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Perhitungan Neraca Massa Ammonia 105-D

1. The document describes calculations to determine the conversion of N2 and H2 in an ammonia converter (105-D) using a mass balance method. 2. Tables show the inlet and outlet compositions and flow rates of gases like N2, H2, NH3, CH4, and Ar based on design data and actual measured data from January 15, 2017. 3. Calculations are shown to determine the mass flow rates and compositions of components at the inlet and outlet of the converter based on the molar flow rates and molecular weights of each gas.

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71 views5 pages

Perhitungan Neraca Massa Ammonia 105-D

1. The document describes calculations to determine the conversion of N2 and H2 in an ammonia converter (105-D) using a mass balance method. 2. Tables show the inlet and outlet compositions and flow rates of gases like N2, H2, NH3, CH4, and Ar based on design data and actual measured data from January 15, 2017. 3. Calculations are shown to determine the mass flow rates and compositions of components at the inlet and outlet of the converter based on the molar flow rates and molecular weights of each gas.

Uploaded by

RifqiMuhammad
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

Universitas Sriwijaya

Laporan Kerja Praktek Unit Operasi PT. PUSRI-IB

LAMPIRAN PERHITUNGAN

Perhitungan dilakukan melalui perhitungan neraca massa untuk


mennghitung konversi N2 dan H2 yang terjadi pada ammonia converter 105-D.
Adapun metode perhitungan yang dilampirkan :

Gambar 1. Skema Aliran Syn-Loop Ammonia Pusri-IB

A. Perhitungan Neraca Massa Data desain

Tabel 1. Komposisis Gas (105-D) Data Desain

Komponen Inlet (kmole/hr) Outlet (kmole/hr)


N2 5393,98 3742,58
H2 16275,62 11321,43
NH3 417,30 3720,09
CH4 1914,71 1914,71
Ar 927,17 927,17
Total 24928,78 21625,98

1. Menghitung %Komposisi

5393,98 kmole/hr
N2 = 100% = 21,64 %
24928,78 kmole/hr
Universitas Sriwijaya
Laporan Kerja Praktek Unit Operasi PT. PUSRI-IB

16275,62 kmole/hr
H2 = 100% = 65,29 %
24928,78 kmole/hr

417,30 kmole/hr
NH3 = 100% = 1,67 %
24928,78 kmole/hr

1914,71 kmole/hr
CH4 = 100% = 7,68 %
24928,78 kmole/hr

927,17 kmole/hr
Ar = 100% = 3,72 %
24928,78 kmole/hr

2. Menghitung Inlet Mass Flow Rate (kg/hr)

Mass Flow Rate = Flow Inlet Komponen A x BM Komponen A


N2 inlet mass flowrate = 5393, 98 kmole/hr 28,013 kg/kmole

= 151101,5617 kg/hr

H2 inlet mass flowrate = 16275,62 kmole/hr 2,016 kg/kmole

= 32811,64992 kg/hr

NH3 inlet mass flow rate = 417,30 kmole/hr 17,031 kg/kmole

= 7107,0363 kg/hr

CH4 Inlet Mass Flow Rate = 1857,94 kmole/hr 16,04 kg/kmole

= 29801,3576 kg/hr

Ar inlet mass flow rate = 927,17 kmole/hr 35,968 kg/kmole

= 33348,45056 kg/hr

3. Menghitung %Komposisi gas outlet

3742,58 kmole/hr
N2 = 100% = 17,31 %
21625,98 kmole/hr

11321,43 kmole/hr
H2 = 100% = 52,35 %
21625,98 kmole/hr

3720,09 kmole/hr
NH3 = 100% = 17,20 %
21625,98 kmole/hr
Universitas Sriwijaya
Laporan Kerja Praktek Unit Operasi PT. PUSRI-IB

1914,71 kmole/hr
CH4 = 100% = 8,85 %
21625,98 kmole/hr

927,17 kmole/hr
Ar = 100% = 4,29 %
21625,98 kmole/hr

4. Menghitung Outlet Mass Flow Rate (kg/hr)

Mass Flow Rate =Flow Outlet Komponen A x Berat Molekul Komponen A

N2 outlet mass flow rate = 3742,58 kmole/hr 28,013 kg/kmole

= 104840,8935 kg/hr

H2 outlet mass flow rate = 11321,43 kmole/hr 2,016 kg/kmole

= 22824,00288 kg/hr

NH3 outlet mass flow rate= 3720,09 kmole/hr 17,031 kg/kmole

= 63359,85279 kg/hr

CH4 outlet mass flow rate= 1914,71 kmole/hr 16,04 kg/kmole


= 30711,9484 kg/hr

Ar outlet mass flow rate = 927,17 kmole/hr 35,968 kg/kmole

= 33348,45056 kg/hr

B. Perhitungan Neraca Massa Data Aktual

Tabel 2. Komposisi gas inlet dan outlet 105-D tanggal 15 Januari 2017
%
Kompone %Komposisi
Komposisi
n mol outlet
mol inlet
Ar 2,43 2,85
N2 22,01 18,28
H2 66,03 54,1
CH4 8,1 9,22
NH3 1,45 15,55

Flowrate inlet total : 505,686 x 103 m3/h

1. Menghitung Inlet Mass Flow Rate (kg/h)


Universitas Sriwijaya
Laporan Kerja Praktek Unit Operasi PT. PUSRI-IB

a) Berat Massa Rata-Rata


2,43
Ar = 39,95 kg/kmol= 0,97 kg/kmol
100
22,01
N2 = 28,013 kg/kmol = 6,17 kg/kmol
100
66,03
H2 = 2,016 kg/kmol= 1,33 kg/kmol
100
8,1
CH4 = 16,04 kg/kmol= 1,3 kg/kmol
100
1,45
NH3 = 17,031 kg/kmol= 0,25 kg/kmol
100

Total
= 0,97 kg/kmol + 6,17 kg/kmol + 1,33 kg/kmol + 1,3 kg/kmol + 0,25 kg/kmol

= 10,02 kg/kmol
b) Mencari mass flow rate
505,686 x 103 m3/h x 10,02 kg/kmol
m= = 226204,184 kg/h
22,4 m3/kmol
c) Mencari mass flowrate inlet tiap komponen
0,97
Ar = 226204,184 kg/h = 21898,0098 kg/h
10,02
6,17
N2 = 226204,184 kg/h = 139289,4027 kg/h
10,02
1,33
H2 = 226204,184 kg/h= 30025,1063 kg/h
10,02
1,3
CH4 = 226204,184 kg/h = 29347,8482 kg/h
10,02
0,25
NH3 = 226204,184 = 5643,817 kg/h
10,02

2. Menghitung Outlet Mass Flow Rate (kg/h)

a) Berat Massa Rata-Rata


2,85
Ar = 39,95 kg/kmol= 1,14 kg/kmol
100
18,28
N2 = 28,013 kg/kmol = 5,12 kg/kmol
100
54,1
H2 = 2,016 kg/kmol= 1,09 kg/kmol
100
9,22
CH4 = 16,04 kg/kmol= 1,48 kg/kmol
100
15,55
NH3 = 17,031 kg/kmol= 2,65 kg/kmol
100
Universitas Sriwijaya
Laporan Kerja Praktek Unit Operasi PT. PUSRI-IB

Total
= 1,14 kg/kmol + 5,12 kg/kmol + 1,09 kg/kmol + 1,48 kg/kmol

+ 2,65 kg/kmol

= 11,48 kg/kmol
b) Mencari mol flow rate out
226204,18 4 kg/h
m= = 19704,1972 kg/h
11,48 kg/kmol
c) Mencari mol flow rate out tiap komponen
1,14
Ar = 19704,1972 kmol/h = 561,5696 kmol/h
11,48
18,28
N2 = 19704,1972 kmol/h = 3601,9272 k mol /h
11,48
54,1
H2 = 19704,1972 kmol/h= 10659,9707 k mol /h
11,48
9,22
CH4 = 19704,1972 kmol/h = 1816,727 k mol /h
11,48
15,55
NH3 = 19704,1972 kmol/h = 3064,0027 k mol /h
11,48

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