Given data
The volume of water filled in the vessel is V0 = 1 litre = 100 ×10-6 m3.
The temperature of water initially is Ti = 20oC.
The temperature attained by water finally is Tf = 90oC.
The formula to show the change in volume is,
V Vw Vp ......(i)
Where, the increment in volume of water is ΔVw and the increment in volume of Pyrex vessel is ΔVp.
The change in the volume of water is,
Vw wV0 T
Where, V0 is the volume at initial state, βw is the coefficient of expansion of water which is 207 ×10 -6 K-1
and ΔT is the change in temperature.
The change in volume of Pyrex vessel is,
Vp pV0 T
Where, βp is the coefficient of expansion of Pyrex which is given as 9 ×10 -6 K-1 .
Substitute the known expressions in equation (i).
V wV0 T pV0 T
V V0 T w Bp
V V0 Tfi T w Bp
Substitute values in the equation.
V 100 10 6 m3 90C 273 K 20C 273 K 207 10 6 K -1 9 10 6 K -1
V 1.386 10 6 m3
Thus, the volume of water that overflows through the vessel is 1.386 ×10 -6 m3.