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Anachem Lab

The document provides a schematic diagram for identifying Group III cations through a series of chemical tests. It lists the following cations: Al+3, Cr+3, Zn+2, Mn+2, Fe+2,Co+2, Ni+2. For each cation, it outlines the expected precipitation reactions, colors, or other results from adding reagents such as saturated ammonium chloride, concentrated ammonia, methylthiosemicarbazide, concentrated hydrochloric acid, concentrated nitric acid, or potassium hydroxide. The diagram then identifies which cations are present based on the observed results.

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Kaye Ibañez Castillo
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118 views3 pages

Anachem Lab

The document provides a schematic diagram for identifying Group III cations through a series of chemical tests. It lists the following cations: Al+3, Cr+3, Zn+2, Mn+2, Fe+2,Co+2, Ni+2. For each cation, it outlines the expected precipitation reactions, colors, or other results from adding reagents such as saturated ammonium chloride, concentrated ammonia, methylthiosemicarbazide, concentrated hydrochloric acid, concentrated nitric acid, or potassium hydroxide. The diagram then identifies which cations are present based on the observed results.

Uploaded by

Kaye Ibañez Castillo
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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SCHEMATIC DIAGRAM FOR GROUP III CATIONS

CATIONS III: Al+3, Cr+3, Zn+2, Mn+2, Fe+2,Co+2, Ni+2


+ SAT’D NH4Cl, + conc. NH3 + CH3CSNH2
P: Al(OH)3, Cr(OH)3, ZnS, MnS, Fe2S3, CoS, NiS
+ conc. HCl, +conc. HNO3, + 3F KOH, + NO2O2 C:
C: SUBFROUP IIIA P:
D
AlO3-3, CrO4, ZnO2 Fa(OH)3, Co(OH)2, Ni(OH)2, MnO(OH)2
+ NH4Ac, + 3R HAc, 3 F NH3
I

R: Al(OH)3 C: CrO4, Zn(NH3)4++


+ 3F HCl + 1F Ba (Ac)2 1s portion 2nd portion 3rd portion 4th portion
+ SAT’D + NaBiO3 +3F + NaF + NaF
NH4Ac NH4SCN +Alcoholic +3F NH3
R: BaCrO4 C:
+ NH4SCN +C4H8O2N2
& BaSO4 2n(NH3)4++
Ca2H23N3O8
+ 3F HCl + 3F HAc
+ 3F NH3
+H2O

-blue color -white ppt


Red ppt -reddish -deep red -blue green -red ppt
which
purple color color at
fades
color in junction of
rapidly supernatant 2 liquids
liquid

Al+3 is Cr+3 is Zn++ is Mn++ is Fe++ is Co++ is Ni++ is


present present present present present present present
SCHEMATIC DIAGRAM FOR GROUP II CATIONS

CATIONS II: Hg++, Cr+3, Zn+2, Mn+2, Fe+2,Co+2, Ni+2


+ SAT’D NH4Cl, + conc. NH3 + CH3CSNH2

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