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Infrared Absorption Guide

The document lists various infrared absorption frequencies and the bond or compound types they correspond to: 1) It describes characteristic frequency ranges for bonds in alkanes, alkenes, alkynes, aromatic rings, alcohols, ethers, carboxylic acids, esters, aldehydes, ketones, amines, and nitro compounds. 2) Specific frequencies are given for C-H, C=C, C≅C, C-O, C=O, O-H, N-H, and C≡N bonds and scissoring/bending vibrations. 3) The ranges and intensities of absorption bands are indicated using descriptors like strong, medium

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Virendra Singh Rajput
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143 views1 page

Infrared Absorption Guide

The document lists various infrared absorption frequencies and the bond or compound types they correspond to: 1) It describes characteristic frequency ranges for bonds in alkanes, alkenes, alkynes, aromatic rings, alcohols, ethers, carboxylic acids, esters, aldehydes, ketones, amines, and nitro compounds. 2) Specific frequencies are given for C-H, C=C, C≅C, C-O, C=O, O-H, N-H, and C≡N bonds and scissoring/bending vibrations. 3) The ranges and intensities of absorption bands are indicated using descriptors like strong, medium

Uploaded by

Virendra Singh Rajput
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

CHARACTERISTIC INFRARED ABSORPTION FREQUENCIES Bond Compound Type Frequency range, cm-1 2960-2850(s) stretch Alkanes C-H CH3

Umbrella Deformation C-H Alkenes Aromatic Rings C-H Phenyl Ring Substitution Bands Phenyl Ring Substitution Overtones C-H Alkynes C=C Alkenes CC Alkynes C=C Aromatic Rings C-O C=O Alcohols, Ethers, Carboxylic acids, Esters Aldehydes, Ketones, Carboxylic acids, Esters Monomeric -- Alcohols, Phenols O-H Hydrogen-bonded -- Alcohols, Phenols Carboxylic acids N-H Amines C-N Amines CN Nitriles 1470-1350(v) scissoring and bending 1380(m-w) - Doublet isopropyl, t-butyl 3080-3020(m) stretch 1000-675(s) bend 3100-3000(m) stretch 870-675(s) bend 2000-1600(w) - fingerprint region 3333-3267(s) stretch 700-610(b) bend 1680-1640(m,w)) stretch 2260-2100(w,sh) stretch 1600, 1500(w) stretch 1260-1000(s) stretch 1760-1670(s) stretch 3640-3160(s,br) stretch 3600-3200(b) stretch 3000-2500(b) stretch 3500-3300(m) stretch 1650-1580 (m) bend 1340-1020(m) stretch 2260-2220(v) stretch 1660-1500(s) asymmetrical stretch 1390-1260(s) symmetrical stretch

NO2 Nitro Compounds

v - variable, m - medium, s - strong, br - broad, w - weak

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