GAMAZYME TDS

Revision: 24/02/2012

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking

1.1 Product identifier

Product Name:
Datasheet Number: 743146-r 5. 0. 0
Product Part Number: 743146 (100 x 50 gram)
Head Office:: Wilhelmsen Ships Service AS
Address: Strandveien 20, N1324 Lysaker, Norway, Tel:(+47) 67 58 45 50
1.2 Relevant identified uses of the substance or mixture and uses advised against
Cleaning agent
1.3 Details of the supplier of the safety data sheet
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB Rotterdam
The Netherlands
Telephone: +31 10 4877 777
Fax: +31 10 4877 888
Responsible Person: Patrick Rijsdijk, Product HSE Manager, Tel.:+31 6 349 440 35
Email: [Link]@[Link]
1.4 Emergency telephone number
-ONLY TO BE USED IN CASE OF AN INCIDENT-
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
Australia: +61 3 9630 0998
Giftinformasjonsentralen in Norway Tel.: +47 22591300

2 Hazards identification

2.1 Classification of the substance or mixture

- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and
preparations
- This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive
(67/548/EEC)
2.2 Label elements

Irritant
- Contains:citric acid - Sulphamic acid - sodium carbonate - Viable bacterial cultures

1
GAMAZYME TDS
Revision: 24/02/2012
2 Hazards identification (....)

Risk Phrases
- Irritating to eyes and skin (R36/38)
Safety Phrases
- Avoid contact with skin (S24)
- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice (S26)
- Wear suitable gloves and eye/face protection (S37/39)
2.3 Other hazards
- Odour: Mint
- Appearance: powder, blue, dispersible in water
- Inhalation: Mildly irritating to respiratory system, May cause breathing difficulty
- Ingestion: May cause irritation

3 Composition/information on ingredients

3.1 Mixtures

Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols

citric acid >15% 77-92-9 201-069-1 R36 Xi
Sulphamic acid >15% 5329-14-6 226-218-8 R36/38, 52/53 Xi
sodium carbonate 5-15% 497-19-8 207-838-8 R36 Xi
Viable bacterial cultures <10% N/A N/A - -

*See Section 16

4 First aid measures

4.1 Description of first aid measures

- IF ON SKIN: Wash with plenty of soap and water.
- Seek medical attention if irritation persists
-
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
- Irrigate eyes thoroughly whilst lifting eyelids
- Seek medical attention if irritation persists
-
- IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- Never make an unconscious person vomit or drink fluids
- Give 200-300mls (half pint) water to drink
- Obtain immediate medical attention
-
- Inhalation is unlikely to occur
- IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
4.2 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
- In cases of severe exposure, breathing difficulty may develop

2
GAMAZYME TDS
Revision: 24/02/2012
4 First aid measures (....)
- May cause gastro-intestinal disturbances
4.3 Indication of immediate medical attention and special treatment needed

5 Fire-fighting measures

5.1 Extinguishing media

- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
- Do not use water fog
5.2 Special hazards arising from the substance or mixture
- Smoke from fires is toxic. Take precautions to protect personnel from exposure
5.3 Advice for firefighters
- Substance evolves toxic fumes, wear self-contained breathing apparatus

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

- Wear protective clothing as per section 8
6.2 Environmental Precautions
- No special precautions are required for this product
6.3 Methods and material for containment and cleaning up
- Sweep or shovel-up spillage and remove to a safe place
- Flush spill area with copious amounts of water
6.4 Reference to other sections
- None

7 Handling and storage

7.1 Precautions for safe handling

- Wear protective clothing as per section 8
- Avoid contact with skin and eyes (S24/25)
7.2 Conditions for safe storage, including any incompatibilities
- Keep in a cool, dry, well ventilated place
7.3 Specific end use(s)

8 Exposure controls/personal protection

8.1 Control parameters

- No exposure limits have been set for this substance
8.2 Exposure controls
- No special precautions are required for this product

3
GAMAZYME TDS
Revision: 24/02/2012
8 Exposure controls/personal protection (....)

Occupational exposure controls

- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
recommended)
- Respiratory protection may be required under exceptional circumstances when excessive air
contamination exists

Gloves Goggles No Smoking

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties

- Odour: Mint
- Appearance: powder, blue, dispersible in water
- Boiling point - not applicable
- Vapour pressure - not applicable
- Vapour density - not applicable
- Water solubility ~100 g/l
- Density 1 - 1,1 g/cm3
9.2 Other information
- None

10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid contact with acids and alkalis
10.5 Incompatible materials
- Incompatible with acids and alkalis
10.6 Hazardous Decomposition Products
- No hazardous decomposition products known

11 Toxicological information

11.1 Information on toxicological effects

- No experimental data available

4
GAMAZYME TDS
Revision: 24/02/2012
11 Toxicological information (....)

Inhalation
- Inhalation is unlikely to occur
- May cause breathing difficulty
Contact with skin
- Causes redness and irritation
Contact with eyes
- Causes redness and irritation
Ingestion
- No effects for small dosage. Large dose effects not known
- May cause gastro-intestinal disturbances
Carcinogenicity
- No evidence of carcinogenic effects

12 Ecological information

12.1 Toxicity
12.2 Persistence and degradability
- Its main ingredients will either dissolve rapidly and dissociate in water or are readily/inherently
biodegradable.
- If this substance is discharged at low concentrations into an adapted biological effluent treatment plant,
the degrading action of the activated sludge will not be affected
12.3 Bioaccumulation Potential
- Bioaccumulation of the components in this product is insignificant.
12.4 Mobility in soil
- Completely soluble in water
12.5 Results of PBT and vPvB assessment
- Not a PBT according to REACH Annex XIII
12.6 Other Adverse Effects
- No environmental problems are expected when the product is used / handled correctly. In its intended use,
the product will not be released into the environment.

13 Disposal considerations

13.1 Waste treatment methods

- Disposal should be in accordance with local, state or national legislation
Classification
- EU Waste class: 06.01.99

14 Transport information

14.1 UN Number
- n/a

5
GAMAZYME TDS
Revision: 24/02/2012
14 Transport information (....)

14.2 UN Proper Shipping Name

- n/a
14.3 Transport hazard class(es)
- n/a
14.4 Packing group
- n/a
14.5 Environmental hazards
- On available data, substance is not harmful to the environment
14.6 Special precautions for user
- Not classified as hazardous for transport
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
Other information

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
Directive 453/2010/EU.
15.2 Chemical Safety Assessment

None

16 Other information

Text of R and S phrase codes used in this safety data sheet:- R36: Irritating to eyes; R36/38: Irritating to eyes and
skin; R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
individual constituents
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable for
other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
without seeking advice from manufacturer

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES

For addresses of other Wilhelmsen Ships Service offices, please refer to [Link]/shipsservice

Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
Tel (+1) 562 624 8888 Fax (+1) 562 624 1011

6
GAMAZYME TDS
Revision: 24/02/2012
16 Other information (....)

Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
(+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
(+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
(+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
210 4239100 Fax (+ 30) 210 4212480
WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
(+971) 4 382 3888