Your Name: Bey Lab section; Chemistry 31 — Quantitative Analysis Exam #2, November 22, 2010 Multiple Choice and Short Answer Circle the one correct answer from the choices listed, enter the correct term or phrase on the blank line, or briefly answer the question as indicated. 1 (4 points). Which of the following expressions will give the pH of a solution: a. log(H"] (2) opeeskeltoHr c, -log(OH] 2 (4 points). Compared to a solution with a pH of 6, a solution with a pH of 3 has an (H’ J: a. that is the same. b. that is 100 greater. (© that is 1000 times greater. d. more information is required. 3 (4 points). ‘To a precision of 2 significant figures, what is the pH of a solution containing a concentration of 1.0x10"*M KOH? @10 b. 14 ©. 0.0 4. 1.0 44 points), When using a least squares linear regression, it is assumed that: a. errors in measured y values are insignificant relative to errors in x values. errors in x and y values are the same. ® errors in x values are insignificant relative to errors in measured y values d. No assumptions need to be made. 5 (4 points). Which of the following analytical methods would be most appropriate to analyze a mixture containing analytes with low volatility (high temperature boiling points)? C® HPLC b. GC c, acid/base titration d. any of these will work 6 (4 points). Analyte separation in chromatography is affected by which of the following: a. differential partitioning between the mobile and stationary phases (difference in retention times) b, band broadening (diffusion) in the column © both aand b d. neither a orb7 (4 points). When using an internal standard, the identity of the standard is: @ different than the analyte. b. the same as the analyte c. it could be the same or different relative to the analyte. 8 (4 points). Emission (fluorescence) spectroscopy tends to have higher sensitivity because: emitted light is of a longer wavelength than absorbed light. Cb) detection of light is on a zero background. c. not all compounds fluoresce. d. both aand b. 9 (4 points). Molar absorptivity is directly proportional to: a absorbance b. pathlength c. concentration d. molecular weight. Worked out Problems Itis your responsibility to work out your answers clearly. Unclear, or unreadable work will not be graded. If there is not enough space provided to show your work, continue on the back of the page and clearly mark the problem number. Be sure to show all of your work and report your final answer with the correct number of significant figures and units. Unless otherwise noted, an unreasonable number of significant figures in a final answer will be marked off 2 points. A correct answer without work shown will not receive credit. Circle or draw a box around your final answer. Equations that may or may not be useful to you: 7 [base] au Pine + whe bx+c=0 HI= pK, + log x ai where ax? +x +e pH = pK, log =0.512? yu 1 2 leave vit =ty, MV) = Mb; 8 TF (aah 1305) Bee uae dilution factor = volume of original solution / total final solution volume diluted concentration = dilution factor(original concentration) =p Xl (x) _ te A=ebc 5 Sl A=2,00-log(%T)10 (10 points). You are using the method of standard addition to analyze a sample of river water for mercury (Hg). Solution A is made by pipeting 5.00 mL of undiluted sample into a 10.00 mL volumetric flask and filling to the mark with DI water. Solution B is made by pipeting 5.00 mL of undiluted sample and 3.00 mL. of 15.00 ppb Hg standard into the same 10.00 mL volumetric flask and filling to the mark with DI water. Solution A and B are analyzed using atomic absorption spectroscopy and give percent transmittance values of 56% and 33% respectively (not blank corrected) A blank has a percent transmittance of 96%. What is the concentration (ppb) of Hg in the undiluted sample? A bsorheen <2 A. 2.252 -~0,01g = Bi 0-4] - [Link] = stoma jie golvdiin B = 15.00 ppb (2) 3 45 ppb Las Ogt [Link] 0.463 fx }2 o.234O9 + (,053 9-229 L2J 2 Losz ; [x32 460 SK selobin B ome A for of fl unknoioy! 4.60. [2 ppb Comctrationt11 (10 points). Accounting for ionic strength, what is the solubility (moles/L) of Pb(BrO3), in water that also contains 0.0500 M NaCl and 0.0500 M KBr? NaCl and KBr are both fully soluble. The appropriate activity coefficient (y) for Pb” is 0.37; you need to find the activity coefficient for BrOs’ in the table below. The K., for Pb(BrOs)2 is 2.1 x 10°. Pb (Br ae +r Cb “Tyee « [B Boss. Broz” es 10 i 2 oO (xi(2-32)(2 2») (0 ey 2 2.17 C + +2x Gy = ee Table 8-1 Activity coefficients for aqueous solutions at 25°C Ton Pree A all nl fon (apm) 0.001 0.005 0.01 0.05 0.1 ae 2 "300 0533. 0914 0860.83 (G\H},CHCO5,(C,H),N- 800 0931 0912 085 0.82 EIEIO CHRINHT CH OG EOE =e 700 0930/0909 084s 0.81 U4, CGH,COz, HOC, H,CO;, CICGH,CO:, CH CH, exrmiien cos, (en cen COs, (Cryer AN ce. 600 0.965 0.829 0.907 0.835 0.80 {1,CHCO5,G,CCO5; [CH,CH,).NA®,(C Nat, CaCI*, CO, 105, HCO;, H,PO;, HSO5, [Link], Cott) aye HEH, hn 500 0.964 0.928 0,908 0.83 0.79 (cH,cH,} ve HNC 0228 oa2 *HNCH,CO,H; (ect NH nf 0927) 0815 OH”, F~/SCN, OCN~, HS", C105, €10;,BrO;,10z,Mn0z, 0; Hct C4 (CH,),NH? 350 0.964 0526 0.900 0.81 e581 CN, NOS, = f a Se 300. 0.964 0925 0.899.805: Rb”, Cs". N, TI, Ag 250 0.964 0524 098 0.80 & Lanthanides are elements 57-71 in the periodic table,12a (8 points). What is the equilibrium pH of a solution with a 0.365 M formal concentration of aminoethanol (HOCH:CH2NH2)? The pK, for HOCH2CH2NHs' is 9.498. AS 4 H.0 == HA + OM" ok ge de pha CHIN eg esusnio™ | * ae (Aa Kee of ae = [Link] xl0 _OO) _5 35 xo? O- 365 -X X pnore dg ge 5300 ee 2 (At) =1Z 2 2.95 KI0 fH) - ea pe 3? f . pa: whoa 3550") 12b (4 points) What is the percent association for aminoethanol at equilibrium in p above? fem 12a Gul, ae" (4x4 au }a[K] * O35 yA < BLOG13 (16 points). Using the systematic method, set up the following problem for solving. Give the charge balance, mass balance, equilibrium expressions, and unknowns. Clearly label each. Do not solve, What is the equilibrium pH of a solution made by dissolving 0.088 moles of KzHPO, into 1.000 L of pure water? Hint: there are tw different mass balance equations, Consider the following chemical reactions K,HPOy —2K jy + HPO}, "ion HPO%, I +POZg K, = 4.22310" HPO}, fey + H,Op HPO jy FOH;, Ky = 158x107 H,0,,<—> OH; +Hgy K. =10x10 charge’ (kJ + [i] = 2fltor D+ B0Pou"S + (He 7O4S + Go#S mass: [et] 2 2(0.0 FA) wovst brave O- 089M = (POF Fel LPOY” 34+ CHyPORS Z oot of 3 (R7) = 2 (CaP Oy7) + CROFT + PHD csmbbavm: Cr(P7) ¢ Veet = 2 422 xiO” [apey?3 HPGSONT i seu10"7 CHRO? cur (ony> Lows’t vekvoons? fe} [uPOeT (POPS, (agPoud, (1, [owS14a (8 points). What is the final pH of a solution produced by adding 75.00 mL of 0.0510 M acetic acid to 50.00mL of 0.105 M sodium acetate? The pK, for acetic acid is 4.76. 50? et. | 0.0510 w ’ is “fect, 25 Aare! HA 50.06reL, |: /05 woneed ee at 4 5.25 wwe! A wae s ( tlog 2,» [4,90 pil 4.76 tog see [472 14b (8 points). Assuming you have 25.0 mL of the solution described in 14a, what would the final pH be after adding 10.0ml, of 0.0550 M HNOs? De OSSO stereo} BES meted HA = 0,0306M ua 10 fo-2Soenel 0, 55Ouen=f Ht 125 wel . Sepseanl A”, g.04 Ht AO A’ +H? = HA aaa 25.00 ml conyasttecll g 0.765 uence] WA + O-SSOmnced = (31S cared HA ! 25.00 [Link] |, [05 uernel A~- 0.886 wor-| 2 OS uel & Time pl: 176 tlog = 14.34 } L3is d