Scribd
Upload
2K views3 pages

NMR & IR Analysis for Chemists

The document provides guidance on using NMR spectroscopy and other techniques to determine the structures of organic compounds. It lists the 1H NMR and other spectral data for 10 compounds and asks to propose the structure that corresponds to each set of data. Key steps include using NMR splitting patterns to determine the number and type of neighboring hydrogens, identifying functional groups from IR spectra, and drawing all possible structures that are consistent with the spectral and molecular formula data.

Uploaded by

Jules Bruno
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
2K views3 pages

NMR & IR Analysis for Chemists

The document provides guidance on using NMR spectroscopy and other techniques to determine the structures of organic compounds. It lists the 1H NMR and other spectral data for 10 compounds and asks to propose the structure that corresponds to each set of data. Key steps include using NMR splitting patterns to determine the number and type of neighboring hydrogens, identifying functional groups from IR spectra, and drawing all possible structures that are consistent with the spectral and molecular formula data.

Uploaded by

Jules Bruno
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

STRUCTURAL DETERMINATION Strategy: 1) Use IHD ______________________________ to determine if a ring or double or triple bond is present.

2) If an IR spectrum is provided use it to determine possible functional groups. 3) Use the integration of hydrogens to determine their split pattern. 4) Start Drawing!!! 1) Propose structures for compounds that fit the following 1H NMR data:

a) Formula: C4H6Cl2

1H

NMR: 2.18 (3H, singlet) 4.16 (2H, doublet) 5.71 (1H, triplet)

b) Formula: C10H14

1H

NMR: 1.30 (9H, singlet) 7.30 (5H, singlet)

c) Formula: C4H7BrO

1H

NMR: 2.11 (3H, singlet) 3.52 (2H, triplet) 4.40 (2H, triplet)

d) Formula: C9H11Br

1H

NMR: 2.15 (2H, quintet) 2.75 (2H, triplet) 3.38 (2H, triplet) 7.22 (5H, multiplet)

e) Formula: C5H10O

1H

NMR: 0.95 (6H, doublet) 2.10 (3H, singlet) 2.43 (1H, multiplet)

f) Formula: C3H5Br

1H

NMR: 2.32 (3H, singlet) 5.35 (1H, singlet) 5.54 (1H, singlet)

g) Formula: C11H14O

IR: 1730 cm-1

1H

NMR: 1.3 ppm (9H, singlet) 7.5 ppm (2H, doublet) 7.7 ppm (2H, doublet) 9.9 ppm (1H, singlet)

h) Formula: C5H8O2

IR: 1730 cm-1

1H

NMR: 2.1 ppm (1H, singlet) 3.6 ppm (3H, singlet)

i) Formula: C4H11N

IR: 3400 cm-1

1H

NMR: 1.0 ppm (6H, singlet) 2.1 ppm (1H, multiplet) 2.6 ppm (2H, doublet) 2.0 ppm (2H, singlet)

j) Formula: C5H10O2

IR: 1750 cm-1

1H

NMR: 1.1 ppm (3H, triplet) 1.3 ppm (3H, triplet) 2.3 ppm (2H, quartet) 4.1 ppm (2H, quartet)

k) Formula: C5H10O2

IR: 1700 cm-1

1H

NMR: 2.2 ppm (2H, triplet) 1.56 ppm (2H, multiplet)

1.33 ppm (2H, multiplet) 1.0 ppm (3H, triplet) 11.0 ppm (1H, singlet)

You might also like