SCHOOL OF HEALTH AND ALLIED HEALTH SCIENCES

COLLEGE OF PHARMACY
CHE 029: ANALYTICAL CHEMISTRY (QUALITATIVE & QUANTITATIVE) SET C
FINAL EXAM
S.Y. 2018-2019
Name: ___________________________________________________ b. 36.117%
Date: _______________________________________________
Schedule: _______________________________________________ c. 37.117%
Score: ______________________________________________

INSTRUCTIONS: Write your name on your test questionnaire and answer sheet. Write the letter of your answer before each number
and shade the letter on the corresponding answer sheet. Pass the test questionnaire and answer sheet together after answering. NO
ERASURE IN ALL ITEMS!

1-3. How may mL of 0.2214N of Ammonium Thiocyanate was

used if it is standardized by a 20mL of 0.09912N of Silver
Nitrate. d. 38.117%
a. 7.34mL
b. 8.95mL 22. The term ____________________usually refers to methods in
c. 7.3mL which the stimulus is heat or electrical energy Coupling
d. 10.3mL a. Emission spectroscopy
b. Decomposition
4-6. 4 grams of Sodium Bicarbonate was called in for a c. Electrophoresis
quantitative analysis, wherein during the assay the it d. Refractometry
required 27.1mL of 1.182N of the titrant to reach to the End
point. 23. A type of spectroscopic analysis wherein the emission of
a. 67.27% photons is measured following absorption…
b. 69.56% a. Fluorescence spectroscopy
c. 72.14% b. Phosphorescence spectroscopy
d. 87.14% c. Chemiluminescence spectroscopy
d. Photoluminescence spectroscopy
7-9. Three grams of Calcium Chloride was Assayed
Volumetrically wherein it was first added with 50mL of 24. A vector whose length is proportional to the field
Silver Chloride(0.1192N) then the Excess titrant was strength…
Titrated with Ammonium Thiocyanate (0.1211N) and a. Radiation
required 15ml to reach to End Point, What is the b. Oscillation
Concentration of the Sample? c. Electric field
a. 3.91% d. Electromagnetic spectrum
b. 4.5%
c. 7.60% 25. This type of spectroscopy refers to excitation of the
d. 9.91% analyte by a chemical reaction.
a. Absorption spectroscopy
10-12. How much volume is needed to reach to the End Point b. Fluorescence spectroscopy
if, a Four gram sample of Magnesium Hydroxide c. Chemiluminescence spectroscopy
was(9.829%) required 50mL of 1.1182N Sulfuric acid and d. Emission spectroscopy
the excess Acid will be titrated with 1.0912N Sodium
Hydroxide. 26. Globar source of light can be used for…
a. 38.8ml a. [Link] spectroscopy
b. 39.8ml b. UV spectroscopy
c. 40.8ml c. NMR spectroscopy
d. 41.8ml d. Vis Light spectroscopy

13-15. Sodium hydroxide (39.53%) was asked for an 27. It represented by the different regions shown in the
analysis, how much Volume of the titrant is needed to reach electromagnetic spectrum wherein it covers an enormous
to the End point if 6 grams of the sample was taken to be range of energies…
titrated with 0.994N Sulfuric Acid. a. Photometric spectrum
a. 39.5mL b. Electron Spin Resonance
b. 50.3mL c. Electromagnetic radiation
c. 59.65mL d. Nuclear magnetic resonance
d. 67.43mL
28. A type of quantum change that occurs when an analyte is
16-18. Sulfuric Acid was called in for standardization exposed to Nuclear Magnetic Resonance (NMR)…
wherein, 23mL of the volume of the solution was required a. Change of spin
110mg of the Sodium Carbonate Primary standard for b. Change of orientation
standardization. what is the concentration of the solution. c. Change of configuration
a. 0.03N d. Change of electron distribution
b. 0.09N
c. 0.18N 29. A type of quantum change that occurs when an analyte is
d. 0.045N exposed to Infrared energy…
a. Change of spin
19-21. Five grams of Lactic Acid (C 3H6O3) was called in for b. Change of orientation
analysis using titration. wherein 40mL of 1.201N Sodium c. Change of configuration
Hydroxide was added then the Excess Base was titrated with d. Change of electron distribution
25mL of 1.119N of Sulfuric acid to reach to the End point.
What is the Concentration of the Sample. (F=1) 30. A type of quantum change that occurs when an analyte is
a. 35.117% exposed to Visible Light …
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CHE 029: ANALYTICAL CHEMISTRY (QUALITATIVE & QUANTITATIVE)
a. Change of spin 40. Using an FTIR spectrometer a peak detected at the wave
b. Change of orientation number of 1300 – 1180 detects the presence of…
c. Change of configuration a. O-H
d. Change of electron distribution b. C=O
c. ɸ-O-R
31. In the analysis of the absorption spectra for colored d. COOH
samples, if the complementary color transmitted of a sample
is Green-Blue, the color of the light absorbed is Red, at which 41. Using an FTIR spectrometer a peak detected at the wave
wavelength range should it be detected… number of 2260 – 2100 detects the presence of …
a. 400 – 435 nm a. Nitrile
b. 435 – 480 nm b. Alkyne
c. 480 – 490 nm c. Ketones
d. 650 – 750 nm d. Aromatic alkanes

32. In the analysis of the absorption spectra for colored 42. The temperature conditions utilized in Flame
samples, if the complementary color transmitted of a sample atomization method…
is Purple, the color of the light absorbed is Green at which a. 1700– 3150oC
wavelength range should it be detected… b. 6000 – 8000oC
a. 500 – 560 nm c. 1200 – 2000oC
b. 435 – 480 nm d. 5000 – 10000oC
c. 480 – 490 nm
d. 490 – 500 nm 43. The temperature conditions utilized in Direct Current –
Plasma atomization method…
33. In the analysis of the absorption spectra for colored a. 6000 – 8000oC
samples, if the complementary color transmitted of a sample b. 1700– 3150oC
is BLUE, the color of the light absorbed is YELLOW, at which c. 1200 – 2000oC
wavelength range should it be detected… d. 5000 – 10000oC
a. a.400– 435 nm
b. 580 – 595 nm 44. Which of the following sources can utilize the lowest
c. 595 – 650 nm wavelength?
d. 500 – 560 nm a. Globar lamps
b. Tungsten lamps
34. The wavelength range for Tungsten lamp … c. Xenon arc lamps
a. 350 – 2200 nm d. H2 and D2 lamps
b. 400 – 20,000 nm
c. 750 – 20,000 nm 45. Which of the following can be utilized for molecular
d. 1200 – 40,000 nm fluorescence?
a. Globar
35. The wavelength range for Globar … b. Nernst glower
a. a.350 – 2200 nm c. Xenon arc lamps
b. 400 – 20,000 nm d. H2 and D2 lamps
c. 750 – 20,000 nm
d. 1200 – 40,000 nm 46. Method of analysis wherein measure the amount of light
absorbed as a function of wavelength …
36. A part of the spectrophotometer that holds the sample… a. Emission spectroscopy
a. Detector b. Absorption spectroscopy
b. Sample container c. Fluorescence spectroscopy
c. Wavelength selector d. Chemiluminescence spectroscopy
d. Spectroscopic source
47-49. Compute for the concentration of an unknown
37. A part of the spectrophotometer that utilizes optical solution (X), with an absorbance value of 0.8123.
materials and must transmit radiation in the wavelength Solution conc ABS
region being investigated…
30 ppm 0.5812
a. Detector
b. Sample container 50 ppm 0.6251
c. Wavelength selector 75 ppm 0.7021
d. Spectroscopic source
X 0.8123
38. The sample container which can cater to a wavelength of 95 ppm 0.9983
150– 7000 nm…
a. 75.63 ppm
a. LiF
b. 76.63 ppm
b. Corex glass
c. 85.63 ppm
c. Silicate glass
d. 86.63 ppm
d. Fused silica / quartz
50-51. A blue-colored sample with a concentration of
0.00001 mol/L is analyzed by a spectrometer using a 1cm
39. Using an FTIR spectrometer a peak detected at the wave
cuvette and yielded an absorbance of 1.982. Compute for the
number of 1720 – 1640 detects the presence of …
Molar Absorptivity Coefficient…
a. Amides
a. 192,200 Lmol-1cm-1
b. Aliphatic ketones
b. 194,200 Lmol-1cm-1
c. Aromatic alkenes
c. 196,200 Lmol-1cm-1
d. Aliphatic and aromatic hydroxyl
d. 198,200 Lmol-1cm-1
 COLLEGE OF PHARMACY
CHE 029: ANALYTICAL CHEMISTRY (QUALITATIVE & QUANTITATIVE)
52-53. An unknown solution of Egg albumin is analyzed c. 4 mL
using a 4cm cuvette by spectrophotometric analysis. The d. 5 mL
absorbance value of the analyte was 0.872 at 390 nm.
Compute for the concentration of the analyte if the Molar 64. The minimum volume capacity of a cuvette for analysis…
Absorptivity Coefficient is 39,000 M-1cm-1… a. 0.5 mL
a. 5.5897 x 10-6 b. 1.0 mL
b. 6.5897 x 10-7 c. 1.5 mL
c. 7.5897 x 10-8 d. 2.0 mL
d. 6.5897 x 10-5
65. Fraction of incident radiation absorbed by the material
54. The part of the spectrophotometer that controls the over a range of frequencies…
amount or intensity of energy to be applied to a sample… a. Lambda max
a. Readout b. Blank solution
b. Detector c. Absorbance spectrum
c. Power switch d. Transmittance spectrum
d. Wavelength selector
66. A solution containing little to no analyte of interest,
55. An accessory of the spectrophotometer that is used as the usually used to calibrate instruments such as a colorimeter…
sample receptacle for analysis… a. Analyte
a. Cuvette b. Blank solution
b. Digital display c. Standard solution
c. Cell compartment d. Calibration standard
d. Wavelength selector
67. A general method for determining the concentration of a
56. The molar absorptivity coefficient of aqueous methylene substance in an unknown sample by comparing the
blue… unknown to a set of standard samples of known
a. 95,000 M cm-1 -1 concentration…
b. 48,000 M-1cm-1 a. Beer’s law
c. 95,000 L/mol-1cm-1 b. Linear regression analysis
d. 48,000 L/mol cm-1 -1 c. Calibration standard curve
d. Molar Absorptivity Coefficient
57. The wavelength utilized for the analysis of aqueous
Methylene blue sample… 68. Which of the following conditions will affect the analysis
a. 670 nm of a sample in spectrophotometric analysis?
b. 595 nm a. Opaque cuvette
c. 390 nm b. Air-conditioned room
d. 450 nm c. Room lights are turned on
d. Controlled room temperature
58. The light source of the spectrophotometer is made of…
a. W lamp 69. The λmax of egg albumin…
b. Nernst glower a. 450 nm
c. H2 and D2 lamp b. 670 nm
d. Nichrome wire c. 390 nm
d. 595 nm
59. Colored samples are analyzed under…
a. Far UV 70. The indicator utilized in the determination of protein
b. Infrared content…
c. Near UV a. Methyl red
d. Visible light b. Gentian violet
c. Coomasie blue
60. The color of Coomasie blue without the presence of d. Malachite green
proteins…
a. Brick red 71. The relationship between the intensity of the color of
b. Light pink samples and concentration in spectrophotometric analysis…
c. Dark green a. Direct correlation
d. Brilliant blue b. Indirect correlation
c. Directly proportional
61. Cuvettes are made up of this type of material… d. Inversely proportional
a. Quartz
b. Silica gel 72. The other names of oxygen, EXCEPT…
c. Amber glass a. Dephlogisticated air
d. Borosilicate glass b. Acid former
c. Fire air
d. Water former
62. The blank solution used in the analysis of methylene
blue… 73. A non-essential ion that can be consumed using antacid
a. Alcohol which may result to renal failure, abnormal bone or osteoid
b. Distilled water formation…
c. Methylene blue a. Ni
d. Methylene blue in alcohol b. Ca
c. Be
63. The maximum volume capacity of a cuvette for analysis… d. Al
a. 2 mL
b. 3 mL
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CHE 029: ANALYTICAL CHEMISTRY (QUALITATIVE & QUANTITATIVE)
74. An ion/element which is considered to be the poison of 84. The positive result for the flame test of Sodium…
kings. a. Blue
a. Al b. Violet
b. Si c. Red
c. As d. Yellow
d. Sb
85. Potassium pyroantimonate…
75. It can be differentiated with magnesium using a. K2H2Sb2O7
Quinalizarin with bromine water producing a persistent blue b. K3H3Sb2O7
color and it is the most toxic metal of group IIA… c. KH2Sb2O7
a. Be d. KHC4H4O6
b. As
c. Cd 86. Tartaric acid is correctly written as…
d. Ni a. HC6H4O6
b. HC2H3O2
[Link] of this metal, if it is still in the GI, utilizes freshly c. H2C 4H4O6
prepared Iron (III) and Magnesium hydroxide for the d. H2C 6H5O7
management…
a. Ni 87. The color of the product of reactants NaCl + Potassium
b. Cd pyroantimonate…
c. As a. No reaction
d. Sb b. Yellow solution
c. White precipitate
77. This metal can be found in gasoline, water pipes and d. Yellow precipitate
constant exposure on these sources may cause a cumulative
toxicity that result to impaired growth and mental 88. The color of the product of reactants Lithium chloride
development… and Sodium cobaltinitrite…
a. Cd a. No reaction
b. Pb b. Yellow solution
c. Hg c. White precipitate
d. Tl d. Yellow precipitate

78. A toxic metal that is used in thermometers … 89. The color of C6H4OHCOOLi….
a. Tl a. White
b. Cd b. Yellow
c. Hg c. Green
d. Ag d. Colorless

79. The compound of this metal can be used to treat 90. Which of the following reagents will cause a result of
rheumatoid arthritis and Lupus … yellow color solution with Sodium ion?
a. Sn a. Picric acid
b. Al b. Cobaltinitrite
c. Au c. Cobaltinitrate
d. Sb d. Magnesium uranyl acetate

80. A volatile metal that is responsible for the ‘minamata’ 91. Which of the following is not included in the test for
disease which is manifested with brittle bones, spinal and leg sodium bicarbonate tablet?
pain, anemia and kidney failure… a. Magnesium uranyl acetate
a. Cd b. Potassium pyroantimonate
b. Zn c. Flame test
c. Hg d. None of the above
d. Ag
92. The positive result for the flame test of Magnesium …
81. A noble metal that is use in making coins, ornaments , a. Red
jewelry and can be precipitated with hydrochloric acid… b. Blue
a. Sn c. Colorless
b. Au d. Yellow Green
c. Ag
d. Sb 93. Compared to a p orbital, a d orbital can contain maximum
of…
82. Dimercaprol is the antidote of choice of this metal a. 2 electrons
toxicity but Penicillamine can also be given to mobilize its b. 5 electrons
toxic metabolite to the urine… c. 10 electrons
a. Pb d. 6 electrons
b. Hg
c. Sb 94. Which is the ground state electron configuration of a
d. Tl phosphorous atom (Z=15) ?
a. 1s22s22p63s23p3
83. The chemical formula for magnesium uranyl acetate… b. 1s22s22p53s13p5
a. C8H12MgO10 c. 1s22s22p53s23p3
b. C6H10MgO8 d. 1s22s32p63s13p4
c. C10H14MgO12
d. C4H6MgO8 95. An elemental form which has same mass number but
with slight difference in atomic number …
 COLLEGE OF PHARMACY
CHE 029: ANALYTICAL CHEMISTRY (QUALITATIVE & QUANTITATIVE)
a. isotopes a. Interstitial
b. isobars b. Cytoplasm
c. isotones c. Vascular
d. nuclides d. Plasma

96. Where can electrons be located? 107. Measures the current and the time needed to complete
a. inside the nucleus an electro chemical reaction…
b. both inside and outside nucleus a. Coulometry
c. outside the nucleus b. Potentiometry
d. Cannot be determined c. Voltammetry
d. Gravimetry
97. The atomic number of an element indicates the number
of ______________ in the atom. 108. Which of the following essential ion is associated to
a. Protons and neutrons moon and used in glass industry imparting red color, and its
b. protons and electrons antioxidant activity is enhanced with vitamin E?
c. neutrons and electrons a. Cobalt
d. electrons only b. Zinc
c. Iodine
98. One of the following is the shape of the s orbital… d. Selenium
a. Spherical
b. Dumbell 109. Below are use or activity of magnesium and magnesium
c. X-shaped salts, EXCEPT…
d. Complex a. Depressant
b. Anti-diarrheal
99. One of the following is physical changes, EXCEPT… c. Anticonvulsant
a. Melting of candle wax d. Anti-hypertensive agent
b. Breaking of glass
c. Distillation of water 110. An excess of calcium in the body can lead to…
d. Rusting or Iron a. Systolic arrest
b. Diastolic arrest
100. Which of the following is a mixture? c. Impair action potential
a. 10% sugar solution d. Decrease blood clotting time
b. CO2
c. Diamond 111. Phosphates are located primarily in the following,
d. Table salt EXCEPT…
a. Nucleic acid
b. Phosphoproteins
101. He is the one who developed the ‘Planetary Model’ of
c. Endoplasmic reticulum
atom in which he proposed that atom is composed of nucleus
d. Hydroxyapatite in bone
and electrons travelling in circular orbits.
a. Niels Bohr
112. The color of Calcium sulfate salt…
b. Ernest Rutherford
a. Red precipitate
c. Erwin Schrodinger
b. Yellow precipitate
d. Joseph John Thompson
c. White precipitate
d. Brown precipitate
102. It is a principle indicating that electrons must occupy all
the energy level first before pairing…
113 .If the solution containing calcium will be added with
a. Aufbau’s principle
oxalic acid, one of the following is the product produced…
b. Hund’s Rule of Multiplicity
a. CaSO4
c. Pauli’s exclusion principle
b. CaC2O4
d. Heisenberg’s uncertainty principle
c. CaCrO4
d. CaNH4PO4.6H2O
103. Drug level toxicity can be assayed by the following,
EXCEPT…
114. A reaction of calcium and oxalic acid will form this
a. GC
product….
b. ISE
a. Brick red ppt.
c. EMIT
b. Pale yellow solution
d. HPLC
c. white octahedral crystal
d. Fine white crystalline ppt.
104. The components of a sample that are to be determined…
a. Titrant
115. Sulfurous acid is chemically…
b. Titrand
a. H2SO4
c. Mobile phase
b. H2SO3
d. Indicator
c. H3SO4
d. H2S2O3
105. The method in the amplification of nucleic acids and
116. An azure blue end color indicates the presence of what
microorganism detection…
ion?
a. MS
a. Al
b. ISE
b. As
c. PCR
c. Cu
d. ELISA
d. Fe3+
106. Extracellular compartment includes the following,
117. If a solution is added with sulfuric acid with sodium
EXCEPT…
nitrite crystals and hydrochloric acid with a few drops of
 COLLEGE OF PHARMACY
CHE 029: ANALYTICAL CHEMISTRY (QUALITATIVE & QUANTITATIVE)
rhodamine produces a lavender color. What ion is likely 136-138. Eighty grams of Magnesium Carbonate was added
present? with Enough water to create 250mL solution. Determine the
a. Sb Concentration of the Sample.
b. Sn a. 8.0952N
c. Cd b. 4.0476N
d. As c. 16.1905N
d. 12.1428N
118. Which of the following is NOT member of II CATION?
a. Ag 139-141. An Accurately measured sample of Hydrogen
b. Pb Peroxide(3g) was placed on a flask that contains 20mL
c. Cu water, and Diluted Sulfuric acid. Wherein the said sample
d. Hg+1 consumed 28mL of 0.1121N Potassium Permanganate titrant
for its Titration. Determine the Concentration of the sample.
119. Potassium stannite is chemically written… mEq Weight: 0.017
a. KSnO3 a. 0.4447%
b. K2SnO2 b. 0.8893%
c. K2SnO4 c. 1.3340%
d. K3SnO2 d. 1.7787%

120. Which of the following will produce white gelatinous 142-144. A Magnesium Hydroxide solution was determined
precipitate? or standardized using volumetric analysis. Wherein 5g of
a. NH4OH Potassium Biphthalate required 29ml of the Analyte to be
b. Al(OH)3 Neutralized. What is the concentration of the Analyte.
c. CoO a. 0.8452N
d. MnO b. 1.6903N
c. 2.5355N
121. Which of the following produce a Turnball’s blue color? d. 3.3807N
a. K3Fe(CN)6
b. Fe3[Fe(CN)6]2 145-147. How much weight of the Silver Nitrate is needed to
c. K4Fe(CN)6 Create a 300ml solution of Silver Nitrate (0.1122N).
d. Fe4[Fe(CN)6]3 a. 2.8611g
b. 5.7222g
122-123. Determine the concentration of a five hundred mL c. 11.4444g
solution of the Sodium Chloride, if it required 35g of the d. 17.1666g
solute to create a Solution. Express the concentration in
Molarity. 148-150. A 200mg sample of Calcium Carbonate was
a. 0.6M Acidified and dissolved in a 500ml of solution. An aliquot of
b. 1.2M 50mL was taken from the solution and required 25mL of an
c. 2.4M EDTA solution for Titration. Find the Molarity of the EDTA
d. 4.8M solution.
a. 0.024M
124-126. Two hundred mL Solution of Sodium Carbonate b. 0.008M
Solution Required 85g of solute to create the Solution, c. 0.016M
Determine the Concentration of the Sample. d. 0.004M
a. 1M
b. 2M
c. .3M
Nothing follows…
d. 4M

127-129. During standardization of Sulfuric Acid Solution, a

115mg of Sodium Carbonate Standard required 19mL of the
solution to be Neutralized/ Reach the End Point. Determine
the Concentration of the Sulfuric acid.
a. 0.1142N
b. 0.1235N
c. 0.0618N ‘’ Believe in yourself and all that you are. Know
d. 0.0571N that there is, something inside you that is greater
than any obstacle.’’
130-132. Express the Concentration of a Sodium Hydroxide
if it required 120g of the solute, to Create a 500mL of the -C.D. Larson
solution.
a. 3N ‘’ Remember that the reason you’re doing this is
b. 9N
c. 6N to make your parents proud and to make your
d. 12N life better. ‘’
-Unknown
133-135. Twenty –five grams of Potassium Hydroxide was
added with Enough water to create a 500mL Solution,
Determine the concentration of the Solution.
a. 0.4464M
b. 0.8929M
c. 1.7857M
d. 2.6788M
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