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Colligative Properties

Colligative properties are solution properties that depend on the amount of solute dissolved, not the type of solute. The four main colligative properties are vapor pressure lowering, boiling point raising, freezing point lowering, and osmotic pressure. Each property can be explained using kinetic molecular theory and calculated using equations that relate the property to solute concentration and a solvent constant.

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Niveditha Sankar
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265 views3 pages

Colligative Properties

Colligative properties are solution properties that depend on the amount of solute dissolved, not the type of solute. The four main colligative properties are vapor pressure lowering, boiling point raising, freezing point lowering, and osmotic pressure. Each property can be explained using kinetic molecular theory and calculated using equations that relate the property to solute concentration and a solvent constant.

Uploaded by

Niveditha Sankar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

Colligative Properties

By definition a colligative property is a solution property (a property of mixtures)


for which it is the amount of solute dissolved in the solvent matters but the kind of
solute does not matter.
This concept is similar to kinetic molecular theory of gases in which gas molecules
were treated as indistinguishable hard spheres and (ideally) it was the number of
them, rather than the type of molecules, that determined gas properties.
This means that when considering the impact of solute on a colligative property,
1 mole of sugar 1 mole Na + 1 mole O2 1 mole urea 1 mole pickles do
exactly the same thing

The four colligative properties associated with fairly famous physical phenomena that will
explained in this project are-

Colligative properties Vapor Pressure Loweringexplains the value of


p putting antifreeze in your
R radiator to keep a car from overheating
Boiling Point Raisingexplains how you can cook p
spaghetti faster in salt water
Freezing Point Lowering explains why salt is placed n
on roads to keep ice from
Forming
Osmotic Pressure explains why your little brother killed t
the family fish when he
P placed them in pure water while cleaning the tank.

Each of these properties will explain the physical phenomenon behind the property and give explanation
on how to perform simple calculations to determine the magnitude the change in
solution state function associated with a colligative property.
Concentration and Colligative Properties
If colligative properties depend on the amount of the solute in the solvent, then the
equations defining them must include a
concentration term.
Note the similarities in structure for the equations: each equation includes a
colligative property on the left side of the equation that is set equal to a
concentration term and a solvent constant.

P vapor pressure T temperature raising or lowering osmotic pressure

P = P0 T f = -mK f = MRT

Three properties set equal to three different concentrations terms times a solvent
constant
Example:

Imagine that we are placing 50 g (0.146 mole) of the solute, sugar, in 117 g (6.5
mole) of the solvent, H 2 O.
What is (mole fraction) of 50g of sugar in 117 g of water?
=moles A = 0.146sugar = 0.022 mole fraction sugar
molesA+molesB 0.146sugar+6.5H2O

What is m (molality) of 50g of sugar in 117 g of water? Note that the molality
calculation is similar to a molarity calculation except that we divide by the mass of
the solvent in kg rather than the liters of solution.
m =moles A =0.146sugar
[Link] 0.117 , 2

kg solvent
molesA
,
=
kg H O
mole sugar
0.117 , 2
0.146 , = 1.25 molal

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