SAFETY DATA SHEET

1. IDENTIFICATION
A. Product name
- EP139PTA-CLEAR

B. Recommended use and restriction on use

- General use : epoxy primer
- Restriction on use : Do not use except for purpose

C. Supplier information
- Company name : KCC Corporation
- Address : 30, Bangeojinsunhwando-ro, Dong-gu, Ulsan
- Emergency telephone
: 82-52-280-1717
number

2. HAZARD IDENTIFICATION
A. GHS Classification
- Flammable liquids : Category2
- Acute toxicity (oral) : Category5
- Acute toxicity (inhalation: vapor) : Category4
- Skin corrosion/irritation : Category2
- Serious eye damage/irritation : Category2A
- Carcinogenicity : Category2
- Reproductive toxicity : Category2
- Specific target organ toxicity(Single exposure) : Category2
- Specific target organ toxicity(Single exposure) : Category3(Narcotic effects)
- Specific target organ toxicity(Single exposure) : Category3(Respiratory tract irritation)
- Specific target organ toxicity(Repeated exposure) : Category1
- Aspiration hazard : Category1
- Acute aquatic toxicity : Category2

B. GHS label elements

○ Hazard symbols

○ Signal words
- Danger
○ Hazard statements
- H225 Highly flammable liquid and vapour
- H303 May harmful if swallowed.
- H304 May be fatal if swallowed and enters airways
- H315 Causes skin irritation
- H319 Causes serious eye irritation
- H332 Harmful if inhaled
- H335 May cause respiratory irritation.
- H336 May cause drowsiness and dizziness.
- H351 Suspected of causing cancer
- H361 Suspected of damaging fertility or the unborn child
- H371 May cause damage to organs (Refer Section SDS 11)
- H372 Causes damage to organs through prolonged or repeated exposure (Refer Section SDS 11)
- H401 Toxic to aquatic organisms.
○ Precautionary statements
1) Prevention
- P201 Obtain special instructions before use.

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 - P202 Do not handle until all safety precautions have been read and understood.
- P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
- P233 Keep container tightly closed.
- P240 Ground/bond container and receiving equipment.
- P241 Use explosion-proof electrical/ventilating/lighting/equipment.
- P242 Use only non-sparking tools.
- P243 Take precautionary measures against static discharge.
- P260 Do not breathe gas/mist/vapours/spray.
- P261 Avoid breathing gas/mist/vapours/spray.
- P264 Wash hands thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P271 Use only outdoors or in a well-ventilated area.
- P273 Avoid release to the environment.
- P280 Wear protective gloves/protective clothing/eye protection/face protection.
- P281 Use personal protective equipment as required.
2) Response
- P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
- P302+P352 IF ON SKIN: Wash with plenty of soap and water.
- P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
- P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
- P308+P313 If exposed or concerned: Get medical advice/attention.
- P309+P311 If exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
- P312 Call a POISON CENTER or doctor/physician if you feel unwell.
- P314 Get medical advice/attention if you feel unwell.
- P321 Specific treatment
- P331 Do NOT induce vomiting.
- P332+P313 If skin irritation occurs: Get medical advice/attention.
- P337+P313 If eye irritation persists: Get medical advice/attention.
- P362 Take off contaminated clothing and wash before reuse.
- P370+P378 In case of fire: Use Suitable extinguishing media for extinction(Refer Section MSDS 5).
3) Storage
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P403+P235 Store in a well-ventilated place. Keep cool.
- P405 Store locked up.
4) Disposal
- P501 Dispose of contents/container in accordance with local/regional/national/international regulation

C. Other hazards which do not result in classification : (NFPA Classification)

○ NFPA grade (0 ~ 4 level)
- Health : 2, Flammability : 3, Reactivity : 0

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Trade names and Synonyms CAS No. Content(%)

4,4'-(1-Methylethylidene)bisphenol polymer with 2,2'-[(1-
methylethylidene)bis(4,1- - 25036-25-3 40 ~ 50
phenyleneoxymethylene)]bis[oxirane]
2-Propanol Isopropanol 67-63-0 22 ~ 22.9
Xylene Dimethylbenzene 1330-20-7 10 ~ 11.1
Toluene Methylbenzene 108-88-3 9 ~ 9.6
4-Methyl-2-pentanone Methylisobutyl ketone, MIBK 108-10-1 7 ~ 7.8
Ethylbenzene Benzene, ethyl- 100-41-4 1 ~ 1.9
Secret Secret 자료없음 0~1

4. FIRST AID MEASURES

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 A. Eye contact
- Do not rub your eyes.
- Immediately flush eyes with plenty of water for at least 15 minutes and call a doctor/physician.
- Get medical attention immediately.
- Go to the hospital immediately if symptoms(flare, irritate) occur.
- Remove contact lenses if worn.

B. Skin contact
- Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
- Wash contaminated clothing thoroughly before re-using.
- Get medical attention immediately.
- Go to the hospital immediately if symptoms(flare, irritate) occur.
- Wash thoroughly after handling.

C. Inhalation contact
- When exposed to large amounts of steam and mist, move to fresh air.
- Take specific treatment if needed.
- Get medical attention immediately.
- If breathing is stopped or irregular, give artificial respiration and supply oxygen.

D. Ingestion contact
- Please be advised by doctor whether induction of vomit is demanded or not.
- Rinse your mouth with water immediately.
- Get medical attention immediately.
- If swallowed, large amounts of water to drink and do not induce vomiting.

E. Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available

F. Notes to physician
- Notify medical personnel of contaminated situations and have them take appropriate protective measures.
- If exposed or concerned, get medical attention/advice.

5. FIREFIGHTING MEASURES
A. Suitable (Unsuitable) extinguishing media
- Dry chemical, carbon dioxide, regular foam extinguishing agent, spray
- Avoid use of water jet for extinguishing

B. Specific hazards arising from the chemical

- Not available

C. Special protective actions for firefighters

- Notify your local firestation and inform the location of the fire and characteristics hazard.
- Avoid inhalation of materials or combustion by-products.
- Do not approach the tank surrounded by fire until it is extinguished.
- Use appropriate extinguishing measure suitable for surrounding fire.
- Wear appropriate protective equipment.
- Keep containers cool with water spray.
- Vapor or gas is burned at distant ignition sources can be spread quickly.
- Due to the extremely low flash point, irrigating fire extinguishing may be less effective when put out a fire.

6. ACCIDENTAL RELEASE MEASURES

A. Personal precautions, protective equipment and emergency procedures
- Wear proper personal protective apparatus as indicated in Section 8 and avoid skin contact and inhalation.
- Ventilate closed spaces before entering.
- Must work against the wind, let the upwind people to evacuate.
- Move container to safe area from the leak area.

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 - Do not direct water at spill or source of leak.
- Avoid skin contact and inhalation.
- Cleanup and disposal under expert supervision is advised.
- Keep unauthorized people away,isolate hazard area and deny entry.

B. Environmental precautions
- Prevent runoff and contact with waterways, drains or sewers.
- If large amounts have been spilled, inform the relevant authorities.

C. Methods and materials for containment and cleaning up

- Large spill : Stay upwind and keep out of low areas. Dike for later disposal.
- Notify the central and local government if the emission reach the standard threshold.
- Disposal of waste shall be in compliance with the Wastes Control?Act
- Appropriate container for disposal of spilled material collected.
- Small leak: sand or other non-combustible material, please let use absorption.
- Wipe off the solvent.
- Dike for later disposal.
- Do not use plastic containers.

7. HANDLING AND STORAGE

A. Precautions for safe handling
- Since emptied containers retain product residue(vapor, liquid, solid) follow all MSDS and label warnings even after container is emptied.
- Avoid contact with incompatible materials.
- Get the manual before use.
- Do not handle until all safety precautions have been read and understood.
- Do not inhale the steam prolonged or repeated.
- Avoid contact with heat, sparks, flame or other ignition sources.
- Contaminated work clothing should not be allowed out of the workplace.

B. Conditions for safe storage, including any incompatibilities

- Do not use damaged containers.
- Do not apply any physical shock to container.
- Avoid direct sunlight.
- Keep in the original container.
- Keep sealed when not in use.
- By specifying a storage area for carcinogenic substances.
- Collected them in sealed containers.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

A. Exposure limits
○ ACGIH TLV
- [2-Propanol] : TWA, 200 ppm (491 mg/m3), STEL, 400 ppm (984 mg/m3)
- [Xylene] : TWA 100 ppm (434 mg/m3), STEL, 150 ppm (651 mg/m3)
- [Toluene] : TWA 20 ppm (75 mg/m3)
- [4-Methyl-2-pentanone] : TWA, 20 ppm (82 mg/m3) STEL 75 ppm (307 mg/m3)
- [Ethylbenzene] : TWA, 20 ppm (87 mg/m3)
- [Secret] : TWA, 200 ppm (262 mg/m3) STEL, 250 ppm (328 mg/m3) Skin
○ OSHA PEL
- [Ethylbenzene0]:100ppm 435mg/m3
- [4-Methyl-2-pentanone0]:100ppm 410mg/m3
- [2-Propanol0]:400ppm 980mg/m3
- [Secret1]:200ppm 260mg/m3
- [Toluene1]: 200 ppm, C 300 ppm
- [Xylene1]:100ppm 435mg/m3

B. Engineering controls

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 - Business owner is recommended to maintain below recommended exposure limits for the working place with general exhaust of
gas/vapour/mist/fume.

C. Individual protection measures, such as personal protective equipment

○ Respiratory protection
- Respiratory protection is ranked in order from minimum to maximum.
- Consider warning properties before use.
- Any chemical cartridge respirator with organic vapor cartridge(s).
- Any chemical cartridge respirator with a full facepiece and organic vaporcartridge(s).
- Any air-purifying respirator with a full facepiece and an organic vapor canister.
- For Unknown Concentration or Immediately Dangerous to Life or Health : Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a
full facepiece.
- Under conditions of frequent use or heavy exposure, Respiratory protection may be needed.
○ Eye protection
- Wear primary eye protection such as splash resistant safety goggles with a secondary protection face shield.
- Provide an emergency eye wash station and quick drench shower in the immediate work area.
○ Hand protection
- Wear appropriate chemical resistant glove.
○ Skin protection
- Wear appropriate chemical resistant protective clothing.
○ Others
- Not available

9. PHYSICAL AND CHEMICAL PROPERTIES

A. Appearance
- Appearance Liquid(Viscous liquid)
- Color Clear
B. Odor Solvent odor
C. Odor threshold Not available
D. pH Not available
E. Melting point/Freezing point Not available
F. Initial Boiling Point/Boiling Ranges Not available
G. Flash point 12 ℃
H. Evaporation rate Not available
I. Flammability(solid, gas) Not available
J. Upper/Lower Flammability or explosive limits 01월 14일
K. Vapour pressure Not available
L. Solubility Not available
M. Vapour density > 1(Air=1)
N. Specific gravity(Relative density) 0.91 ~ 0.97
O. Partition coefficient of n-octanol/water Not available
P. Autoignition temperature 399
Q. Decomposition temperature Not available
R. Viscosity Not available
S. Molecular weight Not available

10. STABILITY AND REACTIVITY

A. Chemical Stability
- This material is stable under recommended storage and handling conditions.

B. Possibility of hazardous reactions

- Cylinders exposed to fire may vent and release flammable gas.

C. Conditions to avoid
- Avoid contact with incompatible materials and condition.
- Avoid : Accumulation of electrostatic charges, Heating, Flames and hot surfaces

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 - Avoid contact with heat, sparks, flame or other ignition sources.

D. Incompatible materials
- Not available

E. Hazardous decomposition products

- May emit flammable vapour if involved in fire.

11. TOXICOLOGICAL INFORMATION

A. Information on the likely routes of exposure
○ (Respiratory tracts)
- May be fatal if swallowed and enters airways
- May cause respiratory irritation.
○ (Oral)
- May harmful if swallowed.
○ (Eye·Skin)
- Causes serious eye irritation
- Causes skin irritation

B. Delayed and immediate effects and also chronic effects from short and long term exposure
○ Acute toxicity
* Oral
- Product (ATEmix) : 2000mg/kg < ATEmix <= 5000mg/kg
- [4,4'-(1-Methylethylidene)bisphenol polymer with 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane]] : LD50 > 2000
㎎/㎏ Rat (Dow Chemical)
- [2-Propanol] : LD50 5840 ㎎/㎏ Rat (OECD TG 401, ECHA)
- [Xylene] : LD50=3523 mg/kg Rat (EU Method B1) (ECHA)
- [Toluene] : LD50 5580 ㎎/㎏ Rat (EU Method B.1) (ECHA)
- [4-Methyl-2-pentanone] : LD50 2080 ㎎/㎏ Rat (NITE, ECHA)
- [Ethylbenzene] : LD50 = 3500 ㎎/㎏ Rat (ECHA, HSDB)
- [Secret] : LD50 = 8000 mg/kg (8ml/kg) Rat (NLM)
- [Secret] : LD50 6200 ㎎/㎏ Rat (EHC)
* Dermal
- Product (ATEmix) : >5000mg/kg
- [4,4'-(1-Methylethylidene)bisphenol polymer with 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane]] : LD50 > 2000
㎎/㎏ Rabbit (Dow Chemical)
- [2-Propanol] : LD50 16400 ㎎/㎏ Rabbit (OECD TG402, ECHA)
- [Xylene] : LD50 ≥1,700mg/kg Rabbit (NIER)
- [Toluene] : LD50 >5000 ㎎/㎏ Rabbit (ECHA)
- [4-Methyl-2-pentanone] : LD50 >16,000 ㎎/㎏ rabbit (NITE)
- [Ethylbenzene] : LD50 = 15400 ㎎/㎏ Rabbit (ECHA, ChemIDPlus)
- [Secret] : LD50 6300 ㎎/㎏ rabbit (6.3 ml/kg, NLM)
- [Secret] : LD50 15800 ㎎/㎏ rabbit (NLM: ChemIDPlus)
* Inhalation
- Product (ATEmix) : 10.0mg/L < ATEmix <= 20.0mg/L
- [2-Propanol] : LC50 >10000 ppm 6 hr Rat (OECE TG 403, GLP)
- [Xylene] : Vapor LC50 = 10 ~ 20 mg/L/4hr (NIER)
- [Toluene] : LC50 >20 ㎎/ℓ Rat (OECD TG 403) (ECHA)
- [4-Methyl-2-pentanone] : vapor LC50 8.2 ~ 16.4 ㎎/ℓ 4h Rat (ECHA)
- [Ethylbenzene] : Vapor LC50 17.8 mg/L 4 hr Rat (conversion value of 4000 ppm) (ECHA, HSDB)
- [Secret] : LC50 83.9 mg/L/4 hr Rat (NLM: ChemIDPlus)
○ Skin corrosion/irritation
- Causes skin irritation
○ Serious eye damage/irritation
- Causes serious eye irritation
○ Respiratory sensitization
- Not available
○ Skin sensitization

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 - Not available
○ Carcinogenicity
* IARC
- [Ethylbenzene0] : Group 2B
- [4-Methyl-2-pentanone0] : Group 2B
- [2-Propanol0] : Group 3
- [Toluene0] : Group 3
* OSHA
- Not available
* ACGIH
- [Ethylbenzene0] : A3
- [4-Methyl-2-pentanone0] : A3
- [2-Propanol0] : A4
- [Toluene0] : A4
- [Xylene0] : A4
* NTP
- Not available
* EU CLP
- Not available
○ Germ cell mutagenicity
- Not available
○ Reproductive toxicity
- Suspected of damaging fertility or the unborn child
○ STOT-single exposure
- May cause damage to organs (Refer Section SDS 11)
- May cause drowsiness and dizziness.
- May cause respiratory irritation.
○ STOT-repeated exposure
- Causes damage to organs through prolonged or repeated exposure (Refer Section SDS 11)
○ Aspiration hazard
- May be fatal if swallowed and enters airways

12. ECOLOGICAL INFORMATION

A. Ecotoxicity
○ Fish
- [2-Propanol] : LC50 9640 ㎎/ℓ 96 hr Pimephales promelas(OECD Guideline 203)
- [Xylene] : LC50=3.3mg/L 96 hr (NITE)
- [Toluene] : LC50 5.5 ㎎/ℓ 96 hr Oncorhynchus kistutch (ECHA)
- [4-Methyl-2-pentanone] : ECHA LD50 >179 ㎎/ℓ 96 hr Brachydanio rerio (ECHA)
- [Ethylbenzene] : LC50 5.1 ㎎/ℓ 96 hr (ECHA)
- [Secret] : LC50 49.738 ㎎/ℓ 96 hr (Estimate)
- [Secret] : LC50 15400 ㎎/ℓ 96 hr Bluegill (NITE: EHC 196, 1998)
○ Crustaceans
- [2-Propanol] : ECHA LC50 5102 ㎎/ℓ 24 hr Daphnia magna(OECD TG 202)
- [Xylene] : LC50 3.6 ㎎/ℓ 24 hr (OECD TG202) (ECHA)
- [Toluene] : EC50 3.78mg/L 48hr (ECHA)
- [4-Methyl-2-pentanone] : ECHA EC50 >200 ㎎/ℓ 48 hr Daphnia magna (ECHA)
- [Ethylbenzene] : LC50 1.8 ㎎/ℓ ~ 2.4 ㎎/ℓ 48 hr Mysidopsis bahia(EC50 48hr >5.2mg/L, EPA 1985, GLP)
- [Secret] : LC50 67.079 ㎎/ℓ 48 hr (Estimate)
- [Secret] : LC50 1340 mg/L Brown shrimp (NITE: EHC 196, 1998)
○ Algae
- [2-Propanol] : EC50 = 2.2 ㎎/ℓ 96 hr
- [Xylene] : ErC50 4.06 ㎎/ℓ 73 hr (OECD TG201, GLP) (ECHA)
- [Ethylbenzene] : EC50 3.6 ㎎/ℓ 96 hr (EPA 1985, GLP)
- [Secret] : ECHA EC50 22000 ㎎/ℓ 96 hr Selenastrum capricornutum(OECD TG 201)

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 B. Persistence and degradability
○ Persistence
- [Xylene] : log Kow=3.16 (NITE)
- [Toluene] : 2.73 log Kow (20 °C) (ECHA)
- [4-Methyl-2-pentanone] : log Kow 1.9 (ECHA)
- [Ethylbenzene] : log Kow 3.15 (ECHA)
- [Secret] : log Kow -0.77
○ Degradability
- [2-Propanol] : (BOD5/COD ratio ≥ 0.5, biodegrades immediately, EU Method C.5)

C. Bioaccumulative potential
○ Bioaccumulative potential
- [Xylene] : BCF25.9 (ECHA)
- [Ethylbenzene] : BCF 1
○ Biodegradation
- [2-Propanol] : (biodegrades immediately, EU Method C.5)
- [Xylene] : 90 % 28 day (OECD TG301F, GLP)(ECHA)
- [Toluene] : 80 % 20 day (Readily biodegradable) (ECHA)
- [4-Methyl-2-pentanone] : 83% 28 day (ECHA)
- [Ethylbenzene] : 70-80% 28 day (ISO 14593 CO2, GLP)

D. Mobility in soil
- [2-Propanol] : log koc= 0.03
- [Xylene] : log Kow = 3.12 (measured) (ortho), 3.2 (measured) (meta), 3.15 (measurements) (p) (5)
- [4-Methyl-2-pentanone] : Koc 101.85 (Estimate)
- [Ethylbenzene] : log koc= 2.41, measured (ECHA)

E. Other adverse effects

- Not available

13. DISPOSAL CONSIDERATIONS

A. Disposal methods
- Stabilization and minimization treatment by incineration or similar method can be applied, if more than two kinds of designated wastes are in
mixture state and it is impractical to separate them
- Oil water separation technology shall be applied as pre-waste treatment if it is applicable
- It shall be treated by incineration

B. Special precautions for disposal

- Anyone with business license number who generates industrial wastes shall treat the waste by him/herself or by entrusting to the legal entities who
treat the wastes, recycle the wastes of others or install and operate the waste treatment facilities according to the Wastes Control Act

- Dispose of waste in accordance with all applicable laws and regulations.

14. TRANSPORT INFORMATION

A. UN No. (IMDG)
- 1263

B. Proper shipping name

- PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH, POLISH, LIQUID FILLER, AND LIQUID
LACQUER BASE

C. Hazard Class
-3

D. IMDG Packing group

-Ⅱ

E. Marine pollutant
- Not applicable

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 F. Special precautions for user related to transport or transportation measures
- Local transport follows in accordance with Dangerous goods Safety Management Law.
- Package and transport follow in accordance with Department of Transportation (DOT) and other regulatory agency requirements.
- Air transport(IATA): This product is NOT classified as dangerous for IATA Transport.
- EmS FIRE SCHEDULE : F-E (Non-water-reactive flammable liquids)
- EmS SPILLAGE SCHEDULE : S-E (Flammable liquids, floating on water)

15. REGULATORY INFORMATION

A. National and/or international regulatory information
○ POPs Management Law
- Not applicable
○ Information of EU Classification
* Classification
- [Toluene] : H225,H361d,H304,H373,H315,H336
- [Xylene] : H226,H332,H312,H315
- [Ethylbenzene] : H225,H332
- [Secret1] : H225,H331,H311,H301,H370
- [2-Propanol] : H225,H319,H336
- [4-Methyl-2-pentanone] : H225,H332,H319,H335
○ U.S. Federal regulations
* OSHA PROCESS SAFETY (29CFR1910.119)
- Not applicable
* CERCLA Section 103 (40CFR302.4)
- [Xylene] : 45.3599 kg 100 lb
- [Toluene] : 453.599 kg 1000 lb
- [4-Methyl-2-pentanone] : 2267.995 kg 5000 lb
- [Ethylbenzene] : 453.599 kg 1000 lb
- [Secret] : 2267.995 kg 5000 lb
* EPCRA Section 302 (40CFR355.30)
- Not applicable
* EPCRA Section 304 (40CFR355.40)
- Not applicable
* EPCRA Section 313 (40CFR372.65)
- [2-Propanol] : Applicable
- [Xylene] : Applicable
- [Toluene] : Applicable
- [4-Methyl-2-pentanone] : Applicable
- [Ethylbenzene] : Applicable
- [Secret] : Applicable
○ Rotterdam Convention listed ingredients
- Not applicable
○ Stockholm Convention listed ingredients
- Not applicable
○ Montreal Protocol listed ingredients
- Not applicable

16. OTHER INFORMATION

A. Reference
- The information contained herein is believed to be accurate. It is provided independently of any sale of the product for purpose of hazard
communication. It is not intended to constitute performance information concerning the product. No express warranty, or implied warranty of
merchantability or fitness for a particular purpose is made with respect to the product or the information contained herein.
- This Safety Data Sheet was compiled with data and information from the following sources: KOSHA, NITE, ESIS, NLM, SIDS, IPCS

B. Issue date
- 2015-12-14

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C. Revision number and Last date revised
- 4 times, 2020-06-22

D. Other
- This SDS is prepared according to the Globally Harmonized System (GHS).

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