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The leading tone is the seventh scale degree of the diatonic scale which in F Major is the note "E".
E
Generally, the leading note is the seventh tonal degree of the diatonic scale leading up to the tonic. For example, in the C major scale (white keys on a piano, starting on C), the leading note is the note B; and the leading note chord uses the notes B, D, and F: a diminished triad. In Music Theory, the leading note triad is symbolized by the Roman numeral vii°.
G
The tonic in any scale is the 1st scale degree. For example, in the key of F major, the tonic is F.