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Hybridisation

1. Hybridisation involves

1. Inter mixing of electron s

m
2. Inter mixing and redistribution of atomic orbitals of only one atom

co
3. Inter mixing and redistribution of atomic orbitals of different atoms

4. All of these

n.
2. The s - character in the hybrid orbital of the central atom present in SF6

io
molecule is

at
1. 25 % 2. 75 % 3. 40 % 4. 16.66 %
uc
3. The hybridization of Nitrogen in Nitrite ion is
ed

1. sp 2. sp2 3. sp3 4. sp3d

4. Hybridisation of iodine in IF7 molecule is

1. sp3d3 2. sp3d 3. sp3d2 4. dsp2

5. The molecule which contains sp3d2 and p orbitals overlapping in it is

1. PCl5
.s

2. BrF5 3. ClF3 4. IF7

6. sp3d hybridisation is not present in

1. PCl5 2. ClF3 3.SeF6 4.XeF2

7. Linear combination of two hybridised orbitals belonging to two atoms

1. Sigma bond only 2. Co-ordinate covalent bond only

3. Pi-bond only 4. Either 1 or 2

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8. Decreasing order of size of various hybrid orbitals is:

1) sp > sp 2 > sp 3 2) sp3 > sp 2 > sp 3) sp 2 > sp > sp 3 4) sp= sp2 = sp3

[Link] molecule which contains sp sp and sp p bonds in it is

1. CH3CH3 2. CH3CHO 3. CH3CH2OH 4. CHCl3

m
10. The type of hybrid orbitals used by the oxygen atom in Cl2O molecule is

co
1. sp3 2. sp2 3. sp 4. dsp2

n.
11. Bond angle between two hybrid orbitals is 180o, s - orbital character of
hybrid orbital is nearly

io
1.25 % 2.33.33% 3. 16.6 % 4. 50 %

at
12. Hybridisation of oxygen in hydronium ion is
uc
1. sp 2.sp2 3.sp3 4. d sp2
ed

13. The type of hybridisation exhibited by carbon in C3O2 [O=C=C=C=O]

1. sp 2. sp3 3. sp2 4. None

14. In which of the following species the underlined carbon having sp3-
a

hybridisation?
.s

CH 3 - COOH CH 3 CH 2 OH CH 3 COCH 3 CH 2 = CH - CH 3
1) 2) 3) 4)
w
w

15. The ratio of pure orbitals to hybridized orbitals in ethylene is

1) 2: 3 2) 3: 1 3) 1: 1 4) 1: 3

16. Which one of the following is a correct set?

1. H2O, sp3 angular 2. H2O, sp3 linear

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17. What is the hybridisation state of the central atom in the conjugate base
of NH4+ ion?

1. sp 2.sp3 3.sp2 4. d sp2

18. The hybridisation of N in CH 3 NH 2 is

m
1. sp 2. sp2 3. sp3 4. d sp2

co
19. The shape of CH4; SO4-2; PO4-3

1. Trigonal planar 3. Angular

n.
3. Tetrahedral 4. Trigonal Bipyramidal

io
20. sp3 hybrid orbital has

1. 1/4 th s - character
at
2. 1/2 th s - character
uc
3. 2/3 th s - character 4. 3/4 th s - character
ed

21. Which of the following is the most efficient overlapping?

1. sp3-sp3 3. sp3-sp2
hi

2. sp-sp 4. All
ks

22. The hybridisation of carbon in carbon dioxide molecule is

1. sp2 2. sp 3. sp3 4. None

23. The hybridisation of central atom is sp3d2 in

1. PCl5 2.BrF3 3. XeF2 4. BrF5

24. N-H Bond in Ammonia molecule is

1. s-s 2. p - p 3. sp3-s 4. sp2-p

25. sp2 s Bond is present in

1. CH4 2. NH3 3. CCl4 4. CH2 = CHCl

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26. Molecule which contains 4 bonded pairs and 2 lone pairs of electrons on
the central atom is

1. XeF2 2. CO2 3. XeF4 4. SF6

27. In which of the following molecule, the central atom undergoes sp3d
hybridisation with three lone pairs of electrons

m
1. Ammonia 2. Xenon difluoride

co
3. Chlorine trifluoride 4. Hydrogen sulphide

n.
28. Molecule having maximum number of lone pairs of electrons on central
atom is

io
1. PH3 2. H2S 3. CH4 4. BrF5

at
29. Hybridisation and bond angle in XeF4 is
uc
1) sP3 d2, 90 2) dsp2, 90
3) sp3 109 4) sp3d, 120
ed

30. Number of hybrid orbitals present in a molecule of propene is

1. 12 2. 10 3. 9 4. 8
ks

31. The number of hybrid orbitals in a molecule of Ethyne is

1. 6 2. 4 3. 8 4. 2
.s

32. The hybridisation of carbon in diamond, graphite and acetylene are

1. sp3,sp,sp2 2. sp,sp2,sp3 3. sp3,sp2,sp 4. sp2,sp3,sp

33. The structural formula of a compound is CH3 - CH = C= CH2. The types

of hybridisation at the four carbons from left to right are

1. sp3, sp, sp2, sp3 2. sp2, sp3, sp2, sp

3. sp3, sp2, sp, sp2 4. sp3, sp2, sp2, sp2

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34. As the s - character in a hybrid orbital increases, the bond angle

1. Increases 2. Decreases 3. Remains same 4. Becomes zero

35. A molecule contains two sigma bonds, two Pi bonds and one lone pair of
elecrons in the valence shell of X. The shape of molecule is

1) Linear 2) Angular 3) Tetrahedral 4) Pyramidal

m
36. Hybridisation noticed in CO2 and CO is

co
1. sp3 2. dsp2 3. sp 4. sp2

n.
37. The compound in which carbon uses sp3 hybridisation for bond

io
formation

at
1. H-COOH 2. (NH2)2C=Ouc 3. H-CHO 4. CH3CH2 OH

38. The total number of sp2 hybrid orbitals used in bonding of ethylene
molecule is
ed

1. 5 2. 6 3. 7 4. 8
hi

39. Carbon atoms C2 (CN )4 are : in

1) sp hybridized 2) sp2 hybridized

3) sp and sp2 hybridized 4) sp, and sp3 hybridized

40. On catalytic hydrogenation, ethylene gives ethane during this reaction

1. Hybridization of carbon atoms changes from sp2 to sp3

2. Bond angle decreases from1200 to 109.50

3. C-C bond length increases from1.34 A0 to 1.54A0

4. All of these.

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41. For which hybridization, there are two unequal bond angles

1. sp3 2. sp2 3. sp 4. sp3d

42. Bond angle in

1) 180 2) 120 3) 109 4) 90

43. The hybrid orbital having an equal amount of s and p - characters is

m
1. sp 2. sp3 3. sp2 4. sp3d

co
44. On hybridisation of ones and one p orbitals we get

n.
1. Two mutually perpendicular orbitals 2. Two orbitals at 180o

io
3. Four orbitals directed tetrahedrally 4. Three orbitals in a plane

at
45. Hybridisation in SO2 molecule is
uc
1. sp 2. sp2 3. sp3 4. sp3d
ed

KEY
hi
ks

1) 2 2) 4 3) 2 4) 1 5) 2 6) 3 7) 1 8) 2 9) 3 10) 1
a
.s

11) 4 12) 3 13) 1 14) 2 15) 3 16) 1 17) 2 18) 3 19) 3 20) 1
w
w

21) 1 22) 2 23) 4 24) 3 25) 4 26) 3 27) 2 28) 2 29) 1 30) 2
w

31) 2 32) 3 33) 3 34) 1 35) 2 36) 3 37) 4 38) 2 39)3 40)4

41) 4 42) 3 43) 1 44) 2 45) 2

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