MAKTAB RENDAH SAINS MARA PDRM

KULIM, KEDAH.

THERMOCHEMISTRY

[PAPER 1]

PREPARED BY

CHEMISTRY UNIT
MRSM PDRM 2006
1. Reaction between iron and copper (II) sulphate solution is exothermic reaction.
Which of the following diagram, represented by the above reaction.

A.

B.

C.

D.

2. The equation below shows a precipitation Barium sulphate reaction.

Ba 2 (aq) + SO 24 (aq) BaSO 4 ( s ) = -42kJ mol 1

What is the total amount of heat when 50 cm 3 of 2 mol dm 3 Barium Chloride

solution reacts with 50 cm 3 of 2 mol dm 3 Sodium sulphate solution in
polystyrene cup.

A. 2.1 kJ C. 8.4 kJ
B. 4.2 kJ D. 21 kJ

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3. Which of the following neutralization reactions release the least heat?

A. Nitric acid and sodium hydroxide

B. Sulphuric acid and potassium hydroxide
C. Ethanoic acid and sodium hydroxide
D. Hydrochloric acid and potassium hydroxide

4. Yogurt is prepared by adding 20.0 cm 3 of lime juice into 200.0 cm 3 fresh milk.
It is found that the temperature of the yogurt increase by 2.0C.
What is the total amount of heat released? Use the information that the specific
heat capacity of yogurt = X J g 1 C 1 . Assume that 1 cm 3 of solution is equal
to 1 gram of solution.

A. 40 x J C. 400 x J
B. 220 x J D. 440 x J

5. The equation below shows a displacement reaction and its heat of reaction.

Mg + Fe 2 Mg 2 + Fe = -189 kJ mol 1

Which of the following statements are true about the reaction represented by the
above equation?

I. Magnesium is oxidized
II. The reaction is exothermic
III. The temperature decrease during the reaction
IV. The heat released by reacting 0.2 mole of ferum (II) ions is 37.8 kJ

A. I and II only C. III and IV only

B. II and IV only D. I, II and Iv only

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6. Figure 1 shows an energy level diagram.

Based on figure 1 what is the increase in temperature of the solution if excess J

powder is added to 50 cm 3 of T salt solution 0.2 mol dm 3 ?
(Specific heat capacity of solution : 4.0 Jg 1 C 1 )

A. 4.4 C C. 8.8 C
B. 5.5 C D. 11.0 C

7. Figure 2 shows a set-up of apparatus to determine the heat of reaction.

Based on figure 2 which of the following statements are true?

I. The process of bonding occurs

II. Temperature increases during the reaction
III. The value in the reaction is positive
IV. The energy content of the products of reaction is higher than that of the
reactants

A. I and II only C. I, II and IV only

B. III and IV only D. I, II, III and IV

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8. The diagram shows the energy level for the displacement reaction of copper by
zinc.

What is the total amount of heat released when 50.0 cm 3 of 0.5 mol dm 3
copper(II) sulphate solution reacts in access zinc.

A. 5.4 kJ C. 21.6 kJ
B. 8.68 kJ D. 54.0 kJ

9. The following equation shows the reaction between Ag and Cl ions.

Ag ( aq ) + Cl ( aq ) AgCl ( s ) = -65kJ mol 1

Which of the following is true about the above equation?

A. Endothermic reaction occurs

B. Heat is released to the surroundings
C. The temperature of the product decreases
D. 65 kJ of heat is absorbed when 1 mole of silver chloride is formed

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10. The following is the energy level diagram of a reaction.

Which of the following acids is suitable to replace nitric acid, HNO 3 to obtain the
same value?

A. Ethanoic acid, CH 3 COOH

B. Carbonic acid, H 2 CO 3
C. Sulphuric acid, H 2 SO 4
D. Hydrocloric acid, HCl

11. In an experiment 100 cm 3 of dilute hydrochloric acid solution is mixed with 100
cm 3 sodium hydroxide solution in a polystyrene cup. The concentration S of two
solutions are the same. During the mixing the temperature of the mixture
increased by 7C.

What is the heat released in the experiment?

Given that the specific heat capacity of the solution is 4.2 Jg 1 C.

A. 1470 J C. 4410 J
B. 2940 J D. 5880 J

12. Figure 3 shows an energy level diagram.

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 Based on Figure 3 it can be concluded that

A. the heat of neutralization is -57 kJ mol 1

B. 57 of energy is needed for the reaction
C. the products of reaction contains more energy than the reactants
D. the temperature at the end of the reaction is lower than that at the
beginning of the reaction

13. The following is an energy level diagram.

What conclusion can be made from the diagram?

A. the product contains more energy than the reactants

B. OH ions contain more energy that H ions
C. heat is needed to initiate the reaction
D. heat is released in this reaction

14. The table shows the heat of combustion of three alcohols.

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 Alcohol Heat of combustion / kJ mol 1
CH 3 OH - 710
- 1310
C 2 H 5 OH
- 2670
C 4 H 9 OH

Which of the following factor increases the heat of combustion of alcohol?

A. Size of molecules decreases

B. Number of carbon atoms per molecule increases
C. Number of oxygen atom per molecule increases
D. Number of hydrogen atom per molecule decreases

15. 20cm 3 of 2moldm 3 of sodium hydroxide solution was added to 10cm 3

2moldm 3 of sulphuric acid which was placed in a plastic beaker. Among the
following, which one is the most accurate to describe the product?

A. The number of moles of H is more than the number of moles of OH

B. The number of moles of OH is more than the number of moles of H
C. The number of moles of H and OH is the same
D. Energy level of the product is higher than the energy level of sodium
hydroxide solution and sulphuric acid used.

16. When 50cm 3 of 2.0moldm 3 of hydrochloric acid is added to 50cm 3 of

2.0moldm 3 potassium hydroxide, there is a raise of temperature of 13C.
Among the mixtures of hydrochloric acid and potassium hydroxide listed below,
which one will give the same raise of temperature?

Potassium Hydroxide Solution Hydrochloric Acid

Volume / cm 3 Molarity / Volume / cm Molarity /
mol dm 3 3
mol dm 3
A 50 1.0 50 1.0
B 50 1.0 50 2.0
C 100 2.0 100 2.0
D 100 2.0 100 1.0

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17. 50 cm 3 of 2 moldm 3 of hydrochloric acid is added to 100cm 3 2.0 moldm 3
of sodium hydroxide solution to produce xkJ heat. Find the volume of 0.8 moldm
3
of sulphuric acid which is added to 100 cm 3 of 2 moldm 3 of sodium
hydroxide needed to release xkJ heat too.

A. 50.0cm 3 C. 75.0cm 3
B. 62.5cm 3 D. 100.0cm 3

18. HCl(aq) + NaOH(aq) NaCl(aq) + H 2 O( ) H = -57kJmol 1 .

The chemical equation given above represents the reaction between hydrochloric
acid and sodium hydroxide. Among the following reactions, which one will
produce H value less than the reaction above?

A. NH 4 OH + HCl NH 4 Cl + H 2 O
B. H 2 SO 4 + 2 KOH K 2 SO 4 + 2H 2 O
C. NaOH + HNO 3 NaNO 3 + H 2 O
D. HCl + KOH KCl + H 2 O

Mixture Volume of 2mol dm 3 of Volume of 2 mol dm 3

Hydrochloric acid / cm 3 of natrium hydroxide / cm
3

W 20 30
X 25 30
Y 30 30
Z 35 30

Table 1

19. 4 mixtures W, X, Y and Z were produced by mixing a variety of volume of 2 mol

dm 3 of hydrochloric acid with 2 mol dm 3 of sodium hydroxide solution as
shown in Table 1. Among the mixtures given below, which one will raise the
highest temperature?

A. W C. Y
B. X D. Z

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20. The heat of neutralization between hydrochloric acid and natrium hydroxide is
-57kJmol 1 . What is the quantity of heat and the rise of temperature released
by the mixture when 200 cm 3 of 2 mol dm 3 of hydrochloric acid is added to
300 cm 3 of 1 mol dm 3 of sodium hydroxide solution?
[specific heat capacity of the solution = 4 J/gC]

Quantity of heat Temperature rise /C

A 17.1 8.55
B 17.1 14.25
C 22.8 7.55
D 22.8 11.40

21. The heat of neutralization between methanoic acid and sodium hydroxide is
lower than the heat of neutralization between hydrochloric acid and sodium
hydroxide because

A. methanoic acid is less reactive than hydrochloric acid

B. methanoic acid is a weak acid while hydrochloric acid is a strong acid
C. methanoic acid is an organic acid while hydrochloric is a mineral acid
D. some of the energy released from the reaction between methanoic acid
and sodium hydroxide is used to break the OH bond in methanoic acid

22. When 50cm 3 1 mol dm 3 sodium hydroxide solution is added to 50 cm 3 1

mol dm 3 of hydrochloric acid, the temperature rises tC. Among the X and Y
solutions below, which one will produce tC rise of temperature when added
together?

X solution Y solution
I 75 cm 3
1 mol dm 3 sodium 75 cm 3
1 mol dm 3 of
hydroxide solution hydrochloric acid
II 25 cm 3 2 mol dm 3 sodium 25 cm 3 2 mol dm 3 of
hydroxide solution hydrochloric acid
III 30 cm 3 1 mol dm 3 of sodium 30 cm 3 1 mol dm 3
hydroxide solution hydrochloric acid
IV 25 cm 3 0.5 mol dm 3 of sodium 25 cm 3 0.5 mol dm 3 of
hydroxide solution hydrochloric acid

A. I and III only C. II and III only

B. I and IV only D. III and IV only

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23. Among the mixture of acids and alkalis given below, which one will release the
same quantity of heat as when 1 mol of acid and 1 mol of alkali is added?

I. Hydrochloric acid and sodium hydroxide

II. Nitric acid and potassium hydroxide
III. Sulphuric acid and aqueous ammonia
IV. Ethanoic acid and sodium hydroxide

A. I and II only C. I, II and III only

B. I and IV only D. I, II and IV only

24. When 20 cm 3 1.0 mol dm 3 sodium hydroxide solution was mixed with 20 cm
3
of 1.0 mol dm 3 of hydrochloric acid, the temperature of the mixture rose tC.
Which of the following mixtures of acid and alkali will give the same rise in
temperature?

I. 20 cm 3 1.0 mol dm 3 potassium hydroxide and 20 cm 3 1.0 mol dm 3

nitric acid
II. 20 cm 3 2.0 mol dm 3 of sodium hydroxide and 20 cm 3 2.0 mol dm 3
of hydrochloric acid
III. 40 cm 3 1.0 mol dm 3 of sodium hydroxide and 40 cm 3 1.0 mol dm 3
of hydrochloric acid
IV. 20 cm 3 1.0 mol dm 3 of sodium hydroxide and 20 cm 3 1.0 mol dm 3
of ethanoic acid

A. I only C. I and IV only

B. I and III only D. I, II and IV only

25. When 100 cm 3 of 1 mol dm 3 of sodium hydroxide is added to 100 cm 3 of 1

mol dm 3 of hydrochloric acid, the maximum rise of temperature is 7C. Among
the following mixtures, which one will produce the maximum rise of temperature
of 14C?

A. 100 cm 3 of 1 mol dm 3 of sodium hydroxide and 100 cm 3 of 4mol dm

3
hydrochloric acid
B. 200 cm 3 of 1.0 mol dm 3 of sodium hydroxide and 200 cm 3 of 1.0 mol
dm 3 hydrochloric acid
C. 50 cm 3 of 1.0 mol dm 3 of sodium hydroxide 50 cm 3 of 1.0 mol dm
3
of hydrochloric acid
D. 50 cm 3 of 2.0 mol dm 3 of sodium hydroxide and 50 cm 3 of 2.0 mol
dm 3 of hydrochloric acid

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26. Which of the following is a chemical equation for combustion.

A. Zn + CuSO 4 ZnSO 4 + Cu
B. HCl + NaOH H 2 O + NaCl
C. CuSO 4 . 5H 2 O CuSO 4 + 5H 2 O
D. CH 4 + 2O 2 CO 2 + 2H 2 O

27. C 3 H 8 + 5O 2 3CO 2 + 4H 2 O H = -2200 kJmol 1

Which of the following energy diagrams represented the reaction given above?

A.

B.

C.

D.

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28. Table 2 shows examples of chemical reaction.

Reaction H Value
I Combustion of methane in excess oxygen 882.0 kJ mol 1
II Combustion of propane in excess oxygen 2202.0 kJ mol 1
III Combustion of ethanol in excess oxygen
1371.0 kJ mol 1

Determine the heat of combustion of methanol?

A. 283.0 kJ mol 1 C. 1542.0 kJ mol 1

B. 715.0 kJ mol 1 D. 2010.0 kJ mol 1

29. Table 3 shows chemical equation for combustion.

Fuel Chemical equation

I Hidrogen 1
H2 + O2 H2 O
2
II Ethanol C 2 H 5 OH + 3O 2 2CO 2 + 3H 2 O
III Methane CH 4 + 2O 2 CO 2 + 2H 2 O
IV Carbon C + O 2 CO 2

Base of the information above which heat of combustion is the highest

A. Hidrogen C. Methane
B. Ethanol D. Carbon

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30. Figure 4 shows the set up of apparatus to determine the heat of combustion of
ethanol. The value heat of combustion in this experiment is -1293 kJ mol 1 .

Which of the following is not true about this experiment?

A. 1293 kJ mol 1 absorbed

B. Total heat of combustion prophand in teory is 1376 kJ mol 1
C. Chemical equation for combustion ethanol is 2C 3 H 7 OH + 9O 2 8H 2
O + 6CO 2
D. Fuel value is also known as heat value.

31. CH 4 + 2O 2 CO 2 + 2H 2 O H = -400 kJmol 1

Calculate energy change in the reaction when 12 dm 3 methane combusted in

excess oxygen in room condition.
(Molar volume : 24 dm 3 at room condition, Relative atomic Mass C = 12, H = 1)

A. 188 kJ C. 210 kJ
B. 189 kJ D. 200 kJ

Alcohol A
C X and water
Complete
combustion

32. Figure 5 shows the flow of conversions related to alcohol A which of the following
is a chemical equation for a reaction.

A. C4 H 9 OH 2[0] C 3 H 7 COOH + H 2 O
B. C4 H 9 OH
C4 H8 + H2 O

C. C4 H 9 OH + 30 2 2CO 2 + 3H 2 O
D. C4 H 9 OH C 4 H 9 + H 2 O

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33. The Thermochemical equation below represents the combustion of methane in
excess oxygen.

CH 4 + 2O 2 CO 2 + 2H 2 O H = -890 kJmol 1

Which of the following are true when 3.2 g methane was burnt in excess oxygen?
[Relative atomic mass H = 1, C = 12, O = 16, molar volume of gas 24 dm 3 at
room conditions].

I. 178 kJ heat was evolved

II. 0.2 mol of oxygen used
III. 7.2 g water produced
IV. 240 cm 3 carbon dioxide evolved

A. I and III only C. I, II and III only

B. II and IV only D. I, II, III and IV

34. Calculate mass of propane need to combusted when 100 kJ heat was evolved.
[Relative atomic mass H = 1, C = 12]

A. 0.1 g C. 1.0 g
B. 0.5 g D. 2.0 g

1
H2 + O2 H2 O H = -242 kJmol 1
2

35. Which of the following is true base on the Thermochemical equation above.
(Relative Atomic mass, H = 1, O = 16)

A. 1 mol of oxygen used C. 242 kJ heat was evolved

B. 1 g of Hidrogen used D. 17 g water produced

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36. Determine the energy change in the reaction when 66 g carbon dioxide is
produce? Relative atomic mass C = 12, O = 16.

A. 200 kJ C. 700 kJ
B. 600 kJ D. 800 kJ

The mass of combusted alcohol = 0.23 g

The mass of heated water = 0.5 kg
The raise of temperature = 20C
Specific heat capacity = 4 Jg 1 C 1
Molar mass alcohol P = 46 g mol 1
Density of water = 1.0 g cm 3

37. Base on the information above, calculate heat of combustion of alcohol P.

A. 8 000 kJ mol 1 C. 3680 kJ mol 1

B. 4 000 kJ mol 1 D. 1840 kJ mol 1

38. C 6 H 12 O 6 + 6O 2 6CO 2 + 6H 2 O H = 2500 kJmol

Calculate the energy change in the reaction when 1.35g glucose is use to heat
up 200 cm 3 water.

A. 18.75 kJ C. 17.75 kJ
B. 18.85 kJ D. 16.65 kJ

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39. The Thermochemical equation below represents the combustion in excess
oxygen.

1
CO + O 2 CO 2 H = -280 kJ mol 1
2
CH 4 + 3O 2 2CO 2 + 2H 2 O H = -900 kJ mol 1
C 2 H 5 OH + 3O 2 2CO 2 + 3H 2 O H = -1400 kJ mol 1
C 3 H 8 + 5O 2 3CO 2 + 4 H 2 O H = -2200 kJ mol 1

Which of the following are true when 1000 kJ heat was evolved.
Relative atomic mass H = 1, C = 12, O = 16.

I. 100g carbon monoxide

II. 17.8 g methane
III. 32.9 g ethanol
IV. 20g propane

A. I only C. III and IV only

B. I and II only D. I, II, III and IV

40. Which of the following shows an ascending order heat of combustion?

A. carbon, hydrogen, propane

B. Hydrogen, carbon, propane
C. Propane, hydrogen, carbon
D. Carbon, propane, hydrogen

[c: KIMIA]Ily

ANSWER (THERMOCHEMISTRY)

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1. C 11. D 21. B 31. D

2. B 12. A 22. A 32. C

3. C 13. D 23. A 33. A

4. D 14. B 24. B 34. D

5. A 15. C 25. B 35. C

6. D 16. C 26. D 36. B

7. A 17. B 27. C 37. A

8. B 18. A 28. B 38. A

9. B 19. C 29. B 39. D

10. D 20. D 30. A 40. B

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