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Ionic Compounds Bonding Worksheet

The document contains 3 chemistry problems involving ionic bonding calculations: 1) Use Born-Haber cycles to calculate missing enthalpy change values for forming BeI2, MnS, and Li2O ionic compounds. 2) Calculate the electron affinity of fluorine using standard enthalpy of formation values for SrF2. 3) Write balanced chemical equations in Lewis notation for forming the ionic compounds KBr, BaI2, Rb2Se, CaTe, and FrAt.

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Khalid Ibrahim Patel
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3K views2 pages

Ionic Compounds Bonding Worksheet

The document contains 3 chemistry problems involving ionic bonding calculations: 1) Use Born-Haber cycles to calculate missing enthalpy change values for forming BeI2, MnS, and Li2O ionic compounds. 2) Calculate the electron affinity of fluorine using standard enthalpy of formation values for SrF2. 3) Write balanced chemical equations in Lewis notation for forming the ionic compounds KBr, BaI2, Rb2Se, CaTe, and FrAt.

Uploaded by

Khalid Ibrahim Patel
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Chapter 8: Bonding in Ionic Compounds Worksheet #1

1. Use a Born-Haber Cycle to calculate the missing ∆H (bold reaction) of the following:

a. Be(g) Be2+(g) + 2 e– ∆H = +2660 kJ/mole


Be(s) Be(g) ∆H = +302 kJ/mole
1/2 I2(s) I(g) ∆H = +107 kJ/mole I
–
I(g) + e I–(g) ∆H = –295 kJ/mole
Be2+(g) + 2 I–(g) BeI2(s) ∆H = –2794 kJ/mole BeI2
Be(s) + I2(s) BeI2(s) ∆H = –208 kJ/mole BeI2

b. Mn(g) Mn2+(g) + 2 e– ∆H = +2230 kJ/mole


Mn(s) Mn(g) ∆H = 224 kJ/mole
S(s) S(g) ∆H = +264 kJ/mole
S(g) + 2 e– S2–(g) ∆H = +246 kJ/mole
2+ 2–
Mn (g) + S (g) MnS(s) ∆H = –3176 kJ/mole
Mn(s) + S(s) MnS(s) ∆H = –212 kJ/mole

c. Li(g) Li+(g) + e– ∆H = +540 kJ/mole


Li(s) Li(g) ∆H = +162 kJ/mole
1/2 O2(g) O(g) ∆H = +244 kJ/mole O
–
O(g) + 2 e O2–(g) ∆H = +598 kJ/mole
2 Li+(g) + O2–(g) Li2O(s) ∆H = –2800 kJ/mole Li2O
2 Li(s) + 1/2 O2(g) Li2O(s) ∆H = –554 kJ/mole Li2O

2. Calculate the EA of F(g), in kJ/mole, given the following:

IE1 + IE2 Sr(g) = +1580 kJ/mole


∆Hsublimation Sr(s) = +144 kJ/mole
∆Hdissociation F2 = +79 kJ/mole F
∆Hfo SrF2(s) = –1215 kJ/mole SrF2
∆Hlattice SrF2(s) = –2441 kJ/mole SrF2

EA F(g) –328kJ/mole F
3. Write a chemical equation in Lewis notation for the following:

a. potassium + bromine KBr

_
+
K + Br K Br

b. barium + iodine BaI2

_
2+ I
Ba + 2 I Ba _
I

c. rubidium + selenium Rb2Se

+ _
Rb 2
2 Rb + Se + Se
Rb
d. calcium + tellerium CaTe

2
_
2+
Ca + Te Ca Te

e. francium + astatine FrAt

_
+
Fr + At Fr At

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