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MATERIAL SAFETY DATA SHEET(MSDS)
1. PRODUCT & COMPANY INFORMATION
I. Product Name : SHAIC AC-700 PRIMER
II. Use : Enhanced adhesion of the coating material and steel pipe
III. Manufacturer
SHAIC International Co.
/ Supplier :
No. 316-6, Bonsan, Jinyoung, Kimhae, Kyungnam, Korea
IV. Telephone No. : +82 55 342 0401~2 / +82 55 343 4845~6
V. FAX : +82 55-342-0403
2. HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Hazard. Risk Classification
Flammable liquids : Class 2
Skin Corrosion / Skin Irritation : Class 2
Eye damage / eye irritation : Class 2
Reproductive toxicity : Class 1A
Specific target organ toxicity (single exposure) : Class 1
Specific target organ toxicity (repeated exposure) : Class 2
Acute toxicity (inhalation: vapor)) : Class 4
Aspiration Hazard : Class 1
MSDS label elements, including precautionary statements
Symbols
Signal word: Danger
Harzard. Risk phrases:
Highly flammable liquid and vapor
If swallowed and enters airways maybe fatal
It causes skin irritation
It causes serious eye irritation
Causes respiratory tract stimulus
It may damage fertility or the unborn child
Causes of damage to the body organs
Damage to the kidney
Causes of damage to the body organs through prolonged or repeated exposure
If prolonged or repeated exposure may cause damage to blood (Revelation)
Precautionary statements:
Prevention : Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Avoid heat, spark, flames. Get away from the hot surfaces. - No smoking
Keep container tightly closed
Please grounding or bonding to a container and receiving equipment
Explosion-proof electrical. Ventilation. Please use the lighting equipment
Please use only non-sparking tools
Take precautionary measures against static discharge
Do not breathe (dust particles, fumes, gas mist steam spray)
Wash after handling the treated area thoroughly
While using this product do not eat drink or smoke
Use only in a well-ventilated area
Wear your protective gloves, Goggles, Face shield
Wear appropriate personal protective equipment
Storage :
Keep in a well-ventilated place and keep cool
Store in a lock storage location
Disposal :
(As specified in the relevant legislation) Dispose of the container contents
Harmful. Which do not result in classification other harmful. Risk (NFPA):
NFPA index
Health Fire Reactivity
Chemical Name
PRIMER 2 3 3
3. COMPOSITION
INGREDIENTS CAS No PERCENTATE REMARKS
TOLUENE 108-88-3 22
Hydrocarbon Solvent 64741-46-4 47
Synthetic Rubber 93573-35-4 6.5 highly polymer compound
CARBON 7440-44-0 2.5
Petroleum Hydrocarbon Resin 64742-16-1 18
4. FIRST AID
I. EYE CONTACT
Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes
II. SKIN CONTACT
Remove contaminated clothing & shoes and flush affected area with soap
and plenty water as soon as possible until not remaining residue.
Remove contaminated clothing and shoes and please isolate the contaminated area
III. Inhalation
Do not induce vomiting
If exposed to dust or fumes remove the excess with a clean air and if you cough or other symptoms
IV. Ingestion
If swallowed immediately call a poison center or physician
Do not induce vomiting
Move patient to fresh air. If the breathing is stopped or difficult, give artificial respiration.
To keep victim warms and at rest.
V. Notices of other caution
Contact staff when exposed to please take special emergency measures such as tracking survey.
Whether the substance of the medical personnel, and please to take protective measures
5. Explosion. FIRE FIGHTING MEASURES
I. Suitable (and unsuitable) extinguishing
This material will be used in conjunction with alcohol-resistant foam extinguishers, carbon dioxide or water spray
Choking extinguishers will use dry sand or soil
II. Specific hazards arising from the chemical
Highly flammable liquid and vapor
Flash point and can form an explosive mixture in the above
Containers may explode when heated
Highly flammable: by heat or sparks, easily ignited by a flame
III. Wear protective equipment during fire fighting operations
The structure need to wear the appropriate protective equipment
Most vapors are heavier than air and spread along the ground
and can accumulate in low areas or confined spaces
Move containers from fire area if without risk
The maximum distance from the tank or fire extinguishing please use unmanned extinguishing equipment
please use unmanned extinguishing equipment
In the case of a large fire, tank fire and, if possible use an unattended fire extinguishing
device you retire ridden leave
6. ACCIDENTAL RELEASE MEASURES
I. Precautions and protective equipment to protect the human body
Avoid inhalation
Because of very fine particles can cause a fire or explosion: Remove all sources of ignition.
Wipe spills immediately that, please follow the precaution protection protest
Remove all sources of ignition.
Please be sure all of the ground material handling equipment
II. Measures to Protect the Environment
Waterways, sewers, basements, Prevent entry into confined spaces
III. Methods for cleaning up
Built a levee for digestion please collect the water
To absorb spilled with inert material (for example, dry sand or earth), and Put to the chemical waste containers
Please use clean explosion tools collected absorbed material
7. Handling and Storage
I. Handling
Do not handle until all safety precautions have been read and understood
Take precautionary measures against static discharge
When using this product, eating Do not eat, drink or smoke
Please use care in handling / storage
Please stop the long-term or lasting skin contact
Please beware of heat
II. Safe storage
Heat, spark, flames get away from the hot surfaces - No smoking
Store in tightly closed containers in a well-ventilated place.
Keep in a well-ventilated place. Keep it cool
Empty drums are completely drained and properly placed.
8. Exposure controls and personal protection
I. Exposure of the chemical and biological criteria, such as exposure
OSHA ACGIH
Hazardous ingredients (US Occupational Safety and (American Industrial Hygiene
Health Administration) Association Expert)
TOLUENE 200ppm TWA , 300ppm Ceiling 1
20ppm TWA
108-88-3 500ppm MAX , CONC 10 minute
Hydrocarbon Solvent
N/A 300ppm TWA
64741-46-4
II. Engineering Controls :
Will be managed by proper ventilation occupational exposure below the standards
III. Personal protective equipment :
Respiratory protection: If ventilation is insufficient, wear appropriate breathing mask
Eye protection: Wear safety goggles or safety glasses with side protection device
Hand protection: The use of chemical gloves of neoprene or natural rubber is recommended
Body protection: Normal industrial hygiene habits should be followed
Use only in well-ventilated space
While preventing contact with the skin and eyes Follow contaminated or take off wet clothes.
A large amount of water, soap, and Skin care products Please remove the contaminants
buried in the skin
9. Physical and chemical properties
A. Appearance (physical state, color etc) : Black color liquid
B. ODOR : gasoline odor
C. Odor threshold : N/A
D. Ph : N/A
E. Melting / freezing point : N/A
F. Boiling range : 80 ℃ ~ 160 ℃
G. Flash Point : 1 ℃ or less
H. Evaporation rate : Not available
I. Flammability (solid, gas) : Highly flammable
J. Upper / lower flammability or explosive limits : N/A
K. Vapor Pressure : N/A
L. Solubility : Insoluble (solvent: water)
M. Vapor Density : N/A
N. Density : 0.83 ~ 0.84
O. N- octanol / water partition coefficient : N/A
P. Auto-ignition temperature : N/A
Q. Decomposition Temperature : N/A
R. Viscosity : 50 CPS
S. Molecular Weight : N/A
10. Stability and reactivity
Chemical stability: Stable under normal conditions
Possibility of hazardous reactions: Will not occur
Conditions to avoid: Heat, flames, sparks, smoke and other sources of ignition.
Materials to avoid: None if used as recommended usage
Hazardous decomposition products: Not available
11. Toxicological information
I. Information on the likely routes of exposure: skin, mouth, eyes
II. Health Hazard Information:
A) Toluene
* Flammable liquid: Category 2
* Acute toxicity:
- Oral: Category et / LD50 4800 mg / kg (rat)
- Dermal: Category et / LD50 14100 mg / kg (rabbit)
- Inhalation: Category 4 / LD50 18mg / L (rat)
* Skin corrosive or irritant: Category 2
* Serious eye damage or irritation: Not available
* Respiratory sensitization: Not available
* Skin sensitization: Not available
* Carcinogenic: Category et al (IARC: Group 3 / ACGIH: Group A4)
* Mutagenicity: Not available
* Reproductive toxicity: Category 1A
* Specific target organ toxicity (single exposure) "Category 1 (central nervous system)
* Specific target organ toxicity (repeated exposure) "Category 1 (central nervous system, kidneys, liver)
* Aspiration hazard: Category 1
B) heavy naphtha
* Flammable liquid: Category 2
* Acute toxicity:
- Oral: Not available
- Dermal: Not available
- Inhalation (vapor): Category 4 / LC50 3400 ppm (rat)
* Skin corrosive or irritant: Category 2
* Serious eye damage or irritation: Not available
* Respiratory sensitization: Not available
* Skin Sensitization: Not applicable
* Carcinogenic: Category 2 (IARC: Group 3 / ACGIH: Group A4)
* Mutagenicity: Not available
* Reproductive toxicity: Category 1B
* Specific target organ toxicity (single exposure) "Category 1 (central nervous system, respiratory system, kidneys, liver)
* Specific target organ toxicity (single exposure) "Category 3 (respiratory, anesthesia)
* Specific target organ toxicity (repeated exposure) "Category 1 (central nervous system, kidneys, liver)
* Aspiration hazard: Category 1
C) Toxic numerical scale (acute toxicity estimate): No data
12. Impact on the environment
A. Aquatic, terrestrial ecotoxicity:
It may cause. It is easily attached to the skin or the outside of the natural organisms that could harm
- Fish: LC50 24mg / L (96 hrs) Oncorhyncus mykiss
- Crustaceans: EC50 11.5mg / L (48 hrs) Daphnia magna
- Birds: Not available
B. Persistence and degradability:
- Persistence: Log Pow <3
- Degradability: No data
All. Bioaccumulative:
- Biodegradability: BOD = 80% (20 days)
- Concentrated Gender: Not available
D. Mobility: leakage, that can have an impact on the environment during disposal
E. Other adverse effects: Not available
13. DISPOSAL CONSIDERATIONS
A. Methods of disposal:
- 5% more than rags, including oil, sand, dirt, etc. (treatment of waste criteria) Waste Management Act and
Article 12 as a designated waste
It will be processed according to law enforcement regulations Article 6 of Annex 4
- If the oil is flowing through the water separating wastewater treatment plant, it will be purified
B. Disposal considerations:
- It must be disposed of only through a designated waste disposal service
- Unauthorized disposal or incineration is harmful to natural ecosystems, so inhibit them
14. TRANSPORT INFORMATION
1. UN Number : 1263
2. Shipping Name : PAINT
3. Hazard Class : 3
4. Packing Class : Ⅱ
5. Marine Pollutant : N/A
6. Special safety measures the user needs to be aware of the shipping or transportation:
- So watch out for fire and flammable rivers will not be contaminated with water, etc.
- Fire kinds of emergency measures: F-E
- Spills type of emergency: S-D
15. Regulatory Information
A. Regulated by the Occupational Safety and Health Act:
- Working environment measurement material: Toluene
- Managed hazardous substances: Toluene
- Exposure limits set material: Toluene
B. Regulations by TCCA:
- All product information: N
- Component information: Heavy naphtha - US regulations, toluene-toxic
All. Dangerous Substance Safety Management Act: 1 petroleum fourth kind
D. Regulation by the Waste Management Act: Waste designation
E. Other regulation by domestic and foreign law: Not applicable
16. Other Resources
A. Source of data:
- KOSHA CODE W-05-2007 [Material Safety Data Sheet written instructions]
- Classification of chemical substances, the Globally Harmonized System Labelling
[Government Joint Committee GHS: registration number issued 11-1410119-000032-01]
- Classification of chemicals, based on revised Notice regarding labeling and Material Safety Data Sheet
[Ministry of Labour Notification No. 2008-1;
- MSDS reference provided by the Korea Occupational Safety & Health Agency of KISCO-NET
- Other domestic non-chemical analysis data DB
B. First Date: 1996. 04
All. It amended many times and the last revision date:
- Revision number: 1 times
- Revision Date: 04/12/2014
D. Other
- The MSDS is after all The users who use The products being supplied to read The respective Notices
It should be delivered to be used
- Handlers, the purchaser or third party materials created to become useful to the safety data being treated
- That guarantee about the suitability or quality of the specific nature of the products or special purpose
Has not to be understood
