山东招源硅胶有限公司
INTERNATIONAL SILICA GEL CO., LTD. (SHANDONG)
530, JINHUI ROAD, ZHAOYUAN, SHANDONG, CHINA
Tel: +86-535-8222489 8251155 Fax: +86-535-8246683 E-mail:
[email protected] Http://www.isgco.net
MSDS for Silica Gel Orange
1. Product Identification
Name Orange Silica Gel
Company International Silica Gel Co., LTD.
Address 530, JinHui Road, Zhaoyuan, Shandong, China.
Telephone number +86-535-8222489
Fax number +86-535-8246683
2. Composition/Information on the components
Chemical Description Orange to Green Indicating Silica Gel
Formula SiO2 + H2O + C25H30ClN3
CAS (R Phrase Classification) 112926-00-8 amorphous silica 98.2%, activated
colouring agent 0.2% max.
3. Health Hazard Identification
Do not breathe dust or exceed the exposure limits
4. First Aid Measures
Inhalation Remove from source of exposure.
Skin Contact Wash spillage from skin with soap and water
Eyes Contact Wash immediately with copious amounts of water and
obtain medical attention.
Ingestion Wash out mouth with water. If large amount
swallowed or symptoms develop
5. Fire Fighting Measures
Extinguishing Media Not applicable. Inorganic compound. Not
combustible.
6. Accidental Release Measures
Personnel Precautions Do not inhale. Wear appropriate protective
clothing. Dust mask essential if conditions are
dusty. See section 8 for exposure limits.
Spillages Contain spillage. Collect in suitable containers
for recovery or disposal.
During collection avoid creating dust.
山东招源硅胶有限公司
INTERNATIONAL SILICA GEL CO., LTD. (SHANDONG)
530, JINHUI ROAD, ZHAOYUAN, SHANDONG, CHINA
Tel: +86-535-8222489 8251155 Fax: +86-535-8246683 E-mail:
[email protected] Http://www.isgco.net
7. Handling and Storage
Handling Avoid creating any dust. Do not smoke. During
handling electrostatic charges can accumulate (see
BS 5958 for advice on the control of static.)
Storage All containers must be closed air tight and kept
in a dry place
8. Exposure Control / Personal Protection
Occupational Exposure Standards:
Synthetic amorphous silica Silica amorphous, total inhalable dust: UK EH40:
OES 6mg/m3 8h TWA.
Silica amorphous, respirable dust: UK EH40: OES
2.4mg/m3 8h TWA.
Silica Gel: ACGIH: TLV 10mg/m3 8h TWA.
Activation agent: ACGIH: 0.5mg/m3 8h TWA.
Engineering Control Measures Engineering methods to prevent or control exposure
are preferred. Methods include process or
personnel enclosure, mechanical ventilation
(dilution and ocal exhaust), and control of process
conditions.
Respiratory Protection Avoid inhalation of dust. Wear suitable
respiratory protective equipment if working in
confined spaces with inadequate ventilation or
whenever there is any risk of the exposure limits
being exceeded.
Hand Protection Wear protective gloves.
Eyes Protection Wear suitable eye protection.
Protection During Application Handle in well ventilated conditions in accordance
with good industrial hygiene and safety practices.
9. Physical and Chemical Properties
Aspect Beads
Colour Dry: yellow/orange Saturated: Green
Odour Odourless
pH 2-10 at 5% w/w in water
Melting Point (oC) >1000
Boiling Point Not Applicable
Flash Point Not Applicable
Explosion Limits Not Applicable
Bulk Density 720kg per cu meter (typical)
Solubility in Water less 1.0% in weight
Thermal Decomposition Stable except when saturated water released during
regeneration
山东招源硅胶有限公司
INTERNATIONAL SILICA GEL CO., LTD. (SHANDONG)
530, JINHUI ROAD, ZHAOYUAN, SHANDONG, CHINA
Tel: +86-535-8222489 8251155 Fax: +86-535-8246683 E-mail:
[email protected] Http://www.isgco.net
10. Stability and Reactivity
Stability Hygroscopic
Conditions to Avoid High temperatures in excess of 155oC
Materials to Avoid None known
Hazardous Decomposition Hygroscopic material
11. Toxicological Information
Toxicity The lethal dose for humans for synthetic amorphous
silica is estimated at over 15,000mg/kg.
Health Effects Inhalation Synthetic amorphous silica gel has little adverse
effect on lungs and does not produce significant
disease or toxic effect when exposure is kept below
the permitted limits. However existing medical
conditions (eg asthma, bronchitis) may be
aggravated by exposure to dust. Effects of dust may
be greater, and occur at lower levels of exposure
in smokers compared to non-smokers.
Eye Contact Dust may cause discomfort and mild irritation.
Skin Contact Dust may have a drying effect on the skin.
Carcinogenicity Amorphous silica is not classifiable as to its
carcinogenicity to humans (Group 3).
12. Ecological Information
Synthetic amorphous silica is virtually inert and
Ecotoxicity
has no known adverse effect on the environment.
13. Disposal
Product Disposal Product can be reactivated in an oven for re-use.
This material is not classified as hazardous waste
under EEC Directive 91/689/EEC.
Dispose of in accordance with all applicable local
and national regulations.
This material is not classified as special waste
under UK Special Waste Regulations 1996 and can be
disposed of by landfill at an approved site.
14. Transport Information
UN Class Not classified as dangerous goods under the United
Nations Transport Recommendations.
山东招源硅胶有限公司
INTERNATIONAL SILICA GEL CO., LTD. (SHANDONG)
530, JINHUI ROAD, ZHAOYUAN, SHANDONG, CHINA
Tel: +86-535-8222489 8251155 Fax: +86-535-8246683 E-mail:
[email protected] Http://www.isgco.net
15. Information on Regulation
EC Classification This product is not classified as dangerous.
S phrases Handle in accordance with good industrial hygiene
and safety practices.
Avoid inhalation of dust.
EINECS Listing Preparation – all components listed
TSCA Listing Mixture – all components listed
AICS Listing Mixture – all components listed
DSL/NDSL (Canadian) Listing Mixture – all components listed
16. Other Information
MSDS first issued 18th April 2000
MSDS first revision 20th November 2002
Date: Feb. 14, 2008
山东招源硅胶有限公司
INTERNATIONAL SILICA GEL CO., LTD. (SHANDONG)
温亭功