Chapter 21
Chapter 21
21
21.1.1 Candles
We use candles as emergency light source and for decorative and ceremonial
purposes. Usually they are made from a mixture of paraffin wax or some other
slow-burning substance like tallow (stearic acid). They are commonly made in
cylindrical form but are also made in fanciful designs. They contain a wick at
their centre. When lighted with a matchstick heat from its flame liquefies the wax
of the candle. This liquefied wax rises up along the wick where it is converted
into vapour form, which then catches fire.
Now a days, candles are made in a variety of colours, shapes and sizes. Some
candles are scented and their aroma spreads in the air when lighted while some
others can float on water. Nainital (in Uttaranchal) is famous for the variety of
beautiful and decorative candles manufactured here.
21.1.2 Inks
We all use inks in various writing instruments like fountain pens, ball pens, gel
pens, roller pens, soft tip pens, etc. Have you ever thought what ink is?
Ink is a coloured fluid or a paste that is used for writing or printing. Earlier,
black ink, also called India ink, was most widely used. It was made by mixing lamp
black or carbon black in water or oil to which some gum was added which stabilized
the mixture and also gave it better sticking property. This ink is used even these
days but more commonly used inks are solutions of water or alcohol soluble dyes.
Inks used in printing are similar in nature but are in the form of thick paste,
which has a better sticking property. This is an essential quality as it causes the
ink to stick to the typefaces and to paper when it is pressed against it.
21.1.3 Soap and detergents
We use soap and detergents to wash our clothes. We wash our hands and take
bath with soap. Soap and detergents help in removing dirt, oil and grease. How
do soap and detergents remove the dirt and grease? What are the chemicals present
in them? What is the difference in soaps and detergents?
21.1.3a Soap
Soap has been in use for at least last three thousand years. Soaps are sodium or
potassium salts of long chain organic acids (called fatty acids) like stearic acid
and palmitic acid.
How is soap manufactured?
Soap is made by heating oil with sodium hydroxide. The oil and sodium hydroxide
solution are fed into an enclosed reaction vessel under high pressure and heated
at high temperature. At this temperature, the reaction is completed in a few minutes.
The mixture of soap and glycerol is cooled and a concentrated solution of sodium
chloride is added. Glycerol dissolves readily in salt solution but soap does not.
So, solid soap separates out from the mixture. It is then removed by centrifugation.
While still hot it is sprayed into a hot vacuum chamber to dry it. Perfume is added
and the particles are compressed into soap cake.
The basic materials used to manufacture soap are animal fats (lard) or vegetable
oils (olive oil, neem oil, etc.) and an alkali, usually sodium hydroxide. Fats and
oils are compounds of organic acids (containing 1214 carbon atoms) and glycerol
(commonly called glycerine). When the fat or oil is heated with sodium hydroxide
solution, the acids are broken away from glycerol and are neutralized by the alkali
to form soap.
Soaps produce lather (foam) with soft water. With hard water, which contains
calcium and magnesium salts in it, they do not produce lather. Instead they
themselves are precipitated as insoluble salts of calcium and magnesium.
21.1.3b Detergents
Animal fats and vegetable oils are important foodstuffs and ideally should not be
used for making something even as important as soap. In their place, long chain
sulphonic acids (usually C8 to C22) are used. Sodium or potassium salts of these
sulphonic acids are known as detergents. Detergents can be manufactured in solid
form (for washing powders) or in liquid form (for shampoos and liquid soaps).
Unlike soaps detergents can be used with soft as well as hard water. This is because
their calcium and magnesium salts are water soluble.
ACTIVITY 21.1
Aim : To compare the lather forming ability of soap and detergent in soft and
hard water.
What is required? Four test tubes, two small pieces of soap and detergent
cakes.
What to do?
Take four test tubes. In two of them take some amount of ordinary tap
water which is soft water. In one of them add a small piece of soap while in the
other add a small amount of some detergent (a small piece or a small amount of
powder). Shake both the test tubes.
What do you observe?
Now repeat the above procedure with hard water from a hand pump
or a well.
You will find that soap does not form lather but detergent does form
lather even with hard water.
21.1.3c Cleansing action of soap and detergent
Soaps and detergents form lather or foam with water. Lather removes grease and
dirt particles from clothes. Water by itself cannot do it as it does not wet oily or
greasy dirt. Addition of soap or detergents improves the wetting property of water
and thus helps in removing oily or greasy dirt.
21.1.4 Matchboxes
In every house you will find a matchbox. Can you imagine life without it? How
would you light up a candle or gas stove without it?
Do you know how a matchstick catches fire? The head of matchstick consists
of a mixture of potassium chlorate and antimony trisulphide bound together by
glue. The striking surface on the matchbox is a mixture of red phosphorus and
powdered glass held by glue. When a matchstick is struck against the coated
surface of the matchbox, some heat is produced that makes the chemicals in the
match head react. The heat of this reaction ignites the wood.
Be careful
Matches must be used carefully. While lighting, it should not be struck so hard
on the side of the matchbox that its burning head breaks and flies away. This
can result in an accident. After using a matchstick, we should not throw it
anywhere carelessly. Even when its flame is blown off, the tip of the stick
continues to burn slowly as can be seen by the dull red glow at the tip. This is
known as after glow. Many accidental fires may occur by this after glow.
Therefore, while throwing away a matchstick you should always check that it
is completely extinguished and there is no after glow. Sometimes matchsticks
are dipped in a solution of borax or sodium carbonate (karborized matches)
and dried as a first step in the manufacture of matches. Matchsticks thus treated
are completely extinguished when blown away and are safer to use.
CHECK YOUR PROGRESS 21.1
1. Give two examples each of natural and man-made materials?
2. Name the substances used for making candles.
3. What are soaps?
4. Can soap be used with hard water to wash clothes?
5. Which type of matches do we use today?
21.2 HOUSING MATERIALS
In the last section, we learned about some common household items. In this section,
we will learn about two important housing materials cement and glass.
21.2.1 Cement
Do you know what cement is made of and how is it manufactured?
a) Raw materials required: Three main raw materials required for manufacture
of cement are as follows:
Limestone which is calcium carbonate, CaCO3
Clay which is mainly a mixture of aluminium silicates containing alumina,
Al2O3 and silica, SiO2
Gypsum which is CaSO4.2H2O
b) Manufacture: Limestone and clay are mixed in definite proportion and ground
to a fine powdery state. This dry powder is used as such or mixed with water
to form a paste and heated in a rotary kiln (a type of furnace). It is slowly
made to pass through the kiln wherein limestone and clay combine chemically
and form a mixture of calcium silicate, CaSiO3 and calcium aluminate,
CaAl2O3. This mixture is in the form of small greenish black or grey-coloured
hard balls known as clinkers. These clinkers are allowed to cool down and
then ground to very fine powder. To this powder, 2-3% gypsum is added and
the mixture is again ground to obtain a grayish coloured powder, which is
cement. It is then packed in airtight bags to exclude the moisture. Gypsum is
added to decrease the setting time of cement.
c) Uses: Cement is one of the most important building materials. It is employed
in the construction of buildings, roads, bridges, dams, etc. For general uses
like plastering or laying of bricks, this powder is mixed with sand and water
and the resulting thick paste is used for construction purposes. As a result of
chemical reactions between water and cement this mixture sets into a hard
mass.
Concrete is a mixture of cement, sand, gravel or small pieces of stone and
water. It sets to an extremely hard structure. It is used for making floors and
roads. Concrete may be further strengthened by filling it around or over a network
of steel rods and allowing it to set. It is known as reinforced concrete cement or
R.C.C. Such structures are very strong and are used in construction of pillars,
roofs of buildings, roads, bridges and dams.
21.2.2 Glass
Glass is used for various purposes. You must have seen glasses fitted in windows
and doors, looking mirrors, windscreens of vehicles, reading glasses, sunglasses,
etc. Have you ever wondered how is glass prepared? What are the raw materials
required for manufacturing of different types of glasses?
a) Raw materials required: The basic raw materials needed for making glass
are:
Soda-lime glass: The glass produced as given above is called sodalime glass or soft glass. It is used for manufacture of bottles ordinary
crockery, ordinary laboratory glass apparatus like soda glass test tubes
etc.
Ammonia (NH3)
b) Manufacture: Washing soda is manufactured by Solvay process. In this
process, firstly, carbon dioxide is obtained by heating limestone strongly.
CaCO3
CaO
+ CO2
lime stone
quick lime
carbon dioxide
ammonia
ammonium chloride
Ca(OH)2 + 2NH4Cl
ammonium chloride
slaked lime
CaCl2
+ 2NH3 + 2H2O
calcium chloride
c) Uses: Washing soda is used in the manufacture of glass, water glass, caustic
soda, borax and soap powders. It is also used for the softening of water, as
laboratory reagent and as a starting material for the preparation of a number
of other sodium compounds. Of course, its most common use in laundry is
for washing of fabrics and clothes from which it gets its name.
21.3.2 Baking soda
You must have seen your mother using baking soda while cooking some dals. If
you ask her why she uses it, she would tell that it helps in cooking some items
faster which otherwise would take much longer time. Chemically, baking soda is
sodium hydrogen carbonate or sodium bicarbonate and its formula is NaHCO3.
a) Manufacture: You have already learned in the previous section that it is the
primary product of the Solvay process used to manufacture washing soda.
It gives small white crystals sparingly soluble in water. Its solution in water is
alkaline in nature.
b) Uses: Baking soda is mainly used in the baking industry. When sodium
hydrogen carbonate or its solution is heated, it gives off carbon dioxide.
It is this carbon dioxide which raises the dough during baking. The sodium
carbonate produced during the heating of sodium hydrogen carbonate gives bitter
taste. Therefore, usually baking powder is used, which is a mixture of baking
soda, NaHCO3 and an acid like tartaric acid. The latter is added to neutralize the
sodium carbonate formed in the reaction given above, to avoid its bitter taste.
You must have eaten cakes. They are made so soft and fluffy by using baking
powder. Baking soda is also used in medicines to neutralize the excessive acidity
in the stomach. Mixed with a solid acid such as citric or tartaric acid, it finds use
in effervescent drinks used to cure indigestion.
Another important use of baking soda is in certain types of fire extinguishers
about which you have already learned in lesson 14.
with 1 part carbon black. If flexibility is not important fillers, such as clay or
chalk, are added to make rubber hard and stiff. Rubber for floor tiles and
mats contains fillers of this type.
b) Synthetic rubber: Synthetic rubber supplements the natural rubber and helps
save precious trees. Its properties are similar and sometimes better than those
of natural rubber. The most common variety of synthetic rubber is made from
the monomer butadiene CH2CH.CH.CH2. It can be vulcanized just like natural
rubber. It has particularly good resistance to wear and tear, which makes it
especially useful for making tyres. Other types of synthetic rubbers are made
by mixing other monomers like styrene and chloroprene (commonly known
as neoprene) with butadiene.
21.4.3 Plastics
You must be using comb, toothbrush, jars and buckets in your house. All these
items of daily use are made of plastic. Plastics are synthetic or man-made polymers.
Let us learn about some of these.
a) Polythene is a polymer made from ethene (CH2=CH2). It is one of the most
commonly used materials. It is a soft plastic, which softens on heating. It is
used for making bottles, buckets, and pipes, as covering for electrical wires
and cables and as film for making bags.
b) Polyvinyl chloride (PVC) is made from the monomer vinyl chloride
(CH2=CHCl). It is used for making rain coats, handbags, toys including dolls,
electrical goods and as a covering of electrical wires.
c) Bakelite (Phenol-formaldehyde resin) is made by reacting phenol and
formaldehyde. It is hard and quite a strong material. It is used for making
combs, electrical switches, and plugs and for making handles of many kitchen
utensils and electrical appliances like pans, pressure cookers, electric irons,
kettles, and toasters.
CHECK YOUR PROGRESS 21.4
1. What is a monomer?
2. What is the name of monomeric unit of natural rubber?
3. Why is sulphur added to rubber?
4. What is the full form of PVC?
21.5 MEDICINES
Whenever we feel sick, we go to the doctor for medicines (also called drugs).
Medicine is a substance used for treating diseases or illness. Let us study about
some common types of medicines.
21.5.1 Anaesthetics
Anaesthetics are drugs which produce a loss of sensation and consciousness.
General anaesthetics result in loss of sensation and consciousness in the entire
body. Examples are divinyl ethers, cyclopropane, etc. They are used during major
surgical operations. Some anaesthetics like Novocain and Xylocaine which show
their effect in a limited area are called local anaesthetics. They are used during
small surgical operations and tooth extraction.
21.5.2 Antibiotics
Antibiotics are medicines which are used to kill bacteria, fungi and moulds. The
first antibiotic discovered was penicillin which is very effective for pneumonia,
bronchitis, sore throat, etc. Ampicillin is a slight modification of penicillin. It has
wider applications. Other commonly used antibiotics are streptomycin, tetracycline
and chloramphenicol.
21.5.3 Analgesics
Analgesics are used for relieving pain. Aspirin, paracetamol, morphine are some
examples of analgesics. They must be used only under medical supervision.
21.5.4 Antacids
Antacids are used to treat acidity in stomach. Digene, ranitidine and omeprazole
are some examples of antacids.
21.5.5 Antipyretics
Antipyretics are the medicines which are used to bring down body temperature in
high fever. Their administration leads to perspiration which brings down the
temperature. Common examples are aspirin, paracetamol, analgin and phenacetin.
In this section you learned about some important types of medicines. However,
it must be remembered that medicines should always be taken on the advice of a
doctor.
CHECK YOUR PROGRESS 21.5
1. What is the use of the drug paracetamol?
2. What is the use of ranitidine?
3. Name an antibiotic.
4. Which types of medicines are used for relieving pain?
21.6 HARMFUL EFFECTS OF MAN-MADE MATERIALS
In this lesson you have learnt about various materials that are useful to us. Many
of them are obtained from natural resources while a large number of them are
man-made. These days the latter are being used extensively. However, after use
their disposal becomes a problem. Many of them are toxic in nature and pollute
air and water. Some of them are so stable that they are not degraded easily and
they get accumulated in the environment. Such materials should be recycled in
order to avoid such problems. In the next lesson you will learn about the harmful
effects of man-made materials and the related environmental problems in detail.
LET US REVISE
Of all the materials that we see around us some are obtained from nature
while others are prepared by man.
Candles are made from a mixture of paraffin wax and stearic acid.
Inks are coloured fluids or pastes that are used for writing or printing.
Soaps are sodium or potassium salts of long chain fatty acids while detergents
are sodium or potassium salts of long chain sulphonic acids. Detergents can
give lather even with hard water whereas soaps cannot.
Safety matches have a mixture of potassium chlorate and antimony trisulphide
and glue at the head of match sticks and a mixture of red phosphorus and
powdered glass on the striking surface. The heat generated when the match
stick is struck starts the ignition.
Cement is one of the most important building material manufactured from
limestone, clay and gypsum.
Concrete is a mixture of cement, sand gravel and water. It sets to an extremely
hard structure.
Glass is prepared by heating a mixture of washing soda, limestone and sand
in a furnace.
Soda glass is used for manufacture of bottles, ordinary crockery, laboratory
apparatus, etc.
Hard glass is made by using potassium carbonate in place of sodium carbonate.
It can withstand very high temperatures and is used for making laboratory
apparatus.
Borosilicate glass is sodium aluminium borosilicate and can withstand rapid
heating and cooling. It is used for making kitchen and laboratory ware.
Flint glass is used for making lenses, prisms, spectacles, etc.
Coloured glass is made by adding small quantities of oxides of different metals.
Fibre glass is a mass of fine threads of glass used as an insulating material for
heat, electricity and sound and reinforcing plastics and rubber.
Washing soda (Na2CO3.10H2O) is prepared by Solvay process. It is used in
the manufacture of glass, caustic soda, borax and soap powders. It is used for
softening of water, as a laboratory reagent and as a starting material for many
sodium compounds.
Baking soda (NaHCO3) is the primary product of Solvay process. It is mainly
used in baking industry and in fire extinguishers.
Baking powder is a mixture of baking soda and tartaric acid.
Bleaching powder (CaOCl2) is prepared by mixing chlorine and slaked lime. It
is used for bleaching cotton, linen and wood pulp and for sterilization of water.
Plaster of Paris (CaSO4. H2O) is prepared by heating gypsum (CaSO4.2H2O).
It is used for making casts and patterns and for plastering the walls, pillars
and ceilings and to make ornamental patterns on them.
Polymers are big molecules formed when a large number of small molecules
join together. Cotton, wool, terylene, etc. are some polymers. Nylon, polyesters,
rubber and plastics are some important polymers.
Medicine is a substance used for treating diseases or illness. Anaesthetics,
antibiotics, analgesics, antacids and antipyretics are some important types of
drugs that are used.
TERMINAL EXERCISES
A. Multiple choice type questions.
Choose the correct answer of the following:
1. The glass that can withstand rapid heating and cooling without breaking is
(a)
hard
(b) soda-lime glass (c) borosilicate (d) flint
2. Novocain is an
(a)
antipyretic (b) analgesic
(c) anaesthetic (d) antibiotic
3. Chloramphenicol is an
(a)
antibiotic
(b) antipyretic
(c) antacid
(d) analgesic
4. Which of the following is not a raw material required for manufacture of
washing soda?
(a)
Lime stone (b) Ammonia
(c) Slaked lime (d) Sodium
chloride
5. Which of the following is a man-made material?
(a)
Glass
(b) Wood
(c) Leather
(d) Silk
B. Descriptive type questions.
1. What are candles made of ?
2. What are the basic materials used for the manufacture of soaps?
3. What is concrete?
4. Mention two uses of bleaching powder.
5. Name the two substances used for making nylon.
6. For printing purpose why is ink used in the form of thick paste?
7. How striking the matchstick on the side of the matchbox helps in lighting it?
8. Why is gypsum added to the powdered clinkers during manufacture of cement?
9. Mention four uses of washing soda.
10. Give two examples each of antibiotics and analgesics.
11. What is an antipyretic? Give two examples.
12. What is vulcanization process? Why is natural rubber vulcanized?
13. List the raw materials required for manufacture of bleaching powder and
describe its process of manufacture.
14. How is Plaster of Paris manufactured? Give its two uses.
15. Name three plastics and give one use of each one of them.
16. What is a candle made of? Explain the process of lighting it.
17. Differentiate between soaps and detergents. Why soaps do not form lather
with hard water while detergents can?
18. List the raw materials required for the manufacture of cement. Describe the
process of manufacture of cement briefly.
19. How is soda-lime glass manufactured? Describe briefly. What changes are
made in the raw materials in the manufacture of optical glass and Borosil
glass? How is colour imparted to glass?
20. Describe the process of manufacture of washing soda giving appropriate
chemical equations. Mention two of its uses.
21. What are the monomeric units of polythene and polyvinyl chloride? Give
three uses of each of these.
ANSWERS TO CHECK YOUR PROGRESS
21.1
1.
2.
3.
4.
5.
Natural materials: Any two of the following wood, silk, cotton, leather
and rubber
Man-made materials: Any two of the following synthetic textiles
like terylene and nylon, cement, glass, plastics, dyes, soap, detergents,
fertilizers, insecticides and pesticides.
Candles are made from mixtures of paraffin wax and stearic acid.
Soaps are sodium or potassium salts of fatty acids.
No, because soap is precipitated out as salts of calcium and potassium
in hard water.
Safety matches
21.2
1.
2.
3.
4.
21.3
1.
2.
3.
4.
Baking soda
Solvay process
Bleaching powder
CaSO4. H2O or CaSO4.1/2H2O
21.4
1.
2.
3.
4.
21.5
1.
2.
3.
4.
GLOSSARY
Analgesics: Medicines which are used for relieving pain.
Antacids: Medicines which are used to treat acidity in stomach.
Antibiotics: Medicines which are used to kill bacteria, fungi and moulds.
Antipyretics: Medicines which are used to bring down body temperature in
high fever.
Bakelite: Phenol-formaldehyde resin made by reacting phenol and
formaldehyde.
Baking powder: Mixture of baking soda and tartaric acid.
Baking soda: Common name of NaHCO3.
Bleaching powder: Common name of CaOCl2.
Borosilicate glass (Borosil glass): Sodium aluminium borosilicate and can
withstand rapid heating and cooling.
Concrete: Mixture of cement, sand, gravel and water.
Dacron: Polyester prepared by reaction between terephthalic acid and ethylene
glycol.
Detergents: Sodium or potassium salts of long chain sulphonic acids.
Fibre glass: Mass of fine threads of glass used as an insulating material for
heat, electricity and sound and reinforcing plastics and rubber.
Flint or optical glass: Lead-potash lime glass which is used for making lenses,
prisms, spectacles, etc.
General anaesthetics: Those drugs which result in loss of sensation and
consciousness in the entire body.
Hard glass: Variety of glass that can withstand very high temperatures.
Ink: Coloured fluid or a paste, which is used for writing or printing.
Local anaesthetics: Drugs which show their effect in a limited area.
Man-made materials: Materials which are prepared by man.
Medicine: Substance used for treating diseases or illness.
Monomers: Small molecules which make a polymer by joining one another.
Natural materials: Materials which we get from nature.
Nylon: Polymer of small monomeric units called amide (-CO-NH-) i.e. it is a
polyamide
Plaster of Paris: Common name of CaSO4 H2O.