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Chemistry Titration Calculations

This document contains calculations for standardizing a sodium thiosulfate solution and analyzing the concentration of bleach and an unknown copper compound. The sodium thiosulfate solution is standardized against potassium iodate, finding an average molarity of 0.0336 M. Bleach samples are then analyzed by reacting with the standardized thiosulfate, finding the bleach to be 0.47% sodium hypochlorite with a 4.78% deviation from the label. An unknown copper compound is also analyzed by reacting with thiosulfate and iodide, identifying it as copper (II) sulfate pentahydrate with 17.3% copper and 8.15% error compared to

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Hidayah Dayah
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121 views8 pages

Chemistry Titration Calculations

This document contains calculations for standardizing a sodium thiosulfate solution and analyzing the concentration of bleach and an unknown copper compound. The sodium thiosulfate solution is standardized against potassium iodate, finding an average molarity of 0.0336 M. Bleach samples are then analyzed by reacting with the standardized thiosulfate, finding the bleach to be 0.47% sodium hypochlorite with a 4.78% deviation from the label. An unknown copper compound is also analyzed by reacting with thiosulfate and iodide, identifying it as copper (II) sulfate pentahydrate with 17.3% copper and 8.15% error compared to

Uploaded by

Hidayah Dayah
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

CALCULATIONS.

PART A. STANDARDISATION OF SODIUM THIOSULPHATE SOLUTION

Find Molarity of Na2S2O3

1. Balancing the Equation

IO33- + I- + 6H+ I2- + 3H2O

2S2O32- + I2 2I- + S4O62-

2. Number of mole of IO3-

Molarity × Volume
Mole=
1000

0.010 ×50.0
Mole=
1000

= 5 × 10-4

1 mole of IO3- = 1 mole of I2-

5 × 10-4 mole IO3- = 5 × 10-4 mole I2-

3. Number of mole of S2O32-

1 mole I2 = 2 mole S2O32-

5 × 10-4 mole I2 = 2 × (5 × 10-4) mole S2O32-

5 × 10-4 mole I2 = 1 × 10-3 mole S2O32-


4. Molarity of S2O32-

Sample 1 Sample 2
Mole Mole
Molarity= Molarity=
1 L Volume 1 L Volume
1× 10−3 1× 10−3
= =
0.0299 0.0297
= 0.0334 M = 0.0337 M

Average molarity of S2O32-

( 0.0334 ) +(0.0337)
= 0.0336 M
2

PART B: ANALYSIS OF BLEACH


1. Balancing equation

𝐶𝑙𝑂− + 2 𝐼 −
+2𝐻 +
→ 𝐼2 + 𝐶𝑙− + 𝐻2O

2S2O32-(aq) + ClO-(aq) + H2O(l) S4O62- (aq) + Cl- (aq) + 2OH- (aq)

2. Mole of S2O22-

Sample 1 Sample 2

Molarity ×Volume
Molarity ×Volume Mole =
Mole = 1000
1000
0.0336 ×4.00
0.0336 ×3.90 =
= 1000
1000
= 1.3104 × 10-4 mole S2O32-
= 1.344 × 10-4 mole S2O32-

2 mole S2O32- = 1 mole ClO- 2 mole S2O32- = 1 mole ClO-


1.3104 × 10-4 mole S2O32- = 6.552 × 10-5 1.344 × 10-4 mole S2O32- = 6.72 × 10-5 mole
mole ClO- ClO-

3. Mole of ClO- in 10 mL aliquot


Sample 1

= 6.552 × 10-5 mole

Sample 2

= 6.72 × 10-5 mole

4. Mole of ClO- in 100mL aliquot


Sample 1

= 6.552 × 10-5 mole


Sample 2

= 6.72 × 10-5 mole

5. Mole of ClO- in 10mL bleach sample


Sample 1

= 6.552 × 10-5 mole × 10

= 6.552 × 10-4 mole

Sample 2

= 6.72 × 10-5 mole × 10

= 6.72 × 10-4 mole

6. Average moles of NaClO in 10 mL bleach sample.

( 6.552× 10−4 )+(6.72 ×10−4 )


2
= 6.636 × 10-4 mole

7. Gram/L of NaClO in bleach


Mass= Mole × Relative Molar Mass

= 6.636 × 10-4 mole × 74.45 g/mole

= 0.0494 g
Gram/L = 0.0494 g ÷ 0.01 L

= 4.94 g/L

8. Mass percent of NaClO in bleach

Mass Solute ( g )
Mass percent= ×100 %
Mass Solution ( g )
0.0494 ( g )
= ×100 %
10.613 ( g )
= 0.47%
9. Mass percent of NaClO from manufacturer label
= 5.25%

10. Percent deviation between experimental and label values


5.25% - 0.47% = 4.78%

PART C: ANALYSIS OF COPPER (II) UNKNOWN


I. Balancing the equation.

2Cu2+ (aq) + 2I- (aq) + 2NaS2O32- (aq) 2CuI(s) + Na2S4O62- (aq)

Sample 1 Sample 2

1. Mole of Molarity ×Volume Molarity ×Volume


Mole = Mole =
Na2S2O32- 1000 1000
0.0336 ×12.60 0.0336 ×12.70
= =
1000 1000
= 4.234 × 10-4 mole = 4.267 × 10-4 mole

2. Mole of Cu2+ 2 mole Cu2+ = 2 mole 2 mole Cu2+ = 2 mole


Na2S2O32- Na2S2O32-
8.468 × 10-4 mole Cu2+ = 8.534 × 10-4 mole Cu2+ = 4.267
4.234 × 10-4 mole Na2S2O32- × 10-4 mole Na2S2O32-

3. Mass of Cu2+
Mass = Mole × Relative Mass = Mole × Relative
Molar Mass Molar Mass
= 8.468 × 10-4 mole × = 8.534 × 10-4 mole ×
63.54 g/mol 63.54 g/mol
= 0.0538 g = 0.0542 g

Average mass of ( 0.0538 g )+ ( 0.0542 g )


Cu2+ 2
= 0.054 g
4. Mass percent
of Copper % Mass = % Mass =
Mass Solute ( g ) Mass Solute ( g )
×100 % ×100 %
Mass Solution ( g ) Mass Solution ( g )
0.0538 ( g ) 0.0542 ( g )
= ×100 % = ×100 %
0.3001 ( g ) 0.3252 ( g )
= 17.93% = 16.67%

5. Average
weight percent ( 17.93 % ) + ( 16.67 % )
of copper in 2
sample
= 17.3%
6. Theoretical mass of copper in compound

Molar mass of Copper = 63.546g/mol


i. Copper (II) acetate monohydrate

Molar mass of Copper


× 100 %
Molar mass of Copper ( II ) acetate monohydrate

63.546 g /mol
× 100 % = 31.81%
199.79 g /mol

ii. Copper (II) chloride dehydrate

Molar mass of Copper


× 100 %
Molar mass of Copper ( II ) chloride dihydrate

63.546 g /mol
× 100 % = 37.28%
170.47 g /mol

iii. Copper (II) sulphate pentahydrate

Molar mass of Copper


×100 %
Molar mass of Copper ( II ) sulphate pentahydrate

63.546 g /mol
× 100 %=25.45 %
249.685 g /mol

7. Percent Error

= 25.45% - 17.3%

= 8.15%

8. Name of Unknown Copper (II) unknown

Copper (II) sulphate pentahydrate


9. Chemical Formula

CuSO4.5H2O

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