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Yes.
Glass, chemically treated (wet-plate negative) and then exposed to light was used.
North was against making slaves states in the west South wanted to make slave states in the west
Korea was isolationist during the Civil War as Japan and China had been earlier, and the country had absolutely nothing to do with the war or the affairs of other countries. After the war a US ship (named the William T. Sherman) attempted to make contact with Korea, but the Koreans captured the ship and slaughtered everyone aboard.
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