, Eq. (1.1) and Fig. 1.6.

1.5 Transformation formulae

(R+(R/L)) ↔ ((R+L)/R)

L11
R22

R21
L12
R11 R12

Figure 1.8: The (R+(R/L)) and ((R+L)/R) circuits are non-distinguishable.

1.5.1 Transformation formulae (R+(R/L)) → ((R+L)/R)

L11 R21 2
R22 = R11 + R21 , L12 = , R12 = R21 +
R11 R11
1.6. CIRCUITS CONTAINING L VS. CIRCUITS CONTAINING C 9

1.5.2 Transformation formulae ((R+L)/R) → (R+(R/L))

L12 R22 2 R22 2 R12 R22
L11 = , R11 = , R21 =
R12 + R22 R12 + R22 R12 + R22

1.6 Circuits containing L vs. circuits

containing C

L11
R22

R21
L12
R11 R12

Circuit 1: HR+HRLLL Circuit 2: HHR+LLRL

C13

R24

R23 C14

R13 R14

Circuit 3: HR+HRCLL Circuit 4: HHR+CLRL

Figure 1.9: (R+(R/L)), ((R+L)/R), (R+(R/C)), ((R+C)/R) circuits are non-

distinguishable, taking account of negative values of parameters.

1.6.1 Transformation formulae circuit 1 ↔ circuit 2

and circuit 3 ↔ circuit 4
cf. § 1.5 and ”Handbook of EIS : Circuits made of Rs and Cs”.

1.6.2 Transformation formulae circuit 3 → circuit 1

L11 = −C13 R13 2 , R21 = R13 + R23 , R11 = −R13

1.6.3 Transformation formulae circuit 1 → circuit 3

L11
C13 = − , R23 = R11 + R21 , R13 = −R11
R11 2

1.6.4 Transformation formulae circuit 4 → circuit 1

R24 2
L11 = −C14 R24 2 , R21 = R24 , R11 = −
R14 + R24
10 CHAPTER 1. CIRCUITS CONTAINING ONE L

1.6.5 Transformation formulae circuit 1 → circuit 4

R21 (R11 + R21 ) L11
R24 = R21 , R14 = − , C14 = −
R11 R21 2

1.6.6 Transformation formulae circuit 3 → circuit 2

R23 (R13 + R23 )
L12 = C13 R13 , R22 = R23 , R12 = −
R13

1.6.7 Transformation formulae circuit 2 → circuit 3

L12 (R12 + R22 ) R22 2
C13 = − , R23 = R22 , R13 = −
R22 2 R12 + R22

1.6.8 Transformation formulae circuit 4 → circuit 2

R14 R24
L12 = C14 (R14 + R24 ), R22 = , R12 = −R14
R14 + R24

1.6.9 Transformation formulae circuit 2 → circuit 4

R12 R22 L12 (R12 + R22 )
R14 = −R12 , R24 = , C14 = −
R12 + R22 R12 2

1.7 Modified inductance

α
Z = Lα (i ω) , Re Z = Lα ω α cα , Im Z = Lα ω α sα
πα πα
cα = cos( ) , sα = sin( )
2 2
πα
|Z| = Lα ω α , φZ = = cte
2
The Lα unit (H cm2 s1−α ) depends on α.

0 0
Π Π
Α -Α
2 2
- Im Z

Im Y

0 0
Re Z Re Y

Figure 1.10: Nyquist diagrams of the impedance and admittance for the modified
inductance Lα , plotted for α = 0.8.
Chapter 2

Circuits made of one R

and two Ls

2.1 Circuit ((R1 /L1 )+L2)

L1
L2

R1

Figure 2.1: Circuit ((R1 /L1 )+L2 ).

2.1.1 Impedance
 
i ω L1 L2
i ω (L1 + L2 ) 1 +
1 (L1 + L2 ) R1
Z(ω) = + i ω L2 =
1 1 i ω L1
+ 1+
R1 i ω L1 R1

2.1.2 Time constants

(L1 + L2 ) i ω (1 + i ω τ2 ) L1 L1 L2
Z(ω) = , τ1 = , τ2 =
1 + i ω τ1 R1 (L1 + L2 ) R1


ω 2 (L1 + L2 ) (τ1 − τ2 ) ω (L1 + L2 ) 1 + ω 2 τ1 τ2
Re Z(ω) = , Im Z(ω) =
1 + ω 2 τ1 2 1 + ω 2 τ1 2

(L1 + L2 ) (τ1 − τ2 )
lim Re Z(ω) = = R1
ω→∞ τ1 2

11
12 CHAPTER 2. CIRCUITS MADE OF ONE R AND TWO LS

2.1.3 Reduced impedance

1 i u (1 + i T u)
Z ∗ (u) = Z(ω)/R1 = (2.1)
1−T 1 + iu

τ2 L2
u = ω τ1 , T = = <1
τ1 L1 + L2


u2 u 1 + T u2
Re Z (u) =
∗
, Im Z (u) = −
∗
, lim Re Z(u) = 1
1 + u2 (−1 + T ) (1 + u2 ) u→∞

- Im Z * 0

-1

-2

0 1
*
Re Z

Figure 2.2: Nyquit diagrams of reduced impedance for the ((R1 /L1 )+L2 ) circuit
(Eq. (2.1), Fig. 2.1, T = 1/4, 1/9, 1/90, the line thickness inceases with increasing T ).
Horizontal tangent for T ≤ 1/9 (L1 /L2 ≥ 8). Dots: reduced caracteristic angular
frequency: uc1 = 1; circles: reduced caracteristic angular frequency uc2 = 1/T .

2.2 Circuit ((R1 +L2)/L1 )

L1

L2
R1

Figure 2.3: Circuit ((R1 +L2 )/L1 ).

2.3. TRANSFORMATION FORMULAE ((R/L)+L) ↔ ((R+L)/L) 13

2.2.1 Impedance
 
i ω L2
1+
i ω L1
i ω L1 (i ω L2 + R1 ) R1
Z(ω) = =
i ω L1 + i ω L2 + R1 i ω (L1 + L2 )
1+
R1

2.2.2 Time constants

i ω L1 (1 + i ω τ2 ) L1 + L2 L2
Z(ω) = , τ1 = , τ2 =
1 + i ω τ1 R1 R1


ω 2 L1 (τ1 − τ2 ) ω L1 1 + ω 2 τ1 τ2
Re Z(ω) = , Im Z(ω) =
1 + ω 2 τ1 2 1 + ω 2 τ1 2
L1 (τ1 − τ2 ) L1 2 R1
lim Re Z(ω) = = 2
ω→∞ τ1 2 (L1 + L2 )

2.2.3 Reduced impedance

i u (1 + i T u)
Z ∗ (u) = Z(ω)/R1 = (1 − T ) (2.2)
1 + iu
τ2 L2
u = ω τ1 , T = = <1
τ1 L1 + L2
2


(−1 + T ) u2 (−1 + T ) u 1 + T u2
Re Z (u) =
∗
, Im Z ∗
(u) = −
1 + u2 1 + u2
L1 2
lim Re Z(u) = 2
u→∞ (L1 + L2 )
(Fig. 2.4)

2.3 Transformation formulae ((R/L)+L) ↔ ((R+L)/L)

2.3.1 Transformation formulae ((R/L)+L) → ((R+L)/L)
2
(L11 + L21 ) R11 L21 2
R12 = , L 22 = L 21 + , L12 = L11 + L21
L11 2 L11

2.3.2 Transformation formulae ((R+L)/L) → ((R/L)+L)

L12 L22 L12 2 L12 2 R12
L21 = , L11 = , R11 = 2
L12 + L22 L12 + L22 (L12 + L22 )
14 CHAPTER 2. CIRCUITS MADE OF ONE R AND TWO LS

- Im Z *
-1

-2

0 1
*
Re Z

Figure 2.4: Nyquit diagrams of the reduced impedance for the ((R1 +L2 )/L1 ) circuit
(Eq. (2.2), Fig. 2.3, T = 1/4, 1/9, 1/90, the line thickness inceases with increasing T ).
Horizontal tangent for T ≤ 1/9 (L1 /L2 ≥ 8). Dots: reduced caracteristic angular
frequency: uc1 = 1; circles: reduced caracteristic angular frequency uc2 = 1/T .

L11 L12
L21
L22
R11 R12

Figure 2.5: The ((R/L)+L) and ((R+L)/L) circuits are non-distinguishable.