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how to

add color
to your ceramic art

a guide to using ceramic colorants,

ceramic stains, and ceramic oxides
This special report is brought to you with the support of LHUCA

How to Add Color to Your Ceramic Art

A Guide to Using Ceramic Colorants, Ceramic Stains and

Ceramic Oxides
Adding color to your ceramic art can be a tricky proposition. Unlike working with paints, what you put on your prize pot or
sculpture can look very different after firing compared to what they look like before firing. As a general rule, ceramic stains
and ceramic pigments look pretty much the same before and after firing while ceramic oxides like iron oxide, cobalt oxide,
and copper oxide as well as cobalt carbonate and copper carbonate all look very different. In this guide youll discover a
little help to better understand what, how, and why ceramic colorants work in a glaze. Enjoy!

The World of Ceramic Colorants

by Robin Hopper
The potters palette can be just as broad as the painters because there are so many
ceramic colorants and combinations to choose from. By combining ceramic oxides,
ceramic stains, and ceramic pigments in various proportions, you can get virtually
every color in the spectrum.

The Many Faces of Iron Oxide

by Dr. Carol Marians
Glaze ingredients, the clay body, firing atmosphere, and even kiln-stacking techniques
can all affect your firing results. Red iron oxide is one of the ceramic colorants thats
quite temperamental and affected by a lot of variables. From dark brown to unusual
speckles, red iron oxide can offer a lot for a single ceramic colorant.

Discovering New Glaze Colors

with Ceramic Stains
By John Britt
Commercially prepared ceramic pigments, commonly referred to as ceramic stains,
expand the potters palette with infinite color options. Ceramic pigments are easy to
use and the simplest way to introduce a wide range of color into your work.

How Lana Wilson Uses Ceramic Pigments

by Annie Chrietzberg
Lana Wilsons work is mostly black and white with bits of vibrant color splashed
about. She gets her color from ceramic pigments mixed with a clay slip which she
makes from a commercial clay body. She explains how to mix the slip, how much
ceramic pigment to add for each color, and how to use the glaze on a finished piece.

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The World of
Ceramic Colorants
by Robin Hopper

Red to Orange

The potters palette can be just as broad as the painters.

Different techniques can be closely equated to working in
any of the two-dimensional media, such as pencil, pen and
ink, pastel, watercolor, oils, encaustics or acrylics. We also
have an advantage in that the fired clay object is permanent,
unless disposed of with a blunt instrument! Our works may
live for thousands of yearsa sobering thought.
Because a number of colors can only be achieved at low
temperatures, you need a series of layering techniques in
order to have the fired strength of stoneware or porcelain
and the full palette range of the painter. To accomplish this,
low-temperature glazes or overglazes are made to adhere
to a higher-fired glazed surface, and can be superimposed
over already existing decoration. To gain the full measure
of color, one has to fire progressively down the temperature
range so as not to burn out heat-sensitive colors that cant
be achieved any other way. Usually the lowest and last firing
is for precious metals: platinum, palladium, and gold.
For the hot side of the spectrumred, orange, and yellowthere are many commercial body and glaze stains, in
addition to the usual mineral colorants. Ceramists looking for difficult-to-achieve colors might want to consider
prepared stains, particularly in the yellow, violet, and purple
ranges. These colors are often quite a problem with standard minerals, be they in the form of oxides, carbonates,
nitrates, sulfates, chlorides or even the basic metal itself.
Minerals that give reds, oranges, and yellows are copper, iron, nickel, chromium, uranium, cadmium-selenium,
rutile, antimony, vanadium, and praseodymium. Variations in glaze makeup, temperature and atmosphere
profoundly affect this particular color range. The only
materials which produce red at high temperatures are copper, iron, and nickel. The results with nickel are usually
muted. Reds in the scarlet to vermilion range can only be
achieved at low temperatures.
The chart should help pinpoint mineral choices for
desired colors (note that the color bars are for guidance
only and not representative of the actual colorsEd.).
Colors are listed with the minerals needed to obtain them,
approximate temperatures, atmosphere, saturation percentage needed, and comments on enhancing/inhibiting
factors. Because of the widely variable nature of ceramic
color, there are many generalities here. Where the word
vary occurs in the column under Cone, it signifies that
the intended results could be expected most of the time at
various points up to cone 10.

COLORANT

CONE ATMOS. %

COMMENTS

Dark Red
Copper

Vary

Red. 0.5%-5% Best in glazes containing less than 10% clay content,
and a high alkaline content. Needs good reduction.
In low temperatures it can be reduced during cooling. Good reds as low as cone 018.

Iron

Vary

Both 5%-10% Good in many glaze bases at all temperatures. Can

be improved with the addition of 2%-5% tin oxide.

Nickel

4-10

Ox.

5%-8% Use in barium-saturated glazes.

Burgundy
Iron
Copper

See Dark Red, Iron.

See Dark Red, Copper.

Owing to the unstable nature of copper, this colorant

can produce a wide range of results. Very controlled
reduction firing and cooling are important.

Maroon
Chrome-Tin Stains

Vary

Ox.

1%-5% Use in glazes with calcium. There should be no zinc

in the glaze.

Copper

Vary

Red. 0.5%-5% Best in high alkaline glazes.

8-10

Red. 1%-5% Try various blends of copper (1%-5%) and titanium

(2%-5%).

Crimson
Copper + Titanium

Calcium-Selenium Stains 010-05 Ox.

0.5-5% Best with special frits.

Indian Red
Iron

Vary

Both 5%-10% Best in high calcium glazes; small amount of bone

ash helps. Tin addition up to 5% also helps. Also
works well in ash glazes.

Vary

Both 5%-10% Similar to Indian Red. Tin to 2% helps.

Iron + Rutile

Vary

Both 1%-10% Various mixtures (up to 8% iron and 2% rutile) in

most glaze bases.

Iron + Tin

Vary

Both 1%-5% Various mixtures (up to 4% iron and 1% tin) in most

glaze bases. Creamier than iron with rutile.

Brick Red
Iron
Orange-Brown

Orange-Red
Cadmium012-05 Ox.
Selenium Stains

1%-4% Best with special frits such as Ferro 3548 or 3278 or

both. Helps to opacify with zirconium.

Orange
Iron

Vary

Both 1%-5% Use in tin or titanium opacified glazes.

Rutile

Vary

Both 5%-15% Many glaze types, particularly alkaline. More successful in oxidation.

Copper

8-10

Both 1%-3% Use in high alumina or magnesia glazes. Addition of

up to 5% rutile sometimes helps.

Iron

Vary

Both 2%-5% With tin or titanium opacified glazes.

Rutile

Vary

Ox. 1%-10% Best with alkaline glazes.

Iron

Vary

Both 1%-10% Use in high barium, strontium or zinc glazes.

Iron + Tin

Vary

Ox.

Iron + Rutile

Vary

Both 1%-5% Various mixtures (up to 2.5% iron and 2.5% rutile)
in many glaze bases.

Orange-Yellow

Yellow Ocher

VanadiumVary
Zirconian Stains

Ox.

1%-5% Various mixtures (up to 3.5% iron and 1.5% tin) in

many glaze bases.

5%-10%Various mixtures in many Zirconium stain

glaze bases.

Lemon Yellow
Praseodymium Stains Vary

Both 1%-10% Good in most glazes. Best in oxidation.

Pale/Cream Yellow
Iron + Tin

Vary

Both 2%-5% Various mixtures (up to 3.5% iron and 1.5% tin)
in high barium, strontium or zinc glazes. Titanium
opacification helps.

Vanadium

Vary

Both 2%-5% Use in tin-opacified glazes.

Rutile + Tin

Vary

Ox.

2%-5% Various mixtures (up to 2.5% iron and 2% tin) in

variety of glaze bases. Titanium opacification helps.

Note: Colors bars are for visual reference only,

and do not represent actual colors.

www.ceramicartsdaily.org | Copyright 2014,

2010, Ceramic Publications Company | How to Add Color to Your
your Ceramic Art | 2

Yellow-Green to Navy Blue

The cool side of the glaze spectrum (from yellowgreen to navy blue) is considerably easier, both
to produce and work with, than the warm. In the
main, colorants that control this range create far
fewer problems than almost any of the red, orange,
and yellow range. Some are temperature and atmosphere sensitive, but thats nothing compared to the
idiosyncrasies possible with warm colors.
COLORANT

CONE ATMOS. %

COMMENTS

Yellow Green
Vary

Both 2%-10% Various mixtures in a wide variety of glazes, particularly those high in alkaline materials. Almost any yellow glaze to which copper is added will produce yellow
green.

Chromium

Vary

Both 0.5%-3% In yellow glazes without tin or zinc.

Chromium

4-8

Ox. 0.25%-1% In saturated barium glazes.

018-015 Ox.

Cobalt

0-2%

In high alkaline glazes with no tin.

0-1%

In any yellow glazes.

Vary

Both

Copper

Vary

Ox.

Cobalt

Vary

Both

0-2%

In glazes opacified with titanium, or containing rutile.

Vary

Both

0-2%

In various glazes without zinc or tin. Good in alkaline glazes with zirconium opacifiers. Also use
potassium dichromate.

Light Green
0-2.5% In various glazes except those high in barium or magnesium. Best in glazes opacified with tin or titanium.

Apple Green
Chromium

COLORANT

CONE ATMOS. %

Copper

Vary

Ox. 1%-10% In high alkaline and barium glazes. Bluish with

no clay content; tends toward greenish tint with
added clay.

Copper + Rutile

Vary

Both 1%-5% In high alkaline and barium glazes.

Copper + Tin

Vary

Ox. 1%-10% In high alkaline and barium glazes; usually opaque.

Light Blue
Nickel

Vary

Ox.

Rutile

Vary

Red. 1%-5% In a wide range of glazes; best with low (10% or

less) clay content.

Cobalt

Vary

Both 0.25%-1% Use in most glazes, particularly those opacified with

tin. Also use mixed with small amounts of iron.

1%-2% See Light Green; use in non-opacified glazes.

6-10

Red. 0.25%-1% In high alkaline or calcium clear glazes. Black iron is

generally preferable to red iron.

Vary

Both 0.5%-2% In most glazes; small amounts of cobalt with iron,

manganese or nickel yield soft blues. Added tin gives
pastel blue.

Wedgewood Blue
Cobalt + Iron

Celadon Green
Vary

Copper

Vary

Red 0.5%-2% Best with high sodium, calcium or potassium glazes.

Do not use with zinc glazes.
Ox. 0.5%-2% Good in a wide range of glazes.

Grass Green
Copper

010-2

Ox.

Chromium

018-04 Ox.

1%-5% In high lead glazes; sometimes with boron.

1%-2% In high alkaline glazes.

Olive Green
Nickel

Vary

Both 1%-5% In high magnesia glazes; matt to shiny olive green.

Iron

Vary

Red. 3%-5% In high calcium and alkalines, usually clear glazes.

Hookers Green
Copper + Cobalt

Vary

Ox.

Cobalt +

Vary

Both 2%-5% In a wide variety of glaze Chromium bases: no zinc or

tin. Good opacified with zirconium or titanium.

2%-5% In a wide variety of glaze bases.

06-12 Both 2%-5% In most glazes; no zinc or tin.

Dark Green
Copper

Cobalt + Manganese Vary

Both 0.5%-2%

Cobalt + Nickel

Vary

Both 0.5%-2%

Cobalt

4-10

Both 0.5%-3% In high zinc glazes.

Nickel

4-10

Ox.

1%-3% In high barium/zinc glazes; likely to be crystalline.

Blue Gray
Nickel

Vary

Ox. 0.5%-5% In high barium/zinc glazes.

Rutile

Vary

Red. 2%-5% In a wide variety of glazes, particularly high alumina

or magnesia recipes.

Cobalt + Manganese Vary

Both 0.5%-2% In most opaque glazes.

Cobalt

Vary

Ox. 0.5%-5% In high zinc glazes.

Vary

Both 0.5%-5% In high barium, colemanite, and calcium glazes; no

zinc, magnesium or opacification.

Cobalt

Vary

Both 0.5%-5% In glazes containing cryolite of fluorspar.

Cobalt + Chromium

Vary

Both 2%-5% In most glazes except those containing zinc or tin.

6-10

Ox. 5%-10% In high barium/zinc glazes.

Ultramarine
Cobalt
Cerulean Blue

Chrome Green
Chromium

1%-2% In high zinc or barium glazes.

Celadon Blue
Iron

Copper

Iron

COMMENTS

Turquoise

Copper + Rutile

Chromium

The colorants known for creating cool hues

are copper, chromium, nickel, cobalt, iron,
and sometimes molybdenum. For variations,
some are modified by titanium, rutile, manganese or black stains. The usual three variables
of glaze makeup, temperature, and atmosphere
still control the outcome, though it is less obvious in this range.

Vary

Ox. 5%-10% Many glaze bases, particularly high barium,

strontium, zinc or alkaline with a minimum of
10% kaolin.

Cobalt + Chromium

Vary

Both 5%-10% Blends of these colorants will give a wide range of

dark greens.

Cobalt + Rutile

Vary

Both 5%-10% Dark greens with blue overtones.

Cobalt + Rutile

Vary

Both 1%-5% In a wide variety of glazes.

Cobalt + Chromium

Vary

Both 1%-5% In most glazes without tin or zinc.

Teal Blue

Prussian Blue
Nickel

Cobalt + Manganese Vary

Both 5%-10% In most glaze bases.

Cobalt + Manganese Vary

Both 5%-10% In most glazes; for example, cobalt 2%, chromium

2% and manganese 2%.

Navy Blue
Cobalt

Vary

Both 5%-10% In most glazes except those high in zinc, barium or

magnesium.

Note: Colors bars are for visual reference only,

and do not represent actual colors.

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2010, Ceramic Publications Company | How to Add Color to Your
your Ceramic Art | 3

Indigo to Purple

The indigo-to-purple part of the color wheel is small

but significant. The colorants that produce this range
are nickel, cobalt, manganese, umber, iron, chromium, rutile ilmenite, copper, iron chromate, and
black stains. In short, one could say that the colorants needed include just about the whole group that
are used for all the other colors in the spectrum. The
only ones I havent talked about previously in this
articles series are umber, ilmenite, iron chromate,
and black stains.
Black Stains Formulated from a variable mixture of
other colorants, black stains are usually rather expensive due to their being saturations of colorant materials.
Various companies produce black stains usually from
a combination of iron, cobalt, chromium, manganese,
iron chromate and sometimes nickel mixed with fillers
and fluxes such as clay, feldspar and silica. I use the
following recipe:

Black Stain
Chromium Oxide . . . . . . . . . . . . . . . . 20 %. %
Cobalt Carbonate or Oxide . . . . . . . . 20 %.
Manganese Dioxide . . . . . . . . . . . . . . 20 %.
Red Iron Oxide . . . . . . . . . . . . . . . . . . 20 %.
Feldspar (any) . . . . . . . . . . . . . . . . . . . 8
Kaolin (any) . . . . . . . . . . . . . . . . . . . . 8
Silica . . . . . . . . . . . . . . . . . . . . . . . . . 4
10 %.0 %. %

This mixture is best ball-milled for a minimum of

four hours to limit its tendency toward cobalt specking, and to make sure that the colorants are thoroughly
mixed. Because any black stain is a very concentrated
mixture, only small amounts are normally needed to
cause a strong effect. In a clear glaze, a maximum of
5% should produce an intense black. In opaque glazes,
more stain than that may be needed. Black stains and
white opacifiers mixed together will produce a range of
opaque grays. Stains, like other ceramic materials, are
subject to the three variables of glaze makeup, temperature and atmosphere.
Outside the color wheel one finds tones of brown, gray,
and black. These moderate other colors. A color wheel
could, I suppose, include the range of opacifiers since they
also have a strong role in affecting color. The toning influence of brown, gray, and black is just as much opacifying
in result as are the white opacifiers such as tin, titanium,
and zirconium compounds such as Zircopax, Opax,
Superpax, and Ultrox. Slight additional increments of any
of these colors will render most glazes, colored or not,
progressively darker as they are added.
Excerpted from The Ceramic Spectrum: A Simplified Approach
to Glaze and Color Development, published by The American
Ceramic Society.
Note: Colors bars are for visual reference only,
and do not represent actual colors.

COLORANT

CONE ATMOS. %

COMMENTS

Indigo
Nickel

Vary

Ox. 8%-15% Use in high barium/zinc glazes. Also likely to crystallize.

Cobalt + Manganese Vary

Both 5%-10% Various mixtures in most glazes.

Cobalt + Black Stain

Vary

Both 5%-8% Various mixtures in most glazes.

Cobalt

Vary

Both 5%-10% In high magnesium glazes.

Nickel

Vary

Ox. 1%-10% In some saturated-barium glazes.

Manganese

Vary

Both 5%-10% In high alkaline glazes.

Copper

Vary

Ox. 8%-10% In some saturated-barium glazes.

Copper

6-10

Both 8%-10% In high barium and barium/zinc glazes.

Copper

8-10

Red. 1%-5% In copper red glazes opacified with titanium.

Violet

Purple

Nickel

Vary

Ox. 5%-10% In some high barium glazes.

Cobalt

Vary

Both 5%-10% In high magnesium glazes.

Manganese

04-10

Ox. 5%-10% In high alkaline and barium glazes.

Iron

8-10

Red. 8%-10% In high calcium glazes; likely to crystallize.

Copper + Cobalt

Vary

Red. 2%-8% Various mixtures in many glazes.

Chrome + Tin + Cobalt Vary

Ox.

2%-8% Various mixtures in many glazes.

Mauve or Lilac
Cobalt

Vary

Both 1%-5% In high magnesium glazes.

Nickel

Vary

Ox.

1%-5% In some saturated-barium glazes.

Cobalt

Vary

Ox.

1%-3% In high magnesium glazes opacified with tin. Also in

very low alumina content glazes.

Copper

Vary

Red. 0.2%-2% In copper red glazes with titanium.

Copper

6-10

Ox. 0.2%-3% In high magnesium or high alumina glazes.

Copper

8-10

Red. 5%-10% In copper red glazes opacified w/min. 5% titanium.

Chromium

Vary

Ox.

1%-2% In calcium glazes opacified with 5%-10% tin.

Iron

Vary

Ox.

1%-5% In calcium glazes opacified with tin.

Vary

Both 5%-10% In high calcium and some ash glazes.

Pink

Rutile
Nickel
Manganese

018-010 Ox.
Vary

1%-3% In high barium glazes with some zinc.

Both 1%-5% In alkaline glazes opacified with tin or titanium. Also

in high alumina glazes.

Brown
Iron

Vary

Both 3%-10% In most glazes.

Manganese

Vary

Both 2%-10% In most glazes.

Nickel

Vary

Both 2%-5% In high boron, calcium, and lead glazes.

Chromium

Vary

Both 2%-5% In high zinc glazes.

Both 2%-10% In most glazes.

Umber

Vary

Ilmenite

Vary

Both 2%-10% In most glazes. High calcium may yield bluish tint.

Rutile

Vary

Both 5%-10% In most glazes; golden brown.

Gray
Iron

Vary

Red. 2%-4% In many glaze bases; gray brown.

Iron Chromate

Vary

Both 2%-5% In most glaze bases without zinc or tin.

Nickel

Vary

Both 2%-5% In most glaze bases; gray brown.

Copper

8-10

Both 3%-10% In high magnesium glazes. Warm gray in reduction;

cold gray in oxidation.

Cobalt + Nickel

Vary

Both 1%-5% Blue gray in most glazes.

Cobalt + Manganese Vary

Both 1%-5% Blue gray to purple gray in most glazes.

Black Stain

Vary

Both 1%-5% Shades of gray in most opacified glazes.

Iron

Vary

Both 8%-12% In high calcium glazesthe temmoku range.

Copper

Vary

Both 8%-10% In a wide range of glazes.

Cobalt

Vary

Both 8%-10% Blue black in most glazes except those high in zinc
and magnesium.

Black Stain

Vary

Both 3%-10% In most zinc-free, non-opacified glazes.

Black

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2010, Ceramic Publications Company | How to Add Color to Your
your Ceramic Art | 4

The Many Faces

of Iron Oxide:
by Dr. Carol Marians

ne of the more fascinating, but sometimes

frustrating parts of ceramics is learning to
balance the innumerable factors
that affect the outcome of a firing.
Glaze ingredients, the clay body
used, firing cycles, atmospheres,
kiln-stacking techniques, and geography (to name a few variables)
can all affect firing results.
This may be frustrating if you
dont control those variables, but
if you do, there is opportunity for
new discoveries. By changing just
one variable, the same glaze recipe
can be deliberately manipulated to
yield different results. In this instance, I decided to investigate one
variable in an iron-rich glaze: the
cooling period.
I achieved greatly differing results
in a single glaze with a single clay
body, consistent glaze thickness and
application, and the same heating
schedule for all of the firings. The
differences in the resulting appearance of the glaze on the pots came
exclusively from their heat treatment after they reached maturity.
When the witness cone bends,
the glaze should be fully vitrified.
The kiln has reached temperature,
but has not yet begun to cool. I
studied what happens between that
point and the return of the kilns
temperature to room temperature.
I found that I could get a glossy
black surface, a densely textured
rough surface, a golden red/mud
color, or anything in between, just
from different cooling schedules.

How does this happen?

At the top of the firing cycle, the
glaze is matured, but not watery;
it doesnt flow off the pot. At this
point, the glaze is not a homogenous melt, but a mixture of several
melts. It is not fully blended. It may
contain a dissolved second phase
in our case an iron compound
analogous to sugar dissolved in hot
tea. More sugar dissolves in hot
tea; less as the tea cools. The sugar
precipitates as crystals as the tea
cools. Our glaze, when melted, has
a dissolved iron compoundthe
sugar in the tea. The iron precipitates as the glaze cools. So how
does the iron form in the glaze?
Glaze is more complex and
more viscous than tea, inhibiting
motion. The iron crystals cannot
precipitate and sink to the bottom
of the glaze, nor can they grow
very large, as the iron ions do not
congregate in the same location.
Instead, as the glaze cools, the dissolved iron separates out, forming
numerous small crystals suspended
in the glaze. The number of particles, and their eventual size, is affected by the surface texture of the
underlying clay body, the cooling
speed of the melt, the thickness of
the glaze application, and several
other factors. The competition
between the number and size of
particles as the glaze cools results
in the variety of desirable effects
(see accompanying figures).
As it cools, the glaze becomes
progressively more viscous and less

recipe
The glaze used in these tests is a minor
modification of the glaze GA16, from Michael Baileys Cone 6 Glazes, poured thick on
Georgies Ceramic Supplys G Mix 6 clay body .

GA16 Variation
(Cone 6)
Bone Ash . . . . . . . . . . . . . . . . . . . .
Dolomite . . . . . . . . . . . . . . . . . . . .
Lithium Carbonate . . . . . . . . . . . . .
Red Iron Oxide . . . . . . . . . . . . . . . .
Unispar . . . . . . . . . . . . . . . . . . . . .
Bentonite . . . . . . . . . . . . . . . . . . . .
OM4 Ball Clay . . . . . . . . . . . . . . . .
Silica . . . . . . . . . . . . . . . . . . . . . .

4 .6 %
13 .6
4 .6
9 .1
22 .7
1 .8
20 %. .9
22 .7
10 %.0 %. .0 %. %

Empirical Formula
CaO . . . . . . . . . . . . . . . . . . . . . .
K2O . . . . . . . . . . . . . . . . . . . . . .
Li2O . . . . . . . . . . . . . . . . . . . . . .
MgO . . . . . . . . . . . . . . . . . . . . .
Na2O . . . . . . . . . . . . . . . . . . . . .
Al2O3 . . . . . . . . . . . . . . . . . . . .
SiO2 . . . . . . . . . . . . . . . . . . . . . .
P2O5 . . . . . . . . . . . . . . . . . . . . .
Fe2O3 . . . . . . . . . . . . . . . . . . . .
TiO2 . . . . . . . . . . . . . . . . . . . . . .

0 %. .4126
0 %. .0 %.454
0 %. .20 %.13
0 %. .2521
0 %. .0 %.886
0 %. .3424
2 .7566
0 %. .0 %.480 %.
0 %. .1912
0 %. .0 %.10 %.4

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2010, Ceramic Publications Company | How to Add Color to Your
your Ceramic Art | 5

Cool down: An uncontrolled drop from 2200F to 1750F,

then 50 per hour from 1750F to 1500F.
Results: The cooling was slower from 2200F down to
1450F. Because the solubility of iron in glaze decreases
at lower temperatures, I cooled at Z\c the speed between
1750F and 1500F. The result was a substantially
textured surface, with much visible variation, and
crystals of a variety of colors breaking the surface.
The glossy black was gone, and the surface variation
uniformly distributed. There were a relatively small
number of largish particles. The color was intermixed
red, bronze and mud brown. Bronze predominated
where the glaze was thickest. I interpreted this as
substantial particle growth below 1750F, with little
precipitation of new particles.

test 1
Cool down: A continuous cool from Cone 6 to 1500F
at 150 per hour.
Results: This is the cool-down profile from
Hesselberth and Roy. It gave a predominantly glossy
black glaze, not greatly different from the quick
cool, but with a hint of variegated color. I could
see isolated metallic bronze and red flecks, but no
crystals breaking the surface.

mobile, until it reaches a temperature at which it freezes and nothing can move or precipitate within
it. If the glaze is held at a temperature high enough to permit continued mobility of the iron into progressively larger crystals, but low
enough that the glaze doesnt run
off the pot, the surface will become
matt. The multitude of tiny iron
particles disrupt light transmission.
Otherwise, the glaze solidifies with
the same smooth, glossy surface
as it had while fully melted. If the
glaze is cooled quickly, few visible,
very small particles form. Most of
the visible color is the reflection off
the smooth surface. This gives an

test 2

aesthetically pleasing, clear, glossy,

black glaze, somewhat akin to a
temmoku (see test 1). The opacity
and depth of the glossy black show
that the glaze can dissolve quite a
lot of iron.
As the glaze cools and becomes
more viscous, crystals begin to
form at edges and imperfections
in the body. If the glaze layer is
thin, different kinds and shapes of
crystal will form. If the crystals are
stuck to the clay body at the bottom of a thick opaque glaze layer,
they will be largely invisible. Crystals that float on top of the glaze
give the appearance of sandpaper,
which can present utilitarian prob-

lems. We want the crystals near

the surface but not on it, large
enough to create surface and color
effects, but not be overwhelming.
A series of cool-down profiles
with lots of jigs and jags showcases a different phase, exposing
a range of surface effects. This
translates into profiles with one
or more narrow temperature
ranges with extreme slow cooling
and/or long holds, and possibly
no retarded cooling outside the
selected ranges. Since extended
firing cycles can be costly, I
framed my experiments with a
maximum extension to the firing
cycle of four hours.

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Cool down: An uncontrolled drop to 1750F, then 50 per hour to 1600F,

a hold at 1600F for one hour, then 50 per hour to 1500F.
Results: By adding a one-hour hold at 1600F, the color shifted from gold/
brown to red/gold. The red and brown regions followed the throwing lines,
indicating that glaze thickness has significant influence. The strength of
this effect showed there is a critical region for this glazes development
somewhere near the temperature 1600F.

test 3
Cool down: An uncontrolled drop to 1750F, hold at 1750F for half an hour, then
50 per hour to 1650F, hold at 1650F for one hour, then 50 per hour to 1500F.

test 4

Results: Adding a half-hour hold at 1750F and a one-hour hold at 1650F gave
smaller particles and a near-smooth, lustrous satin, variegated bronze glaze with
small specks of red and brown. The original glossy black was completely gone.
Color variation in the throwing line showed the considerable effect that glaze
thickness has. The half-hour hold at 1750F facilitated the formation of a large
5number of small particles, leaving little free iron to add to crystal growth later.
This uniform result was much like a pointillist painting, with exceedingly fine
points. Moving the hold from 1600F up to 1650F could have a similar effect.
Alternatively, we could see this change as a result of the glaze spending more
time in the critical temperature interval for crystal development.

Cool down: An uncontrolled drop to 1800F, then 50 per hour to 1450F.

Results: As the previous test result could have come from extended time
in the crystal growing range, or specifically from the hold at 1650F and
1750F, I gave this firing just as much time in the sensitive zone, but uniform
decrease in temperature over the extended region. The results were similar
to the previous test, but with larger grain size and a lizard-skin feel to the
texture. The glaze was mottled and less uniform. The smooth satin look was
gone. I concluded one of the holds in the previous test hit the sweet spot,
at which point many small particles form. I did not know at which level.

test 5
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Cool down: From Cone 6 to 2100F at 50 per hour,

then uncontrolled cooling to 1700F, then 25 per
hour to 1600F.
Results: To test a second slow-cooling region, the
kiln was cooled quickly from the top temperature
to 1700F, then slowly to 1600F. The result was an
intensely variegated effect with relatively few but
larger particles in red and brown. The throwing lines
were not prominent, so glaze thickness was not as
important. The texture is lizard-skin satin, not the
gloss of tests 1 and 5, nor the smooth satin of test 4.
This result was related, but not quite like anything
previous. This could be a jumping off point for a new
series of tests.

test 6
Cool down: An uncontrolled drop to 2000F, then
50 per hour to 1650F.
Results: The slow cool from 2000F to 1650F gave a
surface and color as in test 1, with a much greater
number of gold particles. This also shows that the
effects of test 4 depended on the 1650F hold. This
critical test showed that the greater color effect I
wanted needed two holds.

I started out with the firing

profile in Hesselberth and Roys
Mastering Cone 6 Glazes. The
ramp for reaching temperature was
a fast rise (200F in the first hour,
then 500F per hour to 2100F)
until the last three hours, which
had a rise of approximately 30F
per hour. Orton cones showed a
hard Cone 6. These firings were
done in a very old Skutt 1227 with
a computer controller. I examined
the results of my firings and based
my next firings on those results,
only changing one factor with each

test 7

firing. I chose 1450F as a low

end for controlled cooling, selecting intervals for markedly slow
cooling in the temperature range
22001450F.

Speculation
With this limited series of tests,
I produced a variety of textures
and colors, by poking the cooldown profile. Each firing included
several identically glazed test
pieces distributed throughout the
kiln. I obtained an encouraging
indication that the different results

were caused by the cooling-down

profiles and not extraneous effects. I next will explore whether
maximal particle size growth takes
place hotter than the temperature at which the greatest number
of particles is formed. Cooling to
approximately 1600F, then reheating to around 1800F should
obtain both good numbers and
development of microcrystals.
the author Dr. Carol Marians holds a Ph.D.
in materials science from the Massachussetts
Institute of Technology, and makes pots at
Basic Fire studio in Portland, Oregon.

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2010, Ceramic Publications Company | How to Add Color to Your
your Ceramic Art | 8

Discovering New Colors

A

A triaxial blend is a method of testing three ingredients on a three-axis

system similar to a two-ingredient line blend.
Often triaxial blends are used to test the primary ingredients in a
glaze base, (for example, feldspar, whiting, and kaolin). It is often
employed when you dont have a percent analysis to reference. If
you have a percent analysis, you can use a glaze software program to
predict glaze surfaces, but if you dont, a triaxial blend is the empirical
A 100
method to see how they melt.
B 0
Another use of the triaxial system is color blending. In this
C 0
method, you keep the base glaze the same and vary the colorants
(oxides or stains or even opacifiers). In this triaxial color blend, I
tested various stains to develop different colors. Since we do not
know the exact amounts of oxides in commercial stains, blending
them in a triaxial can reveal surprising and unusual colors.
A 21-point triaxial is a systematic blending of three variables
A 80
A
B 20
B
with 100% of each variable at the three corners. So in this
C
0
C
case, Mason Deep Crimson #6006 is corner A at 100%,
Mason Sky Blue #6363 is corner B at 100% and Mason
Praseodymium Yellow #6433 is corner C at 100%. The flow
along the vertices is then 80/20, 60/40, 40/60, 20/80. Instead
of using the numbers directly from the triaxial chart, I used 4
grams of stain at each corner. So 100% = 4 grams and then
A 60
A 60
I figured out that 80% of 4 grams was 3.4 grams, 60% was
B 20
B 40
2.4 grams, and 20% was 0.8 grams. Then I substituted
C 20
C 0
those numbers into the triaxial mixtures. For the triaxial glaze chart shown at the right, I used the 5 20
Base Glaze as shown below.
For additional testing you can also add metallic
oxides to stains to change the colors or add visual textures; add 3% Zircopax to brighten a color; add 3%
A 40
A 40
A
B 60
B 40
B
titanium dioxide to make colors slightly more varieC 0
C 20
C
gated; add 1% copper carbonate to any stain to push
it toward green. The list can go on and on.

80
0
20

6
A 60
B 0
C 40

10

40
20
40

A 40
B 0
C 60

11

12

13

14

15

A 20
B 80
C 0

A 20
B 60
C 20

A 20
B 40
C 40

A 20
B 20
C 60

A 20
B 0
C 80

5 X 20 Base Glaze
Cone 6
Wollastonite. . . . . . . . . . . . . . . . . . . .
Custer Feldspar . . . . . . . . . . . . . . . . .
Ferro Frit 3134. . . . . . . . . . . . . . . . . .
EPK Kaolin. . . . . . . . . . . . . . . . . . . . .
Silica . . . . . . . . . . . . . . . . . . . . . . . . .

20 %
20
20
20
20
100 %

21-Point Triaxial Blend Grid: Hansen 5

20 Clear Glaze mixed with AMason
stain Deep Crimson 6006 (Cr, Sn), B
Mason stain Sky Blue 6363 (Co, Al, Si),
and CMason stain Praseodymium Yellow 6433 (Pr, Zr, Si,) dipped on porcelain, fired to cone 6 in an electric kiln.

16

17

18

19

20

21

A 0
B 100
C 0

A 0
B 80
C 20

A 0
B 60
C 40

A 0
B 40
C 60

A 0
B 20
C 80

A 0
B 0
C 100

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How Lana Wilson Uses

Ceramic Pigments
by Annie Chrietzberg

ana Wilsons work is mostly

black and white with bits of
vibrant color splashed about.
She says, I have a background
in painting, and this technique really appeals to the painter in me. She gleaned
this current surface treatment from two
artists, Denise Smith of Ann Arbor,
Michigan, and Claudia Reese, a potter
from Texas.

Simple Slip

To prepare the slip, Wilson takes 100

grams of small pieces of bone dry clay
and adds 1050 grams of a stain. The percentages of stains varies according to the
intensity of color she is trying to achieve.
The clay Wilson uses is Half & Half
from Laguna, formulated for firing at
cone 5, though she fires it to cone 6. This
clay body is half porcelain and half white
stoneware. Its not as white as porcelain,
but it does fire white rather than yellow
in oxidation, isnt as finicky as porcelain,
and works well with Wilsons making
methods. If youre buying clay from the
East Coast, she suggests a clay body called
Little Loafers from Highwater Clays.

Easy Application

The technique is simple. On a piece of

bisqueware, first brush on black slip or
one of the base colors (figure 1) then
sponge it off, leaving slip in the crevices
(figure 2). Then, using colored slips dab
on bits of color here and there (figure
3). Remove some of that with steel wool
(figure 4). I cant use water for this step
or it will muddy the colors, Wilson
explains. CAUTION: You must wear
a respirator during this stage. In the
final step, she dips the piece in a clear
glaze, and fires to cone 6. Through lots
of experimenting, and with lots more to
go, Wilson finds that ending with a dark
color on top works best for her.

Base Coat or Wash Colors

660 %.0 %. Best Black . . . . . . . . . . . . . . . . . 10 %.
6339 Royal Blue . . . . . . . . . . . . . . . 510 %.
60 %.69 Dark Coral . . . . . . . . . . . . . . . . 35

%
%
%

Accent Slips

Recipes

There are two groups of colored

slips. The first group Wilson uses for
the base coat that she washes off,
leaving color in all the recesses. The
accent slips are more intense and
removed with steel wool. All stains
are Mason stains except for 27496
Persimmon Red, which is from Cerdec. Add the stains and bone dry clay
to water and allow to sit for 3060
minutes so it will mix easier.
Note: Stain-bearing slips applied
to surfaces that come into contact
with food need to be covered with
a food-safe clear glaze.

6129 Golden Ambrosia . . . . . . . . . . .

6485 Titanium Yellow . . . . . . . . . . . .
60 %.24 Orange . . . . . . . . . . . . . . . . . . .
6236 Chartreuse . . . . . . . . . . . . . . . .
60 %.27 Tangerine . . . . . . . . . . . . . . . . .
6211 Pea Green . . . . . . . . . . . . . . . . .
6288 Turquoise . . . . . . . . . . . . . . . . .
6242 Bermuda . . . . . . . . . . . . . . . . . .
60 %.69 Dark Coral . . . . . . . . . . . . . . . .
6122 Cedar . . . . . . . . . . . . . . . . . . . .
630 %.4 Violet . . . . . . . . . . . . . . . . . . . .
K5997 Cherry Red* . . . . . . . . . . . . . .
27496 Persimmon Red (Cerdec)* . . . .
* inclusion pigments

30 %.
20 %.
30 %.
50 %.
15
50 %.
50 %.
10 %.
35
25
60 %.
30 %.
30 %.

%
%
%
%
%
%
%
%
%
%
%
%
%

Kate the Younger Clear Glaze

Cone 6
Ferro Frit 3195 . . . . . . . . . . . . . . . . . . 70 %. %
EPK Kaolin . . . . . . . . . . . . . . . . . . . . . . 8
Wollastonite . . . . . . . . . . . . . . . . . . . . 10 %.
Silica . . . . . . . . . . . . . . . . . . . . . . . . . 12
10 %.0 %. %
Add: Bentonite . . . . . . . . . . . . . . . . . . . 2

From Richard Burkett . Use over colored slips .

Shiny, resistant to crazing, cool slowly .

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2010, Ceramic Publications Company | How to Add Color to Your
your Ceramic Art | 10