1.
Mohrs salt is a
4. Copper complex of ethylene
(a) Single salt
(a) Unidentate ligand
(b) Double salt
(b) Tridentate ligand
(c) Complex salt
(c) Polydentate ligand
(d) Chelate
(d) Chelate
2. Potassium Ferro cyanide is
5. In potassium ferroayanide, the
coordination number of iron is
(a) Sigma compound
(a) Two
(b) Pi compound
(b) Four
(c) Double salt
(c) Six
(d) Complex salt
(d) Eight
6. The coordination number of Ag in
3. Ethylene diamine is
(a) Unidentate ligand
(b) Bidentate ligand
(c) Polydentate ligand
(d) Chelating ligand
potassium argent cyanide is
(a) One
(b) Two
(c) Three
(d) Four
7. The oxication number of Cu in
10. The neutral complex is.
[Cu[NH3]4]SO4 is
(a) K[Ag (CN)2]
(a) One
(b) [Ag (NH3)2] Cl
(b) Two
(c) Ni (CO)4
(c) Three
(d) [CO (Cl6)]3
(d) Four
11. Which one of the following
compounds will exhibit linkage
isomerism?
8. Potassium hexacyanoferrate (II) is
(a) [Pt (NH3)2 Cl2]
(a) Anionic complex
(b) [Co (NH3)5 NO2] Cl2
(b) Caironic complex
(c) [Co (NH3)4 Cl2] NO2
(c) Neutral complex
(d) [Ag (NH3)2] NO2
(d) None of these
12. Which one of the following complexes
9. Diammine silver (I) chloride is
(a) Anionic complex
(b) Cationic complex
(c) Neutral complex
(d) Chelating complex
will show ionization isomerism?
(a) [Co (NH3)4 Cl2] NO2
(b) [Cr (H2 O]6 Cl3
(c) [Co (NH3)6] [Cr (CN)6]
(d) K (Ag (CN)2]
13. Diaminopropane exhibit
16. Which of the complexes has bonds
only
(a) Coordinate isomerism
(a) Ni (CO)4
(b) Lignad isomerism
(b) Pb (C2 H5)4
(c) Linkage isomerism
(c) Fe (C5 H5)2
(d) Optical isomerism
(d) Fe (CO)5
14. Dichloro diammine platinum exhibit
17. Ferrocene complex is
(a) Optical isomerism
(a) Sigma bonded
(b) Geometrical isomerism
(b) bonded
(c) Linkage isomerism
(c) Both of there
(d) Coordination isomerism
(d) None of these
15. Out of the following which complex
will exhibit optical isomerism?
18. Which one of them is not a bonded
complex
(a) Ni (CO)4
(a) Dibenzene Chromium
(b) Na2 [Ni (CN)4]
(b) CH3 Mg Br
(c) Co (H2 N. CH2. CH2 NH2) Cl2
(c) (C2 H5)2 Zn
(d) [Ni (H2 O)6]2+
(d) Al2 (CH3)6
19. Which one of the complex is not
(d) Rutherford
bonded
(e) Thompson
(a) Ferrocene
22.Radioactivity results from the decay of
(b) Dibenzene Chromium
unstable
(c) Ni (CO)4
(a) electrons.
(d) (CH3)2 Cd
(b) very light nuclei.
(c) heavy nuclei.
20. Among the following ions which one
(d) photons.
has the highest paramagnetism
(e) bonds.
(a) [Cr (H2 O)6 ]3+
23.Which type of radioactive emission has
(b) [Fe (H2 O)6 ]2+
the highest penetrating power?
(c) [Cu (H2 O)6 ]2+
(a) electrons
(d) [Zn (H2 O)6 ]2+
(b) beta particle
(c) alpha particle
21.Which of these scientists is responsible
(d) gamma rays
for coining the term radioactivity and is a
lso the only person to
(e) neutrons
receive two noble prizes in science?
(a) Becquerel
(b) Curie
(c) Einstein
24.Which of these statements about fissio
n is incorrect?
(a) Fission reactions release a large amount
(a) Why spectral lines appear when atoms
of energy.
are heated.
(b) Two lighter nuclei combine to form a hea
(b) The energies of the spectral lines for
vier nuclei.
each element.
(c)Fission of uranium238 is initiated by the
(c) Why electrons travel in circular orbits
absorption of a neutron.
around the nucleus.
(d) Fission of uranium238 nuclei was at the
(d) none of the above answers is correct.
heart of the first atomic bomb.
(e) Fermi mistakenly discovered fission tryi
ng to synthesize a new element.
27. Line spectra are caused primarily
by:
(a) The existence of many ground states in
25. What piece of laboratory equipment is
an atom
best-suited for accurately measuring the
volume ofa liquid?
(b) The existence of many excited states in
an atom
(a) graduated cylinder
(c) The existence of many atoms in a typical
(b) beaker
sample
(c) Erlenmeyer flask
(d) None of the above
(d) more than one of the above
28. A continuous spectrum is caused
primarily by:
26. Bohrs model of the atom was able to
accurately explain:
(a) The presence of so many excited states
that the lines all blur together into arainbow.
(b) The presence of so many ground states
(c) The repulsion between bonds helps
that the lines all blur together into arainbow.
determine the shapes of covalent molecules.
(c) The presence of many atoms in a typical
(d) None of these statements is correct.
sample.
(d) None of the above
31. Carbon disulfide undergoes a single
displacement reaction with oxygen to
form carbon dioxide. If 100 grams of
carbon dioxide are reacted with 50 grams
29. The magnetic quantum number of an
orbital defines:
(a) The energy level of the orbital
(b) The shape of the orbital
(c) The spatial orientation of the orbital
(d) The spin of the electrons in the orbital
30. VSEPR basically states that:
of oxygen, what will the limiting reagent
be?
(a) carbon disulfide
(b) carbon dioxide
(c) oxygen
(d) sulfur
32. The difference between dipole-dipole
forces and hydrogen bonds are that:
(a) The repulsion of atomic nuclei help
determine the shapes of covalent molecules.
(a) dipole-dipole forces only exist between
nonpolar molecules
(b) The repulsion between electrons helps
determine the shapes of covalent
(b) dipole-dipole forces occur between polar
molecules
Molecules.
(c) dipole-dipole forces are caused by the
(a)Ni(CO)4 and NiCl42- are diamagnetic; and
interaction of partial charges on both
[Ni(CN)4] 2- is paramagnetic.
molecules.
(b) [Ni(CN)4]2- and NiCl42- are diamagnetic;
(d) None of the above are able to distinguish
and Ni(CO)4 is paramagnetic.
between dipole-dipole forces and hydrogen
(c)Ni(CO)4 and [Ni(CN)4]2- are diamagnetic;
bonds.
and NiCl42- is paramagnetic.
33. For which process would the heat be
negative?
(a) Changing the temperature of ice water to
0
50 C
(d)
Ni(CO)4 is
diamagnetic;
[Ni(CN)4]2- and NiCl42- are paramagnetic.
36. Bond angle in [SO3]2- is
(a) <109.5
(b) Condensing steam.
(c) Boiling water.
(d) more than one of the above
34. Which of the following elements shows
maximum number of different oxidation
states in its compounds?
(a) Eu
(b) La
(b) 109.5
(c) <120
(d) 120
37. The IUPAC name for the complex
[Co(en)2Cl(ONO)]+ is
(a) Cobalt diethylenediaminechloranitrate
(b) Chlorodiethylenediaminenitrito
cobalt(II)
(c) Gd
(c) Chloronitritodiethylenediamine
(d) Am
cobalt(III)
(d) Chlorobis(ethylenediamine)nitrito
35.Amongst Ni(CO)4, [Ni(CN)4]2- and
NiCl42-:
cobalt(III)
38.The elevation of boiling point was 0.52
0
C when 6 g of compound X was dissolved
in 100g water. Molecular weight of X is
( Kb of water = 0.52 K mol-1)
41.What is the major product of the
following reaction?
(a) 120 g
(b) 60 g
(c) 600 g
(d) 180 g
(a) S-2-butanol
(b) R-2-butanol
(c) a racemic mixture of 2-butanol
(d) the hemiketal of 2-butanone and
39.Toluene is nitrated and the resulting
product is reduced with tin and
hydrochloric acid.
The product so obtained is diazotized and
then heated with cuprous bromide. The
reaction mixture so formed contains
(a)mixture of o and pbromotoluenes
(b)mixture of o and pdibromobenzenes
(c)mixture of o and pbromoanilines
methanol...2-hydroxy-2-methoxybutane
42. Synthetic rubber is made by
polymerization of
(a) chloroform
(b) acetylene
(c) divinyl acetylene
(d) chloroprene
43. Which ofthem is most reactive one
(d) mixture of o and mbromotoluenes
(a)Alkane
40. Sulfonamides are metabolized by
(b)Alkyne
humans principally by
(a) acetylation
(b) deamination
(c)Alkene
(d)Benzene
(c) oxidation
(d) conjugation
44. Ketones are prepared by the oxidation
(e)methylation
of
(a) primary alcohol
(d) Nucleophilic substitution
(b) secondary alcohol
(c) tertiary alcohol
47. An alcohol is converted into an
aldehyde with same number of carbon
(d) none of these
atoms in the presence ofK2CrO4/H2SO4 .
The alcohol is
45. The compound with an atom which
has an unshared pair of electron is called
(a) nucleophile
(b) electrophile
(a)CH2C(CH)2OH
(b)CH3CH2CH2OH
(c)(CH3)3COH
(d)(CH3)2CHOH
(c) protophile
(d) none of these
46.when purely alcoholic solution of
sodium/potassium hydroxide and
halogenalkane are refluxed analkene is
48. when hexanedioic acid is heated with
hexamethylenediamine the compound
formed is
formed:CH3-CH2-Br (in presence of
alcoholic KOH )--- >CH2=CH2what is the
(a) polypeptide
mechanism of the reaction
(b) ester
(a) elimination
(c) addition polymer
(b) dehydration
(d) nylon 6,6
(c) debromination
49. Glucose and fructose are common
example of
50. PVC is an example of
(a) pentoses
(a) addition polymer
(b) hexoses
(b) condensation polymer
(c) heptoses
(c) biopolymer
(d) butoses
(d) thermosetting polymer
