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Perhitungan Reagen dan Transfer Massa

This document contains calculations for determining reagent amounts and mass transfer coefficients in a reactor. It provides the area and volume calculations for the reactor based on dimensions provided. It then calculates the amounts of reagents needed based on molar masses. Experiments were run at different air flow rates and calculations shown to determine holdup, circulation rates, and the mass transfer coefficient (KLa) between gas and liquid in the reactor. KLa values were found to be around 0.25 L/s across the different flow conditions tested.

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44 views5 pages

Perhitungan Reagen dan Transfer Massa

This document contains calculations for determining reagent amounts and mass transfer coefficients in a reactor. It provides the area and volume calculations for the reactor based on dimensions provided. It then calculates the amounts of reagents needed based on molar masses. Experiments were run at different air flow rates and calculations shown to determine holdup, circulation rates, and the mass transfer coefficient (KLa) between gas and liquid in the reactor. KLa values were found to be around 0.25 L/s across the different flow conditions tested.

Uploaded by

panji_gomis8416
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

LEMBAR PERHITUNGAN REAGEN

Tinggi Cairan

= 90 cm

Luas Area Riser (Ar)

= ( 8,3 cm x 14 cm) = 116,2 cm2

Luas Area Downcomer (Ad) = ( 5,2 cm x 14 cm) = 72,8 cm2


Volume Reaktor

= Luas alas total x tinggi cairan


= (116,2 cm + 72,8 cm) x 90 cm
= 18018 cm3 = 18,018 dm3

BM Na2SO3

= 126 gr/mol

BM Na2S2O3.5H2O

= 258 gr/mol

a. Na2S2O3.5H2O 0,1 N ( basis 500 ml )

= 6,45 gram
b. Na2SO3 0,01 N ( basis volume reaktor)

= 11,35 gram
c. KI 0,1 N @ 5 ml
d. Amilum 3 gr dalam 100 ml aquadest

LEMBAR PERHITUNGAN

1. Penentuan Hold Up Gas


= 0,0012 gr/ml
Z = 90 cm 15 cm = 75 cm
a. Variabel 1 (laju alir udara 4 cm3/s) hr = 0,7 cm ; hd = 0,5 cm
c ir n =
=

(79,12-29,29)gr
50 ml
hr

0,9966 gr/ml
(0,9966 0,0012)gr/ml
d

0,7
75

= 0,0093

hd
g
0,9966 gr/ml

= (0,9966
=
=

= 0,9966 gr/ml

0,0012)gr/ml
r r

0,2
75

= 0,0027

d d

(0,0186) 116,2) 0,0093) 72,8)


116,2 72,8)

= 0,015

b. Variabel 2 (laju alir udara 5 cm3/s) hr = 0,9 cm ; hd = 0,5 cm


c ir n =
r

(79,11-29,29)gr
50 ml
hr

g
0,9964 gr/ml

= (0,9964
d=

0,0012)gr/ml

0,9
75

= 0,012

hd
g

0,9964 gr/ml

= (0,9964
=
=

= 0,9964 gr/ml

0,0012)gr/ml
r r
r

0,5
75

= 0,0067

d d
d

(0,012) 116,2) 0,0027) 72,8)


116,2 72,8)

= 0,0084

c. Variabel 3 (laju alir udara 6 cm3/s) hr = 1,4 cm ; hd = 0,7 cm


c ir n =
r=

(79,06-29,29)gr
50 ml

hr
g
0,9954 gr/ml

= (0,9954
d=

= 0,9954 gr/ml

0,0012)gr/ml

1,4
75

= 0,0186

hd
g
0,9954 gr/ml

= (0,9954

0,0012)gr/ml
r r

0,7
75

= 0,0093

d d
d

(0,0093) 116,2) 0,0067) 72,8)

116,2 72,8)

= 0,0083

2. Perhitungan Laju Sirkulasi


Lc = 30 cm

r=

d
r

a. Variabel 1 (laju alir udara 4 cm3/s) tc = 2,85 s


d=

30 cm

=
=10,53 cm/
c 2,85

r=

= 10,53 m/
r

72,8 cm2
116,2 cm2

= 6,6 cm/

b. Variabel 2 (laju alir udara 5 cm3/s) tc = 2,43 s


d=

30 cm

=
=12,35 cm/
c 2,43

r=

= 12,35 m/
r

72,8 cm2
116,2 cm2

= 7,74 cm/

c. Variabel 3 (laju alir udara 6 cm3/s) tc = 2,32 s


d=
r=

30 cm

=
=12,93 cm/
c 2,32
d

= 12,93 m/
r

72,8 cm2
116,2 cm2

= 8,1 cm/

3. Perhitungan Koefisien Transfer Massa Gas-Cair (KLa)


Reaksi dalam reaktor :
Na2SO3 + 0,5 O2 Na2SO4 + Na2SO3(sisa)
Reaksi saat analisa :
Na2SO3(sisa) + KI + KIO3 Na2SO4 + 2KIO2 + I2(sisa)
I2 (sisa) + 2 Na2S2O3 Na2S4O6 + 2NaI

Mol Na2SO3 mula-mula (a) =


Mol I2 excess (b) =

re

or

e
1

Mol Na2SO3 sisa (c) = - 2 (


Mol O2 yang bereaksi (d) =

e
1

2 2

-c)

O2 yang masuk reaktor (e) =

2
60

Koefisien transfer massa gas-cair (KLa)

a. Variabel 1 (laju alir udara 4 cm3/s)


t
(menit)

V titran
(ml)

a
(mmol)

0
5
10
15
20

7,9
8,9
8,3
8,3
8,3

90,09
90,09
90,09
90,09
90,09

b
(mmol)

c (mmol)

d (mmol)

e
(mgr/s)

KLa
(L/s)

0,5
0,48025
0,5
0,47775
0,5
0,47925
0,5
0,47925
0,5
0,47925
KLa rata-rata (L/s)

44,8049
44,8061
44,8054
44,8054
44,8054

0
4,78
2,39
1,593
1,195

0
0,597
0,299
0,199
0,149
0,249

c (mmol)

d (mmol)

e
(mgr/s)

KLa
(L/s)

0,5
0,47575
0,5
0,48
0,5
0,4795
0,5
0,4795
0,5
0,4795
KLa rata-rata (L/s)

44,8071
44,805
44,80525
44,80525
44,80525

0
4,78
2,39
1,593
1,195

0
0,597
0,299
0,199
0,149
0,249

b. Variabel 2 (laju alir udara 5 cm3/s)


t
(menit)

V titran
(ml)

a
(mmol)

0
5
10
15
20

9,7
8
8,2
8,2
8,2

90,09
90,09
90,09
90,09
90,09

b
(mmol)

c. Variabel 3 (laju alir udara 6 cm3/s)


t
(menit)

V titran
(ml)

a
(mmol)

0
5
10
15
20
25

7,6
7,8
7,9
7,8
7,8
7,8

90,09
90,09
90,09
90,09
90,09
90,09

b
(mmol)

c (mmol)

d (mmol)

e
(mgr/s)

KLa
(L/s)

0,5
0,481
0,5
0,4805
0,5
0,48025
0,5
0,4805
0,5
0,4805
0,5
0,4805
KLa rata-rata (L/s)

44,8045
44,80475
44,8049
44,80475
44,80475
44,80475

0
4,779
2,39
1,593
1,195
0,956

0
0,597
0,299
0,199
0,149
0,119
0,227

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