Protection upgraded
SurTec 856
Bright Nickel Process
for Rack and Barrel Application
Properties
very high quality of the deposited nickel layers
coatings are very active and easy to chromium plate
very good throwing power and metal distribution
deposits "white" nickel
not foaming
insensitive against impurities
process is easy to handle and to control (additives can be premixed)
stable brightener system, very much reduced building of break down products
additive system contains no formalin
IMDS-number: 749088
Application
The process SurTec 856 includes the following products:
SurTec 850 A Carrier is the basis of the additive system
SurTec 856 Brightener for Barrel Nickel gives brightness and levelling to the layer
SurTec 850 LN Wetting Agent is used especially for air agitated baths
SurTec 850 MA Wetter is used especially for mechanical agitated baths
SurTec 850 D Ductilizer works together with the Brightener to reach white
nickel layers and a high gloss, the process can also work without ductilizer
SurTec 850 LCD Purifier is used to correct impurities of zinc and copper and
in the low current density it can be used for improving the brightness
SurTec 850 P Purifier masks organic impurities and the excess of additives in
bright nickel electrolytes
SurTec 850 C Corrector improves the throwing power
make-up values:
nickel sulfate 6 H2O
nickel chloride 6 H2O
boric acid
SurTec 850 A Carrier
SurTec 856 Brightener
air agitation:
SurTec 850 LN
mechanical agitation: SurTec 850 MA
SurTec 850 D Ductilizer
SurTec 850 C Corrector
SurTec 850 P Purifier
SurTec 850 LCD Purifier
260 g/l
50 g/l
45 g/l
19 ml/l
0.25 ml/l
3 ml/l
3 ml/l
as required
as required
as required
as required
page 1
(16-23 ml/l)
(0.1-1.0 ml/l)
(2-4 ml/l)
(2-4 ml/l)
(0.1-0.5 ml/l)
(0.2-1.0 ml/l)
(0.2-2.0 ml/l)
(0.2-2.0 ml/l)
analytical values:
nickel (Ni2+)
chloride (Cl-)
for barrel application
boric acid
make-up:
Steps for make-up:
65 g/l
15 g/l
Cl- should be higher
45 g/l
(50-75
(12-18
(20-45
(40-45
g/l)
g/l)
g/l)
g/l)
1. In a separate tank, dissolve nickel salts and boric acid in very hot
(> 60C) deionised water (ca. 1/3 of the final volume), under
thoroughly stirring.
2. Add 5 g/l active carbon and stir again for about 2 hours.
3. Allow it to settle and filter into the active tank.
4. Fill up to the final volume with deionised water.
5. Dummy plate for about 4 hours at 0.4 A/dm2, then check the
ductility by plating a test panel.
6. If the test panel is ductile enough, the additives can be added,
if not, dummy plating has to be continued further.
temperature:
55C
(50-60C)
pH-value:
4.2
(4.0-4.4)
adjust with sulfuric acid or increase by plating
cathodic
current density:
2.0 A/dm2
(1.5-6.0 A/dm2)
anodic
current density:
0.3 A/dm2
(0.2-1 A/dm2)
current efficiency:
98 %
deposition rate:
0.22 m/min at 1 A/dm2
ratio
anode : cathode:
2:1
anodes:
pure nickel anodes according to DIN 1702,
with anode bags out of pre-cleaned PP
agitation:
barrel rotation with 6-12 rpm or air agitation (oil free!)
tank material:
steel tanks coated with plastic or PVC reinforced material
filtration:
continuously: 4-5 times the total bath volume per hour;
pore size: 5-10 m
heating:
out of resistant material (e.g. porcelain, Teflon, titanium)
exhaust:
required for worker's protection
recommended process sequence (for iron parts):
1. hot degreasing
emulsifying:
SurTec 188 + SurTec 415
demulsifying:
SurTec 188 + SurTec 089
2. hydrochloric acid pickling with SurTec 424
3. anodic electrolytic cleaning with SurTec 188
page 2
4.
5.
6.
7.
8.
9.
acid dip with SurTec 481
if required: Semi Bright Nickel Process SurTec 853
Nickel Process SurTec 856
no rinsing with DI-water if chromium plating follows!
Decorative Chromium Process SurTec 871
drying
Between each step, there has to be rinsed. The rinsing methods have
to be adapted to the plating line.
Technical Specification
(at 20C)
SurTec
SurTec
SurTec
SurTec
SurTec
SurTec
SurTec
SurTec
850
856
850
850
850
850
850
850
A
LN
MA
D
LCD
C
P
Appearance
Density (g/ml)
liquid,
liquid,
liquid,
liquid,
liquid,
liquid,
liquid,
liquid,
1.102
1.066
1.019
1.005
1.035
1.001
1.070
1.177
yellowish
yellowish
colourless-yellowish
colourless
colourless
colourless-yellowish
greenish
colourless
(1.09-1.12)
(1.05-1.08)
(1.00-1.04)
(0.90-1.10)
(1.02-1.05)
(0.95-1.05)
(0.99-1.15)
(1.13-1.23)
pH-value (conc.)
4.0 (3-5)
4.5 (3.5-5.5)
4.0 (3.5-4.5)
3.5 (2-5)
ca. 3.3
ca. 4.2
3.3 (2-5)
ca. 13
Maintenance and Analysis
Compensate evaporation losses with deionised or distilled water.
The analytical values must be restrained: A loss of nickel or boric acid leads to burnings, an
excess of boric acid leads to pitting. A loss of chloride causes a low anodic dissolution. A low pHvalue decreases the levelling power, a high pH leads to burnings.
Excessive SurTec 850 A Nickel Carrier will have nearly no effect (neither positive nor negative);
a lack will lead to milky haze and brittle nickel layers.
A lack of SurTec 856 Brightener results in weak brightness and bad levelling. Never add more
than 0.2 ml/l at a time. An excess will lead to bad adhesion of the layer and even to double
nickel layers and has to be worked out.
Pores and irregular marks on perfectly pre-treated parts indicate a lack of the Wetting Agent
SurTec 850 LN resp. SurTec 850 MA.
A lack of SurTec 850 D Nickel Ductilizer causes lower ductility. A strong excess will result in an
orange peeling effect.
Dark deposits in the low current density indicate metallic impurities. An addition of 1 ml/l
SurTec 850 LCD Nickel Purifier masks 100 ppm copper resp. 50 ppm zinc. Furthermore this
solution can also be added to the bath without any contaminations in order to increase the
brightness in the low current density.
Organic impurities can be mask by an addition of up to 2 ml/l SurTec 850 P Purifier.
A lack of SurTec 850 C Corrector reduces the throwing power, a strong excess decreases
brightness and levelling.
page 3
Sample Preparation
Take a sample at a homogeneously mixed position and let it cool down to room temperature.
If the sample is turbid, let the turbidity settle down and decant or filter the solution.
Nickel Analysis by Titration
reagents:
procedure:
0.1 mol/l EDTA solution (Titriplex III)
ammonia solution (conc.)
indicator: murexide
1.
2.
3.
4.
5.
Pipette 1 ml bath sample into a 250 ml Erlenmeyer flask.
Dilute with approx. 100 ml deionised water.
Add 12 ml ammonia solution.
Add a spatula tip of indicator.
Titrate with 0.1 M EDTA from yellow to violet.
calculation:
consumption in ml 5.87 = g/l nickel
correction:
rise by 1 g/l = addition of 4.5 g/l nickel sulfate 6 H2O
or:
4.1 g/l nickel chloride 6 H2O
Chloride Analysis by Titration
reagents:
procedure:
0.1 N silver nitrate solution
indicator: potassium chromate solution (5 %)
or: 5 g K2Cr2O7 + 95 g NaHCO3
1.
2.
3.
4.
Pipette 1 ml bath sample into a 250 ml Erlenmeyer flask.
Dilute with approx. 100 ml deionised water.
Add some indicator (pH has to be between 6.5 and 10.5).
Titrate with 0.1 N silver nitrate solution from clear yellow to
turbid yellow, until the first sign of a brown shade appears.
calculation:
consumption in ml 3.54 = g/l chloride
correction:
rise by 1 g/l = addition of 3.0 ml/l HCl (30 %)
or:
3.4 g/l nickel chloride 6 H2O
Boric Acid Analysis by Titration
reagents:
procedure:
calculation:
0.1 N NaOH solution
EDTA sodium salt
mannitol
NaOH solution (15 %)
1.
2.
3.
4.
5.
Pipette 2 ml bath sample into a 250 ml Erlenmeyer flask.
Dilute with approx. 50 ml deionised water.
Add 2-4 g EDTA salt.
Adjust the pH-value to pH 7.9 with 15 % NaOH solution.
Add so much mannitol to the clear solution, until the pH is
not changing more than 0.1 points (approx. 10 g).
6. Titrate with 0.1 N NaOH solution to pH 7.9 again.
consumption in ml 3.09 = g/l boric acid
page 4
Consumption and Stock Keeping
The consumption depends heavily on the drag-out. To determine the exact amounts
of drag-out, see SurTec Technical Letter 11.
The following values per 10,000 Ah can be taken as estimated average consumption:
SurTec
SurTec
SurTec
SurTec
SurTec
850
856
850
850
850
A
LN
MA
C
Carrier
Brightener
Wetter
Wetter
Corrector
1-2 l
1.0-2.0 l
approx. 0.5 l
approx. 0.5 l
approx. 0.3 l
In order to prevent delays in the production process, per 1,000 l bath the following amounts
should be kept in stock:
SurTec
SurTec
SurTec
SurTec
SurTec
SurTec
SurTec
SurTec
850
856
850
850
850
850
850
850
Carrier
Brightener
LN
Wetter
MA Wetter
D
Ductilizer
LCD Purifier
P
Purifier
C
Corrector
25
50
25
25
25
25
25
25
kg
kg
kg
kg
kg
kg
kg
kg
Product Safety and Ecology
Classification and designation are noted in the Material Safety Data Sheets (according to the
European legislation).The safety instructions and the instructions for environmental protection
have to be followed in order to avoid hazards for people and environment. Please consider the
explicit details in our Material Safety Data Sheets.
Warranty
We are responsible for our products in the context of the valid legal regulations. The warranty
exclusively accesses for the delivered state of a product. Warranties and claims for damages
after the subsequent treatment of our products do not exist. For details please consider our
general terms and conditions.
Further Information and Contact
If you have any questions concerning the process, please contact your local technical
department.
For further information and contact details please visit our homepage:
http://www.SurTec.com
10 August 2015/DK, MT
page 5
Trouble Shooting (1)
problem
burnings
cloudy or hazy
depositions
insufficient
throwing power
turbid bath solution
pitting
insufficient layer
thickness
delamination
of the Ni layer
possible cause
remedy
a) current density is too high
lower the current density
b) agitation is insufficient
improve the agitation
c) Carrier content is too low
add SurTec 850 A Carrier
d) metal content is too low
add nickel sulfate
e) content of boric acid is too low
add boric acid
a) pre-treatment is insufficient
check the pre-treatment,
improve the rinsing procedure
b) bath temperature is too high
lower the temperature
c) metal content is too high
reduce the anode surface,
work out excessive nickel
d) Carrier content is too high
work out SurTec 850 A Carrier
e) current density is too low
amplify the current density
f) content of Brightener is too low
add SurTec 856 Brightener
g) improper kind of agitation
adjust speed and/or type of agitation
a) metal content is too high
reduce the anode surface,
work out excessive nickel
b) too high concentration of additives
work out at pH 3.8
c) organic impurities
treat with active carbon
a) bath temperature is too high
lower the temperature
b) filtration is insufficient
improve the filtration
c) content of boric acid is too high
filtrate the bath solution at 25C
d) iron impurities
treat with peroxide at high pH-value
e) calcium impurities
add potassium fluoride to precipitate
calcium
a) agitation is insufficient
improve the agitation
b) metal content is too low
add nickel sulfate
c) current density is too high
lower the current density
d) content of Wetter is too low
add SurTec 850 LN resp. MA Wetter
e) calcium impurities
add potassium fluoride to precipitate
calcium
a) metal content is too low
add nickel sulfate
b) current density is too low
amplify the current density
c) defective contacts
check the contacts and clean them
d) anode surface is too small
enlarge the anode surface
e) too much Brightener
work out SurTec 856 Brightener at pH 3.8
f) plating time is too short
prolong the plating time
a) too much Brightener
work out SurTec 856 Brightener at pH 3.8
b) pH-value is too high
adjust with sulfuric acid
c) contacts are bad
check the contacts and clean them
page 6
Trouble Shooting (2)
problem
yellowish Ni layer
possible cause
remedy
a) iron impurities
treat with peroxide at high pH-value
b) iron impurity in the spare rinse
refill spare rinse freshly
hazy in the lcd
content of Brightener is too low
add SurTec 856 Brightener
hazy in the hcd
a) content of Carrier is too low
add SurTec 850 A Carrier
b) organic impurities
treat with active carbon
a) contamination with anode sludge
check the anode bags,
filtrate the bath solution
b) iron impurities
treat with peroxide at high pH-value
c) pre-treatment is insufficient
improve the pre-treatment
a) content of Brightener is too high
work out SurTec 856 Brightener at pH 3.8
b) organic impurities
treat with active carbon
a) zinc impurities
plate selectively in the lcd or
add SurTec 850 LCD
b) copper impurities
plate selectively in the lcd or
add SurTec 850 LCD
rough depositions
brittle Ni layer
dark in the lcd
page 7
