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Assignment Work1 Introduction Questions

The document requests payment to an email address in order to provide solutions to homework problems involving polymer synthesis reactions, polymer structures, types of polymerization, determining polymerization mechanisms, calculating number average and weight-average molecular weights, and defining and relating the effects of chemical structure on Tm and Tg.

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78 views2 pages

Assignment Work1 Introduction Questions

The document requests payment to an email address in order to provide solutions to homework problems involving polymer synthesis reactions, polymer structures, types of polymerization, determining polymerization mechanisms, calculating number average and weight-average molecular weights, and defining and relating the effects of chemical structure on Tm and Tg.

Uploaded by

John Michael
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOC, PDF, TXT or read online on Scribd

#For solutions, please pay on PayPal 5 USD to my email: jcollinstesha@hotmail.

com
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1. Show by equations the overall chemical reactions involved in the synthesis of

polymers from

a. CH2=CH – CO2H

b.

c. H2N – (CH2)5 – NH2 + ClCO – (CH2)5 – COCl

d. HO – (CH2)5 – CO2H

e.

f. CH2=CH – F

2. What is the structure of the repeating unit in each of the polymer in question 1?. Can

any other monomers used to obtain the same polymer structure for any of these

polymers?

3. Classify the polymers as to whether they are condensation or addition polymers.

Classify the polymerizations as to whether they are step, chain or ring-opening

polymerizations.
4. How would you experimentally determine whether the polymerization of an

unknown monomer X was proceeding by a step or a chain mechanism?

7. A sample of Polystyrene is composed of a series of fractions of different sized

molecules:

Fraction Weight Fraction Molecular Weight

A 0.1 12,000

B 0.19 21,000

C 0.24 35,000

D 0.18 49,000

E 0.11 73,000

F 0.08 102,000

G 0.06 122,000

H 0.04 146,000

Calculate number average and weight-average molecular weights of this polymer sample.

Draw molecular weight distribution curve analogous to Fig. 1-4.

9. Define Tm and Tg and indicate how they are affected by chemical structure.

#: For solutions, please pay on PayPal 5 USD to my email: jcollinstesha@[Link]


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