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Reaksi Peledakan NH4NO3 dan CH2

This document discusses the calculation of ammonium nitrate (NH4NO3) and fuel (CH2) composition percentages in an ammonium nitrate fuel oil (ANFO) explosive. It first shows the reaction equations for three types of ANFO explosions and calculates the percentages of NH4NO3 and CH2 as 94.49% and 5.51% respectively based on the balanced reaction for one of the equations. It then presents an alternative method to calculate the percentages when the reaction equation is unknown, setting up elemental composition equations and solving the system of equations, arriving at the same percentages of 94.49% for NH4NO3 and 5.51% for CH2.

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arief warjiyanto
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65 views2 pages

Reaksi Peledakan NH4NO3 dan CH2

This document discusses the calculation of ammonium nitrate (NH4NO3) and fuel (CH2) composition percentages in an ammonium nitrate fuel oil (ANFO) explosive. It first shows the reaction equations for three types of ANFO explosions and calculates the percentages of NH4NO3 and CH2 as 94.49% and 5.51% respectively based on the balanced reaction for one of the equations. It then presents an alternative method to calculate the percentages when the reaction equation is unknown, setting up elemental composition equations and solving the system of equations, arriving at the same percentages of 94.49% for NH4NO3 and 5.51% for CH2.

Uploaded by

arief warjiyanto
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

Persamaan reaksi peledakan :

1. 3 NH4NO3 + CH2  7 H2O + CO2 + 3 N2  Smoke (ZOB)


2. 2 NH4NO3 + CH2  5 H2O + N2 + CO  Fumes (NOB)
3. 5 NH4NO3 + CH2  11 H2O + CO2 + 4 N2 + 2NO  Fumes (POB)

Perhitungan kadar NH4NO3 dan CH2


1. Diketahui persamaan reaksinya
3 NH4NO3 + CH2  7 H2O + CO2 + 3 N2
( Hitung berat molekul dari masing – masing senyawa )
3 ( 80 ) + 14  7( 18 ) + 44 + 3 ( 24 )
254 = 254

NH4NO3 =BM NH4NO3


*100%
BMreaktan

240 =
*100%
254

= 94,49 %
CH2 = BM CH2
*100%
BMreaktan
14
*100%
254=
= 5,51 %
Apabila suatu ANFO diketahui beratnya 100 gram, maka kita dapat
menghitung berat dari NH4NO3 dan CH2 dengan cara mengalikan kadar dengan
berat.
Berat NH4NO3 = 94,49 % * 100 = 94,49 gram
Berat CH2 = 5,51 % * 100 = 5,51 gram ( berat CH2 dari gram diubah ke
liter )
5,51 gam / 0,82 = 6,72 liter. ( 1 Liter =
0,82 gram )
2. Tidak diketahui persamaan reaksinya
NH4NO3 + CH2  H2O + CO2 + N2

Jenis % berat H0 C0 N0 O0
bahan
NH4NO3 x 4/80 x - 2/80 x 3/80 x
CH2 y 2/14 y 1/14 y - -
Total x + y = 100 2/80x + 1/14 y 2/80 x 3/80 x
2/14 y

Persamaan I : x + y = 100
Persamaan II: ZOB = O0 – 2C0 – ½ H0
0 = 3/80 x – 2(1/14y) – ½(4/80x + 2/14y)
0 = 3/80x – 2/14y – 2/80x – 1/14y
0 = 1/80x – 3/14y
0 = 0,0125x – 0,2142y
y = 0,058333x ( subsitusi ke persamaan I )
Nilai x : x + y = 100
x + 0,05833 x = 100
x = 94,49 %
y = 0,05833 * 94,49 = 5,51 %
Nilai dari NH4NO3 dan CH2 :
NH4NO3 :
N = 2/80 * 94,49 = 2,36225 mol * 14 = 33,1 gram
H = 4/80 * 94,49 = 4,7245 mol *1 = 4,7245 gram
O = 3/80 * 94,49 = 3,543375 mol * 16 = 56,694 gram
CH2 :
C = 1/14 * 5,51 = 0,3936 mol * 12 = 4,7229 gram
H = 2/14 * 5,51 = 0,7871 mol * 1 = 0,7871 gram

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