COATINGS
Polyurea Spray
SUPRASEC MDI
FOR PROTECTIVE SYSTEMS
COATINGS
COATINGS
Polyurea Spray
Polyurea Spray
PART 1
PART 1
PART 1
The concept of polyurea spray elastomer technology was introduced
about 20 years ago by chemists at
Texaco Chemical Company (now
Huntsman Corporation) in Austin,
Texas. This new application was
based on the reaction of an isocyanate
component with an amine blend to
produce a polyurea elastomer system.
The concept
The catalyst-free isocyanate/amine reaction is normally rapid, proceeding to
completion within a few seconds. Working times (gel times) generally fall
within the sub-five-second range, thus requiring specialised mixing and
application equipment. High pressure two-component spray machines
equipped with impingement mixing have proven efficient and entirely adequate for sufficient blending and rapid dispensing of the polyurea raw materials. It is chiefly this equipment that allows polyurea technology to venture
outside of the realm of Reaction Injection Molding (RIM).
chain extenders, and therefore will develop the characteristic amber or yellow
colour when exposed to sunlight. However, unlike with polyurethanes, no
chalking or cracking is observed in polyureas. Pigmentation, for example
carbon black, improves the resistance to discoloration and masks its effects.
Polyurea spray elastomers based on JEFFAMINE polyetheramines, aliphatic
isocyanates and amine chain extenders are light stable and do not change
colour or chalk in sunlight. As would be expected, light-stable polyureas are
more expensive than those based on conventional products, due to higher
costs of raw materials.
The Polyurea advantage
Since this seminal work, a number of
advances in both the chemistry and
application equipment for polyurea
have enabled polyurea elastomer
coatings to compete with (and often
displace) their traditional counterparts
in the commercial arena. Legislation
regarding volatile organic compounds
(VOC) in coatings has further heightened market interest in polyurea
coatings.
This brochure provides the coatings
expert and novice alike with background starting-point formulation and
application information for these
unique polymer systems.
Definition
A polyurea coating/elastomer is derived from a reaction of an isocyanate
component and a resin blend component. The isocyanate can be aromatic
or aliphatic in composition. It can be a monomer, polymer, or any variant
reaction of isocyanates quasi-pre-polymer, or a pre-polymer. The pre-polymer or quasi-pre-polymer can be made of an amine-terminated polymer
resin, or hydroxyl-terminated polymer resin. The resin blend must be made
up of amine-terminated polymer resins, and/or amine-terminated chain
extenders. The amine-terminated polymer resins will not have any intentional
hydroxyl moieties. Any hydroxyls are the result of incomplete conversion to
the amine-terminated polymer resin. The resin blend may also contain additives, or non-primary components. These additives may contain hydroxyls,
such as pre-dispersed pigments in a polyol carrier. For clarification purposes, a polyurethane/polyurea hybrid is a reaction of an isocyanate with a
resin blend. The resin blend will contain an amine-terminated polymer resin
and a hydroxyl containing polyol. It may or may not contain catalysts.
Technology
Polyurea spray elastomers can be formulated from ingredients which produce
either conventional or light-stable products. Conventional polyureas use
JEFFAMINE polyetheramines with aromatic SUPRASEC isocyanates and
Polyurea elastomer coatings offer many advantages over their traditional
counterparts (i.e. polyurethanes, polyurethane-urea hybrids). The following
list highlights a number of polyureas advantages.
1. Fast cure. Polyurea can be sprayed on sloped (and even vertical)
surfaces without drip or run formation. Foot traffic can resume on
coatings applied to horizontal surfaces within 30 seconds.
2. Water insensitivity. Relative moisture and temperature insensitivity
during application. Little effect is encountered on adhesion or coating
performance due to weather variations (i.e. high humidity, temperature
and residual moisture).
3. 100 % solids. Two-component, one-coat system can be sprayed
and poured at 1:1 volume ratio. Eliminates the need for multi-coat
applications. It is environmentally friendly.
4. Excellent physical properties, including tensile strength, tear strength
and elongation. (See page 8)
5. Thermal stability. Stable up to 150C.
6. Pigment compatible. Colorants can be added to change appearance
and light-stability.
7. Formulation flexibility. Can be formulated into products ranging from
soft to hard elastomer.
8. Reinforcible fibres and fillers can be incorporated during application.
3
COATINGS
COATINGS
Polyurea Spray
Polyurea Spray
PART 1
PART 1
Sprayed polyurea elastomers have exhibited excellent adhesion to clean
substrates such as concrete, wood, asphalt and fresh blasted steel.
However, as with other rapid cure coatings, the rapid cure of polyurea
systems can sometimes limit surface wetting and penetration of substrate
surfaces for mechanical bonding. For this reason the end users are advised
to test the adhesion of the sprayed elastomer films on target substrates to
assess bonding of the coating, Surface primers and adhesion promoters
may be necessary. In addition, because the polyurea film exhibits such
robust physical properties and remains intact as it is pulled from the substrates surface, greater adhesion may be necessary for specific applications.
Basic chemistry
Polyurea systems have been defined as the reaction of an isocyanate or
isocyanate pre-polymer with a resin blend that consists of amine functional
species.
A key advantage of polyurea spray coatings is that the amine/isocyanate
reaction is very fast, predictable and consistent. In contrast, polyurethane
elastomers require high levels of catalyst packages which can cause
degradation of the elastomer and usually possess tight processing parameters such as temperature and humidity ranges. The following figure offers a
structural comparison of generic polyurethanes and polyureas.
These specialty amines generally possess soft, flexible polyoxypropylene
backbones that significantly contribute to the hydrophobic/waterproof nature
of the respective polyurea coatings. These alternating hard block/soft block
polymer units are linked by DETDA, which is commonly referred to as the
chain extender of the system.
Spray equipment
Processing of spray polyurea coatings requires specialised, high pressure/
high temperature impingement mix equipment. The capability of heating the
components prior to mixing is a key attribute of the spray equipment, as it
was found that heating of the materials prior to spray was necessary to
reduce system viscosity (i.e. the isocyanate amine resin blend components).
Viscosity reduction improves the mix, flow, and leveling of the applied material
and leads to significant improvements in the performance and appearance
of the coating. To ensure proper mixing, it was found that the use of a highpressure proportioner and a spray or pour gun are essential.
Application areas
POLYURETHANE
The concept of instant, high-performance coatings has attracted the interest
of many who possess an entrepreneurial spirit, as well as those with vivid
imaginations. In the infancy of this new polyurea technology, spray applications of structures and objects too numerous to fully list, were attempted.
As already mentioned, the reaction of the isocyanate component with the
amine blend is generally a very rapid, predictable reaction. The fast reactivity
allows for rapid return to service for coating application work.
POLYUREA
The current polyurea technology allows the preparation of both aromatic
and aliphatic (light stable) elastomer systems. By selecting the appropriate
isocyanate component and amine blend, a variety of system reactivities is
possible. Slower systems can be utilised for a variety of sealant/caulk-type
applications.
While polyols are often utilised in the construction of isocyanate pre-polymers
used in polyurea spray systems, these specialty pre-polymers, such as
Huntsmans line of SUPRASEC isocyanates, are produced without the
catalysts that are usually required to promote the reaction of isocyanates
and polyols. Polyols are not to be added into the amine resin blend if the
elastomer is considered to be a true polyurea. Polymer systems that do
incorporate polyols into the resin blend are commonly referred to as hybrid
systems. The term hybrid refers to the presence of both polyurea and
polyurethane linkages within the system, and it should be noted that on
many occasions these materials do not offer the same performance or
processing profiles as true polyureas.
Given these attributes, polyurea elastomer systems are well-suited for a myriad
of application areas including pipeline coatings, secondary containment,
synthetic stucco coatings, concrete coatings, railcar coatings, foam and
EPS coatings, tank linings, part production, truck bed liners, various waterproofing applications and floor joint/seam sealants. In addition to these
uses, polyurea continues to be evaluated for use in numerous niche applications that require high performance coatings with near-immediate return to
service.
Recent European projects cover applications such as trading hall flooring,
secondary containment in harbour areas, anti-abrasion coatings on
sieves, pipeline coatings, road marking, truck bed lining.
Typically, aromatic SUPRASEC isocyanates are reacted with JEFFAMINE
amines and diethyltoluene diamine (DETDA).
The SUPRASEC isocyanate component functions as the systems rigid
hard block while the JEFFAMINE amine segments are commonly referred
to as the systems soft block.
COATINGS
COATINGS
Polyurea Spray
Polyurea Spray
PART 2
PART 2
PART 2
Polyurea elastomer systems are
based on formulations that can be
finely tuned for an application.
Just as in a complex cooking recipe,
a number of chemical ingredients
(raw materials) are incorporated into
this two-component system. It is not
uncommon to utilise 5 or 10 functionspecific additives in addition to the
isocyanate component and amine
blend. Below is a brief summary of the
types of reagents that are
commonly incorporated into polyurea
formulations. In part 3, entitled
Polyurea Physical Properties,
specific admixtures are presented
and the impact of their varying
constitutions on coating performance
and properties discussed.
RAW MATERIALS
New JEFFAMINE SD-secondary polyetheramines.
Resin blend
The amine blends used in the application of polyurea elastomer systems are
often referred to as the resin blend. As mentioned in part I, the resin blends
multi-functional, amine terminated-polyethers and chain extenders are used
in conjunction with the quasi-isocyanate pre-polymers. At the heart of the
resin blend mixture are Huntsmans JEFFAMINE polyetheramines and
JEFFLINK chain extender. JEFFAMINE polyetheramines are amine-terminated ethylene oxide and propylene oxide-based polyethers exhibiting molecular weights from ~ 200-5000 g/mole. JEFFLINK products are cycloaliphatic
amine products that have been designed to give slower reaction times in
elastomer/coating systems. Suitable JEFFAMINE amines and JEFFLINK
diamine products for polyurea elastomer technology include:
Product
JEFFAMINE T-5000 amine
JEFFAMINE D-2000 amine
JEFFAMINE T-403 amine
JEFFAMINE D-400 amine
JEFFAMINE D-230 amine
JEFFLINK 754 diamine
Approx.
molecular
weight
Approx
functionality
amine group
5000
2000
400
400
230
250
3
2
3
2
2
2
Resin components viscosities range from about 800 to 1000 mPa.s at
25C and 140 to 170 mPa.s at 65C.
Product
JEFFAMINE SD-231 amine
JEFFAMINE SD-401 amine
JEFFAMINE SD-2001 amine
Approx.
molecular
weight
Approx
functionality
amine group
315
515
2050
2
2
2
JEFFAMINE SD-231 amine, JEFFAMINE SD-401 amine and JEFFAMINE
SD-2001 amine are high content, secondary aliphatic, liquid polyetherdiamines. The secondary amine functional groups provide a slower reaction
compared to primary amines, capable of slowing down the cure speed of
polyurea/polyurethane elastomeric coating systems. Designed to be used in
conjunction with aromatic or aliphatic chain extenders, or to partially replace
existing primary polyether amines, they can improve the flexibility and colour
of aromatic formulations, while reducing the overall cost of development.
As low viscosity liquids, these new secondary aliphatic diamines allow the
efficient formation of much lower viscosity isocyanate prepolymers, with properties equivalent to primary polyetheramines or polyols used. The products
are stable and there is no off-gassing of reversible blocking agents. They
can also expand the formulation capabilities of aspartic esters and aromatic
formulations at a lower cost, with equivalent performance properties.
Secondary aliphatic polyetheramines also enable the formation of high hardness aromatic and aliphatic systems while maintaining flexibility and good
cure speeds at a reasonable cost.
Because of their backbone and structure type, JEFFAMINE polyetheramines
are largely responsible for the low moisture vapor transmission rates in the
corresponding polyurea systems. The primary amine groups in these molecules react rapidly and consistently with the isocyanate components, obviating the need for catalysts.
6
COATINGS
COATINGS
Polyurea Spray
Polyurea Spray
PART 2
PART 2
Soft flexible system
Such soft formulations are used to produce for example elastomeric truck
bed linings, roof coatings and flexible membranes.
Isocyanate component
The isocyanate component is a soft block quasi-pre-polymer based on
commercially available isocyanates, such as MDI for aromatic systems and
IPDI for aliphatic systems. Viscosities of the isocyanate quasi-pre-polymer
components vary with the formulations employed and are typically under 3000
mPa.s at room temperature (25C) and under 500 mPa.s at normal processing
temperatures of 65C.
Isocyanates
Description
%NCO
Viscosity at
25C mPa.s
Average
functionality
SUPRASEC2008
Low-functional
pre-polymer
10.2
1800
2.0
SPRASEC2054
Low-functional
pre-polymer
15.0
775
2.0
SUPRASEC2058
Low-functional
pre-polymer
15.4
850
2.0
SUPRASEC2067
Higherfunctional
pre-polymer
19.3
610
2.2
Isocyanate
SUPRASEC 2008
100 pbw
Resin blend
JEFFAMINE T-5000 amine
JEFFAMINE D-2000 amine
DETDA
Pigment
16.0
59.5
14.5
10.0
Typical properties
Gel time
Tack free time
Tensile @break
Elongation @break
Angle tear
Trouser tear
Hardness
Advantages:
very high flexibility
relatively high strength
very low shrinkage
1.10
1.00 v/v
75-80 C
150-180 bar
Isocyanate
SUPRASEC 2054
100 pbw
Resin blend
JEFFAMINE D-2000 amine
DETDA
74.0 pbw
26.0 pbw
Typical properties
Gel time
Tack free time
Tensile @break
Elongation @break
Angle tear
Trouser tear
Hardness
MPa
%
N/mm
N/mm
Shore A
Shore D
SUPRASEC 2054
100
pbw
Resin blend
JEFFAMINE T-5000 amine
JEFFAMINE D-2000 amine
DETDA
Chain extender
Adhesion promoter
Pigment
UV-stabiliser
6.0
53.5
20.5
8.0
1.0
10.0
1.0
pbw
pbw
pbw
pbw
pbw
pbw
pbw
Typical properties
Gel time
Tack free time
5
7
sec.
sec.
The following examples are all performed at below-process parameter:
Standard base formulation
13
638
46
20
75
25
Isocyanate
Isocyanate analysis in polyurea spray applications
Index
Ratio isocyanate/resin
Application temperature
Application pressure
13 sec.
25 sec.
Standard high strength system
Similar formulations are used to produce secondary containment coatings,
floor coatings, waterproofing membranes and truck bed lining.
The SUPRASEC MDI grades are designed to be used in polyurea
applications, ensuring extremely good miscibility with the resin blends
and therefore provide a constant reactivity profile.
Processing
pbw
pbw
pbw
pbw
Advantages:
relative high flexibility
combined with high strength
good tear resistance
good chemical resistance
Tensile @break
Elongation @break
Angle tear
Trouser tear
Hardness
21
312
71
41
94
47
MPa
%
N/mm
N/mm
Shore A
Shore D
3 sec.
7 sec.
15.6
349
63
34
96
50
MPa
%
N/mm
N/mm
Shore A
Shore D
COATINGS
COATINGS
Polyurea Spray
Polyurea Spray
PART 2
PART 2
High hardness system
Such a system is required and used for corrosion protection and abrasion
resistance.
Replacement of UNILINK 4200 additive with secondary amines in aromatics.
All formulations based on US-origin aromatic isocyanate RUBINATE 9480
Reference No.
Advantages:
very high hardness
moderate flexibility combined
with strength
very high tear resistance
good chemical resistance
very low water uptake
Isocyanate
SUPRASEC 2067
100 pbw
Resin blend
JEFFAMINE T-5000 amine
JEFFAMINE D-2000 amine
DETDA
JEFFAMINE D-400 amine
Chain extender
Pigment
Adhesion promoter
8.0
25.0
8.0
20.0
32.0
6.0
1.0
Typical
properties
Gel time
Tack free time
Tensile @break
Elongation @break
Angle tear
Trouser tear
Hardness
pbw
pbw
pbw
pbw
pbw
pbw
pbw
13 sec.
18 sec.
16
171
117
35
97
60
MPa
%
N/mm
N/mm
Shore A
Shore D
8276-72
8314-12
8276-92
53
10
22
0
0
10
5
55
10
22
0
8
0
5
53
10
22
10
0
0
5
Tensile strength, MPa
Max Elongation, %
100% Modulus, MPa
300% Modulus, MPa
Tear strenght, N/mm
20.0
637
7.7
11.3
88.6
18.4
606
7.3
10.8
83.3
17.7
653
6.9
10.0
83.7
Shore D, 0 sec/10 sec
50/41
51/43
52/41
6
12
7
11
7
11,5
JEFFAMINE D-2000 amine
JEFFAMINE T-5000 amine
DETDA
JEFFAMINE SD-231 amine
JEFFLINK 754 curing agent
UNILINK 4200 additive
TiO2
Spray, Gel Time, sec
Tack Free, sec
Chain extenders
A second set of amine reagents, referred to as chain extenders play a key
role in both processing time and the ultimate properties of the respective
coatings. As with isocyanate components, chain extenders can be eithe
aliphatic or aromatic in nature. Aliphatic species are utilised in applications
where light stability is a high priority. However these chain extenders are
significantly more expensive. Listed are common chain extenders used in
polyurea elastomer systems: ETHACURE 100, LONZACURE 80, UNILINK
4200, ETHACURE 300, CLEARLINK 1000, JEFFLINK 754 Diamine.
JEFFLINK 754 diamine, available from Huntsman, was originally developed
for use as UV stable chain extender in aliphatic polyurea, but it may also be
used as partial or complete replacement for aromatic chain extenders such
as UNLINK 4200. By replacing aromatic chain extenders with JEFFLINK
754 diamine, or with the new secondary polyetheramines, it is possible to
formulate aromatic systems with high hardness while maintaining good flexibility, and good cure speed at a reasonable cost. It also improves initial coating color. More information is available on request.
- Secondary aliphatic amines can partially replace UNILINK 4200 additive.
- Reduces cost and improves the initial coating color.
Slower amines may be used to fine-tune the reactivity of spray systems to
control surface appearance and improve physical properties.
Other additives
The resin blend mixture can contain a host of other additives that serve a
variety of functions in the ultimate polyurea elastomer system. When needed
by certain difficult substrates, silane based adhesion promoters can be
used. For applications where a good rough morphology is desired (e.g.
truckbed liners), texturing agents such as washed sand or calcium carbonate
can be incorporated. For caulk applications a thixotrope such as fumed silica
is required to maintain dispersion of the other resin blends. A variety of UVstabilisers and anti-oxidants are also formulated into coatings by adding the
resin blend side. Polyurea elastomer technology is also amenable to the use
of pigments and colorants.
A number of JEFFAMINE polyetheramine-based pigments dispersions are
available. These offer a wide range of possible coating colours.
Polyurea system availability
Huntsman manufactures and sells the family of JEFFAMINE polyetheramines, JEFFLINK chain extenders and SUPRASEC methyl-diisocyanates
(MDI) that are key ingredients in polyurea.
Formulators can supply the technical service support and work with their
applicator customers, supplying materials designed to meet the specific
needs of the applications.
10
11
COATINGS
COATINGS
Polyurea Spray
Polyurea Spray
PART 3
PART 3
PART 3
POLYUREA PHYSICAL PROPERTIES
Chemical resistance testing for polyurea spray elastomers
Polyurea spray elastomer systems are 100 % solids, two-component spray
systems which have extremely fast reactivities and cure times. This technology is similar to the high-performance polyurethane systems currently used,
except in several key areas. In the polyurea spray technology, JEFFAMINE
polyoxyalkylene diamines and triamines have replaced the polyols, amine
chain extenders are utilised, and catalysts have been eliminated.
mers in a variety of applications. It is the responsibility of each system supplier and/or end user to assess the suitability of polyurea spray elastomers
for specific applications.
ASTM D 1308: Effect of household chemicals on clear and pigmented
organic finishes.
This test describes the spot test or watch glass method to simulate exposure
of the coating through possible spillage. Each chemical was in contact with the
elastomer system for a period of seven days, except where noted. Daily visual
Elastomer systems based on polyurea technology are good candidates for
coating and non-coating applications. In each application type, the chemical
resistance of the material could be of major importance
There are many factors which affect the chemical resistance of elastomer
systems including:
- Elastomer system formulation
- Service conditions
- Chemicals/impurities present in the system components
Tables 1 and 2 describe the chemical resistance of polyurea polymers. The
polyurea systems utilised are standard spray elastomer systems, including
both aromatic and aliphatic based elastomers. It is believed that these systems give a good representation of each particular type technology. For testing purposes, both ASTM D1308 and ASTM D3912 methods were utilised.
These tests were performed at 25C with visual observations being noted at
the end of the test procedures. Because of the simplicity of these tests and
due to the factors listed above - which are beyond the control of Huntsman
- no guarantee or warranty concerning the use of these elastomer systems
is either intended or implied, thus the chemical resistance should be determined on actual polyurea elastomers that are to be used. These test results
are reported to serve as a guide to the applicability of polyurea spray elasto-
12
observations were made on the elastomer and additional chemical was added
as needed. The tested area was covered with a watch glass to inhibit evaporation and /or contamination of the chemicals.
Table 1: Chemical resistance ASTM D 1308
Chemical
Aromatic polyurea
Aliphatic polyurea
Acetone
Brake Fluid
C
A
CLOROX , 10 %
NR1
Dimethyl formamide
NR
NR
Gasoline, unleaded
Hexane
Hot tub water 2
Hydraulic oil
JEFFAMINE D-400
NR
NR
Methanol
5% Methanol/gasoline
Motor oil
B1
B1
Propylene carbonate
Sodium hydroxide 5%
10%
25%
50%
B1
B1
13
COATINGS
COATINGS
Polyurea Spray
Polyurea Spray
PART 3
PART 3
Sulfuric acid, 5%
10%
50%
NR
NR
NR3
NR3
Vinegar, 5% acetic acid
conc.
Water
No visible damage
Little visible damage
Some effect-swelling, discolouration, cracking
NR
Not recommended
Swelling, <24 hrs
Some discolouration only
Brominated water
Less than 24 hour exposure
Table 3: Comparative polymer performance
Performance type
Polyurea
Polyurethane
Polyester
Epoxy
Vinyl ester
Acrylic
Polysulfide
Physical strength
Low-High
Low-Mid
High
High
High
Mid-High
Low-Mid
High
Elongation
High
High
Low
Low
Low
Low-Mid
Impact resistance
High
Mid-High
Mid
Mid
Mid
Mid-High
Mid-High
Abrasion resistance
High
Mid-High
Mid-High
Mid-High
Mid-High
Mid-High
Mid
Adhesion to concrete
Low-High
Low-Mid
Mid
High
Mid
Low-Mid
Low-Mid
Cure shrinkage
Low
Low
High
Low
High
High
Low
Permeability
Low
Mid-High
Low
Low
Low
Low-Mid
Mid-High
UV resistance
Mid-High
Low-High
Mid-High
Low
Mid
High
High
Creep
Low
High
Low-Mid
Low-Mid
Low-Mid
Low-Mid
High
Temperature limit
Low-High
Mid
Low-Mid
Mid-High
Mid-High
Mid
Low-Mid
Mineral acids
Low-Mid
Low-Mid
Mid-High
Mid-High
Mid-High
Mid
Low-Mid
Organic acids
Mid
Low-Mid
High
Mid
High
Mid
Low-Mid
Alkalis
Mid-High
Low-Mid
Mid
High
High
High
Low-Mid
Chlorinated solvents
Low-Mid
Low-Mid
Low-Mid
Low-Mid
Mid-High
Low-Mid
Low-Mid
Oxygenated solvents
Low-Mid
Low-Mid
Low-High
Low-High
Mid-High
Low-High
Low-Mid
Hydrocarbon solvents
Low-Mid
Low-Mid
Mid-High
Mid-High
Mid-High
Low-High
Low-Mid
Salts
High
Mid-High
High
High
High
High
Mid-High
Water
High
Low-High
Mid-High
Mid-High
Mid-High
Mid-High
Low-High
Chemical resistance
ASTM D 3912 :
Chemical resistance of coating used in light-water nuclear power plants.
This test method describes the immersion method of exposure for a coating system to chemicals. In this testing procedure, a black pigmented aromatic polyurea
spray elastomer system was used. This system was spray-applied to 2 mm blast
Table 2
profile steel panels, giving total encapsulation. These coated panels were then
Health and safety
immersed half way into individual chemicals for a period of 1 year at 25C,
Potential health and safety hazards associated with the spray application de-
except were noted. The panels were then removed and inspected.
scribed in this bulletin may arise from both the toxicological properties of the
chemical components and from the mechanical aspects of the high pressure
Chemical resistance ASTM D 3912
equipment involved. Before undertaking any spray work, the applicator should
Methanol
Sulphuric acid/5 %
be thoroughly familiar with the safe operation of the equipment and should follow
Gasoline
Sulphuric acid/10 %
all instructions and safety precautions provided by the manufacturer of the
Diesel fuel
Hydrochloric acid/5 %
equipment. Particular care should be taken that the spray nozzle is never directed
Toluene
Hydrochloric acid/10 %
towards anyones face or body during operation. Under normal equipment oper-
MTBE
Phosphoric acid/10 %
ating conditions, the isocyanate component and the resin component of the
5% MTBE/gasoline
Ammonium hydroxide/10 %
polyurea spray system react almost instantaneously so that there is no excess of
Motor Oil
Ammonium hydroxide/20 %
either isocyanate or amine exiting from the spray nozzle. However, even under
Hydraulic fluid
Sodium hydroxide/10 %
ideal operating conditions, very small amounts of unreacted MDI (4, 4-diphenyl-
2-Methylbutane
Sodium hydroxide/ 20 %
methane diisocyanate), or IPDI (isophorone diisocyanate) depending on the for-
Water/Room temperature
Sodium hydroxide/50 %
mulation of the isocyanate component, or DETDA (diethyltoluene diamine) or
Water/82C, 14 days
Sodium hydroxide/1%,50C, 14 days
IPDA (isophorone diamine) depending on the formulation of the resin compo-
10% NaCL/water/room temp
Potassium hydroxide/10 %
nent, may be present as an aerosol or vapour. Prior to handling or using any
10% NaCL/water/50C, 14 days
Potassium hydroxide/20%
component of a polyurea spray system or engaging in polyurea spray work, the
10 % Sugar/water
Acetic acid/10%
manufacturers Material Safety Data Sheet (MSDS) for both the isocyanate
component and the resin component should be reviewed for their recommenda-
No visible damage
tions for appropriate respiratory and dermal protection measures when handling,
Slight surface change
using or spraying their products. Additional information available from Huntsman
Slight surface discolour, no hardness loss
about safe handling of the different components should be consulted as well.
Swelling, <48 hrs
To minimise any risk due to exposure to chemicals used or the particulate matter
Swelling, <24 hrs
created in polyurea spray applications, spraying should be done only in a wellventilated location (either outdoors or by use of mechanical fans), or in a properly
In addition to the chemical resistance chart above, we have included a compara-
ventilated spray booth. Applicators should wear the appropriate personal protec-
tive polymer guide (Table 3) to familiarise customers with the relative performance
tive clothing and equipment. In areas with poor ventilation, or where oxygen sup-
ranking of the polyurea chemistry with other available polymer systems. The
ply is at risk, supplied air breathing equipment must be worn.
information described here, along with Table 2, can be regarded as a general
guide to the chemical and performance benefits of polyureas.
14
15
For more literature or information,
please call our European headquarter
For SUPRASEC
Huntsman Polyurethanes
Everslaan 45
3078 Everberg
Belgium
Tel : +32 2 758 9420
Fax : +32 2 758 7420
[email protected]www.huntsman.com/pu/ACE
For JEFFAMINE, JEFFLINK
Huntsman Performance Products
Everslaan 45
3078 Everberg
Belgium
Tel : +32 2 758 9392
Fax: +32 2 758 9112
www.huntsmanpolyurea.com
The Huntsman story
Global resources for local needs
Huntsman Polyurethanes is a business division of Huntsman
Corporation. Huntsman is a global manufacturer and marketer of
differentiated chemicals. Its operating companies manufacture products for a variety of global industries including chemicals, plastics,
automotive, aviation, textiles, footwear, paints and coatings, construction, technology, agriculture, health care, detergent, personal
care, furniture, appliances and packaging. Originally known for pioneering innovations in packaging, and later rapid and integrated
growth in petrochemicals, Huntsman today has 14,000 employees
and 78 operations in 24 countries. The company had 2006 revenues of over $ 13 billion.
Huntsman Polyurethanes warrants only that its products meet the
specifications agreed with the buyer. Typical properties, where stated, are to be considered as representative of current production
and should not be treated as specifications.
While all the information and recommendations in this publication
are to the best of our knowledge, information and belief accurate
at the date of publication, NO GUARANTY, WARRANTY OR
REPRESENTATION IS MADE, INTENDED OR IMPLIED AS TO THE
CORRECTNESS OR SUFFICIENCY OF ANY INFORMATION OR
RECOMMENDATION OR AS TO THE MERCHANTABILITY, SUITABILITY OR FITNESS OF ANY PRODUCTS FOR ANY PARTICULAR
USE OR PURPOSE. IN ALL CASES, IT IS THE RESPONSIBILITY
OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY
OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.
NOTHING IN THIS PUBLICATION IS TO BE CONSTRUED AS
RECOMMENDING THE INFRINGEMENT OF ANY PATENT OR
OTHER INTELLECTUAL PROPERTY RIGHT AND NO LIABILITY
ARISING FROM ANY SUCH INFRINGEMENT IS ASSUMED.
NOTHING IN THIS PUBLICATION IS TO BE VIEWED AS A LICENCE
UNDER ANY INTELLECTUAL PROPERTY RIGHT.
Products may be toxic and require special precautions in handling.
The user should obtain Safety Data Sheets from Huntsman
Polyurethanes and Huntsman Performance Products containing
detailed information on toxicity, together with proper shipping,
handling and storage procedures, and should comply with all
applicable safety and environmental standards.
Hazards, toxicity and behaviour of the products may differ when
used with other materials and are dependent on the manufacturing
circumstances or other processes. Such hazards, toxicity and
behaviour should be determined by the user and made known to
handlers, processors and end users.
JEFFAMINE, JEFFLINK, SUPRASEC, and RUBINATE are registered trademarks of Huntsman CORPORATION or an affiliate thereof,
in one or more countries, but not all countries.
Copyright 2007Huntsman CORPORATION or an affiliate thereof.
All rights reserved.
