Metamorphism Reviewer
Metamorphism Reviewer
What is metamorphism?
– is the change undergone by an existing rock (e.g. igneous, sedimentary or metamorphic), in the solid
state, to another rock
– a process that produce structural and mineralogical changes in any type of rock in response to physical
and chemical conditions differing from those under which the rocks are originally formed.
Why do rocks change?
Agents of metamorphism
1. Heat
2. Pressure
3. Chemically active fluids
1. Heat
Sources of heat?
• Geothermal gradient - temperature increases with depth (20o – 30oC per km in the crust)
• Large bodies of molten rock or intrusive bodies
Provides the energy to drive chemical reactions → recrystallization of minerals
2. Pressure
When subjected to confining pressure, minerals may recrystallize into more compact forms.
Confining pressure – equal stress in all directions; from overlying rock
Confining pressure (=hydrostatic pressure) – operating equally in all directions and determined largely by
depth
Directed pressure ( shear stress) – operating in one particular direction
Stress minerals - minerals stable in the extended range of temperature
Anti-stress minerals:
1. cordierite 3. olivene
2. andalusite
Differential stress – unequal pressure in different directions
3. Chemically active fluids
Sources of fluids?
• Water trapped in pore spaces of the original rock.
• Water released during dehydration of minerals, such as amphibole or mica.
• Water from magmatic bodies (hydrothermal fluids).
Changes in temperature are generally more effective than changes in pressure in bringing about mineralogical
changes in most rocks.
For metamorphism to be effective, especially at low temperature, some catalytic influence capable of
accelerating chemical reaction appears to be necessary.
Types of metamorphism
1. Contact metamorphism
Contact metamorphism occurs when magma invades pre-existing rock. A zone of alteration called an
aureole (or halo) forms around the emplaced magma .
Takes place at shallow depths (0-6km) and low pressure.
Foliation
Round grains can become flattened Sheet silicate minerals can have a preferred orientation
3. Hydrothermal metamorphism
Protoliths
Metamorphic grades
Temp Index
Temp C Coal Limestone Sandstone Basalt Shale
F Minerals
Lignite
Bituminous
500 Anthracite
700 Greenstone
1200 Sillimanite
Melting
700
Begins
Metamorphic environments associated with plate tectonics
Metamorphic Facies
Depth\Temp 300C 400C 500 C 600 C 700 C 800 C
40 km - 12
Not Found Eclogite (Mantle)
kb
Pre-kinematic crystals
a. Bent crystal with
undulose
extinction
b. Foliation
wrapped around
a porphyroblast
c. Pressure shadow
or fringe
d. Kink bands or
folds
e. Microboudinage
f. Deformation
twins
Typical textures of pre-kinematic crystals. From Spry (1969) Metamorphic Textures. Pergamon. Oxford.
Post-kinematic crystals
a. Helicitic folds b. Randomly oriented crystals c. Polygonal arcs
d. Chiastolite e. Late, inclusion-free rim on a poikiloblast (?)
f. Random aggregate pseudomorph
Syn-kinematic crystals
Spiral Porphyroblast
Syn-kinematic crystals
Deformation may not be of the same style or
even coeval throughout an orogen
Mantled porphyroclasts and “mica fish” as sense-of-shear indicators. After Passchier and Simpson (1986)
Porphyroclast systems as kinematic indicators. J. Struct. Geol., 8, 831-843.
Other methods to determine sense-of-shear. Winter (2010) An Introduction to Igneous and Metamorphic
Petrology. Prentice Hall.
Supplemental Notes:
2 major types of metamorphism may be distinguished on the basis of geological setting
1) Local extent which includes thermal or contact metamorphism
2) Regional extent which refers to regional metamorphism
Metamorphic rocks
are derived from pre-existing rock types and have undergone mineralogical, textural, and structural
changes.
the changing conditions of temperature and/or pressure are the primary agents causing metamorphic
reactions in rocks.
grade refers to the range of temperature under which metamorphism occurred.
when metamorphism occurs there is usually little alteration in the bulk chemical composition of the rocks
involved with the exception of water and volatile constituents such as carbon dioxide. Little material is
lost or gained and this type of alteration is described as an isochemical change. By contrast, allochemical
changes are brought about by metasomatic processes which introduce or remove material from the rocks
they affect.
metasomatic changes are brought about by hot gases or solutions permeating through rocks.
Metamorphic textures and structures
Preferred orientation
commonly exhibited as mesoscopic linear or planar structures which allow the rocks to split more
easily in one direction than another. (e.g. cleavage in a slate)
slaty cleavage most familiar type and occurs in low metamorphic grade
fracture cleavage is a parting defined by closely spaced parallel fractures which is usually
independent of planar preferred orientation
Schistosity
of higher grade
was developed in a rock when it was subjected to increased temperatures and stress which
involved its reconstitution, which was brought about by localized solution of mineral material
and recrystallization.
a preferred orientation of inequaint mineral grains or grain aggregates produced by
metamorphic processes
aligned minerals are coarse grained enough to see with the unaided eye
Gneissose structure
Either a poorly-developed schistosity or segregated into layers by metamorphic processes
Gneissose rocks are generally coarse grained
The formation of metamorphic rocks
any type of rock can become a metamorphic rock if it is heated to temperatures of several hundred
degrees Celsius,
and/or if subjected to high pressure (because of the weight of overlying rocks)
during metamorphism, the minerals making up the rock become chemically unstable, meaning that their
constituent ions are redistributed. The result is that either large crystals grow at the expense of existing
smaller ones, or a new set of minerals is formed. Generally speaking, the overall chemical composition of
the rock remains about the same
although igneous and metamorphic rocks both form at high temperatures, an important distinction is that
metamorphism occurs in the solid state, whereas igneous activity involves liquid rock (magma).
Causes of metamorphism
What natural process could cause a rock to be heated?
Answer
Heating can be caused when hot magma is intruded into a cool rock.
On the other hand, an increase in both pressure and temperature will come about if the rock becomes more
deeply buried as a result of Earth movements, particularly at convergent plate boundaries where continents
collide, or is covered by a deepening layer of sedimentary deposits.
In igneous rocks grain size is controlled by cooling rate (and crystals grow from a liquid); the slower the cooling, the
coarser the grain size. In metamorphic rocks grain size is controlled by pressure and temperature (and crystals
grow by transformation of existing minerals in the solid state); the higher the temperature and pressure, the
coarser the grain size.
The end product of metamorphism depends on two main variables:
1. the chemical composition of the starting rock, and
2. the pressure and temperature conditions under which metamorphism occurred.
A useful analogy is with cooking – the product of baking in an oven depends on the ingredients that went
in (chemical composition) and the temperature that the ingredients were subjected to in the oven. Just
as the shape, colour and taste of food from the oven gives us clues about the ingredients and the baking
conditions, so the texture and mineralogy of a metamorphic rock allow us to say something about the
original rock type and the temperature and pressure conditions in the crust where metamorphism
occurred.
Question
Compare and contrast contact metamorphism and regional metamorphism in terms of (a) the presence of foliation
and (b) the distribution of the affected rocks.
Answer
(a) Rocks formed by regional metamorphism possess a foliation due to the alignment of platy minerals that grew
during compression. Rocks formed by contact metamorphism do not show foliation.
(b) Contact metamorphic rocks are confined to a narrow band in the rocks surrounding an igneous intrusion.
Regional metamorphism occurs in vast tracts of land as a result of mountain building.
What term is used to describe the contact between the tilted and horizontal strata?
Answer
It is an unconformity.
Some terms which describe the general bulk chemical composition are as follows:
1) perlitic
derivatives of aluminum sedimentary rocks like shale and mudrocks
recognized by an abundance of aluminous minerals like clay minerals, micas, kyanite, sillimanite,
andalusite and garnet
2) quartzo-feldspathic
– originally contained mostly quartz and feldspar like granitic rocks and arkosic sandstones will also
contain an abundance of quartz and feldspar as metamorphic rocks since these minerals are stable
over a wide range of temperature and pressure. Those that exhibit mostly quartz and feldspar with
only minor amounts of aluminous minerals are termed quartzo-feldspathic.
3) Calcareous
– calcium-rich
– usually derivatives of carbonate rocks although they contain other minerals that result from reaction
of the carbonates with associated siliceous detrital minerals that were present in the rock
– at low grades of metamorphism calcareous rocks are recognized by their abundance of carbonate
minerals like calcite and dolomite
– with increasing grade of metamorphism these are replaced by minerals like brucite, phlogopite(Mg-
rich biotite), chlorite, and tremolite.
– At even higher grades anhydrous minerals like diopside, forsterite, wollastonite, glossurite, and calcic
plagioclase
4) Basic
just like in igneous rocks, the general term basic refers to low-silica content
generally derivatives of basic igneous rocks like basalts and gabbros
have an abundance of Fe-Mg minerals like biotite, chlorite, and hornblende, as well as calcic
minerals like plagioclase and epidote
5) magnesian
rich in Mg with relatively less Fe
contain Mg-rich minerals like serpentinite, brucite, talc, dolomite, and tremolite
in general, usually have an ultrabasic protolith, like peridotite, dunite, or pyroxenite
6) ferrigenous
rich in Fe with little Mg
could be derivatives of Fe-rich cherts or ironstones
characterized by the abundance of Fe-rich minerals like greenlite (Fe-rich serpentinite), minnesotaite
(Fe-rich talc), ferroactinolite, ferrocummingtonite, hematite, and magnetite at low grades
abundant of ferrosilite, fayalite, ferrohedenbergite, and almandine garnet at higher grades
7) manganiferrous
characterized by the presence of Mn-rich minerals
characterized by such minerals as stilpnomelane and spessartine
Underlying principles
Metamorphic facies
defined by the mineralogical composition of a rock
when the temperature or pressure in a rock body change, the rock can cross into a different facies and
some minerals become stable while others become unstable or metastable. Whether minerals really react
depends on the reaction kinetics, the activation energy of the reaction and how much fluid is present in
the rock.
the minerals in a metamorphic rock and their age relations can be studied by optical
microscopy or Scanning Electron Microscopy of thin sections
apart from the metamorphic facies of a rock, a whole terrane can be described by the abbreviations LT,
MT, HT, LP, MP, HP (from low, medium or high; pressure or temperature). Since the 1980s the term UHP
(ultra high pressure) is used for rocks that saw extreme pressures.
which minerals grow in a rock is also dependent of the original composition of the protolith (the original
rock before metamorphosis)
carbonate rocks have a different composition from say a basaltic lava, the minerals that can grow in them
are different too. Therefore a metapsammite and a metapelite will have different mineralogical
compositions even though they were in the same metamorphic facies.
Index mineral
every metamorphic facies has some index minerals by which it can be recognized. That does not mean
these minerals will necessarily be visible with the naked eye, or even exist in the rock; when the rock did
not have the right chemical composition they will not grow.
typical index minerals are the polymorphs of aluminosilicate (Al2SiO5, all are nesosilicates)
andalusite is stable at low pressure
kyanite is stable at high pressure but relatively low temperature
sillimanite is stable at high temperature.
Metamorphic facies and their mineral assemblages
Slate
2. Phyllite
a rock with a schistosity in which very fine phyllosilicates (sericite/phengite and/or chlorite),
although rarely coarse enough to see unaided, impart a silky sheen to the foliation surface
with both a foliation and lineation are very common
Phyllite
3. Schist
exhibits schistosity. By this definition, term is a broad, and slates & phyllites are types of schists
In common usage, schists restricted to those metamorphic rocks in which the foliated minerals are
coarse enough to see easily in hand specimen.
rock of intermediate metamorphic grade between phyllite and gneiss
Schist
4. Gneiss
a metamorphic rock displaying gneissose structure
typically layered (also called banded), generally with alternating felsic and darker mineral layers
may also be lineated, but must also show segregations of felsic-mineral-rich and dark-mineral-rich
concentrations.
Gneiss
Non-Foliated Metamorphic Rocks
simpler than for foliated rocks
1. Granofels
a comprehensive term for any isotropic rock (a rock with no preferred orientation)
Granofels
2. Hornfels
type of granofels that is typically very fine-grained and compact, and occurs in contact aureoles.
tough, and tend to splinter when broken.
Hornfels
Specific Metamorphic Rock Types
1) Marble
a metamorphic rock composed predominantly of calcite or dolomite. The protolith is typically
limestone or dolostone
Marble
2) Quartzite
a metamorphic rock composed predominantly of quartz. The protolith is typically sandstone. Some
confusion may result from the use of this term in sedimentary petrology for a pure quartz sandstone
Quartzite
3) Greenschist/Greenstone
a low-grade metamorphic rock that typically contains chlorite, actinolite, epidote, and albite
first three minerals are green, w/c imparts color to the rock. Called greenschist if foliated, and
greenstone if not.
the protolith is either a mafic igneous rock or graywacke.
Greenschist
4) Amphibolite
a metamorphic rock dominated by hornblende + plagioclase.
amphibolites may be foliated or non-foliated
the protolith is either a mafic igneous rock or greywacke
Amphibolite
5) Serpentinite
an ultramafic rock metamorphosed at low grade, so that it contains mostly serpentine
Serpentinite
6) Blueschist
a blue amphibole-bearing metamorphosed mafic igneous rock or mafic greywacke
this term is so commonly applied to such rocks that it is even applied to non-schistose rocks
Blueschist
7) Eclogite
a green and red metamorphic rock that contains clinopyroxene and garnet (omphacite + pyrope)
the protolith is typically basaltic
Eclogite
8) Skarn
a contact metamorphosed and silica metasomatized carbonate rock containing calc-silicate
minerals, such as grossular, epidote, tremolite, vesuvianite, etc
tactite is a synonym
Skarn
9) Granulite
a high grade rock of pelitic, mafic, or quartzo-feldspathic parentage that is predominantly composed
of OH-free minerals
muscovite is absent
plagioclase and orthopyroxene are common
Granulite
10) Migmatite
a composite silicate rock that is heterogeneous on the 1-10 cm scale, commonly having a dark
gneissic matrix (melanosome) and lighter felsic portions (leucosome)
migmatites may appear layered, or the leucosomes may occur as pods or form a network of cross-
cutting veins
Migmatite
Additional Modifying Terms:
1) Porphyroblastic
a metamorphic rock has one or more metamorphic minerals that grew much larger than the others
each individual crystal is a porphyroblast
Some porphyroblasts, particularly in low-grade contact metamorphism, occur as ovoid “spots”
If such spots occur in a hornfels or a phyllite (typically as a contact metamorphic overprint over a
regionally developed phyllite), the terms spotted hornfels, or spotted phyllite would be appropriate
3) Other modifying terms emphasizing some aspect of a rock may concern such features as grain-size, color,
chemical aspects, (aluminous, calcareous, mafic, felsic, etc.)
as a general rule, use these when the aspect is unusual
obviously a calcareous marble or mafic greenschist is redundant, as is a fine grained slate
4) Ortho- a prefix indicating an igneous parent, and
5) Para- a prefix indicating a sedimentary parent
The terms are used only when they serve to dissipate doubt. For example, many quartzo-
feldspathic gneisses could easily be derived from either an impure arkose or a granitoid rock. If
some mineralogical, chemical, or field-derived clue permits the distinction, terms such as
orthogneiss, paragneiss, or orthoamphibolite may be useful.