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1999, Physical Review B
The diagonal component xx and off-diagonal component xy of the complex dielectric tensor for the ferromagnetic compound NiMnSb are determined using ex situ spectroscopic ellipsometry and magneto-optic analysis over the spectral range from 0.7 to 6.2 eV. The effects of the overcoat on the raw data are removed by the analysis. First, the complex xx of thin-film NiMnSb were determined by ex situ spectroscopic ellipsometry; then xy was determined by analyzing Kerr rotation and ellipticity data using the determined xy data. Lorentz oscillators were used to model peaks seen in the xx spectra. The diagonal dielectric component xx is dominated by free-carrier effects below 1.15 eV, and dominated by interband transitions above 2.0 eV. The center energies of the Lorentz oscillators are consistent with the calculated band structure and minority-spin optical conductivity of NiMnSb. Joint density of states and optical conductivity calculated from xx (2) data with free-carrier effects removed shows onset energies at ϳ0.6 and ϳ0.2 eV, respectively. From a study of the xx and xy spectra, the Kerr rotation peak at lower energy is determined to be due to combined contributions from: ͑1͒ a crossover between the free-carrier effect and interband transitions, and ͑2͒ transitions involving spin-orbit coupling. The high-Kerr rotation peaks at higher energies result exclusively from transitions involving spin-orbit coupling. ͓S0163-1829͑99͒13615-4͔
2006
The magneto-optical spectra of NiMnSb were calculated in the framework of the Local Spin Density Approximation (LSDA) combined with Dynamical Mean-Field Theory (DMFT). Comparing with results based on plain LSDA, an additional account of many-body correlations via DMFT results in a noticably improved agreement of the theoretical Kerr-rotation and ellipticity spectra with corresponding experimental data.
Physical Review B, 2006
The magneto-optical spectra of NiMnSb were calculated in the framework of the Local Spin Density Approximation (LSDA) combined with Dynamical Mean-Field Theory (DMFT). Comparing with results based on plain LSDA, an additional account of many-body correlations via DMFT results in a noticably improved agreement of the theoretical Kerr-rotation and ellipticity spectra with corresponding experimental data.
Europhysics Letters (EPL), 2000
The composition in the surface region of the Heusler alloy NiMnSb has been studied using angle-resolved X-ray photoemission spectroscopy, low-energy electron diffraction and spin-polarized inverse photoemission. The results are consistent with a generally Mn-Sb terminal layer, though the surface composition is very sensitive to preparation. The surface composition has a critical influence on the polarization near the Fermi level in spin-polarized inverse photoemission. Under some conditions, the polarization at the Fermi level for normal incidence inverse photoemission can reach values very close to 100% above background.
Journal of Magnetism and Magnetic Materials, 2004
NiMnSb has attracted a great deal of interest as a spin injector/detector in spintronic devices because it has a Curie temperature of 728 K and is predicted to be half-metallic (100% spin polarized). NiMnSb has been reported to have greatly reduced surface polarization, and to lose its half metallicity above 80 K. Here we report the investigation of the surface polarisation and electronic structure of NiMnSb by measurement of the transport spin polarization using point contact Andreev reflection spectroscopy, and anomalous Hall effect in thin films on Si(0 0 1). A comparison to bulk properties is made. r
Applied Physics Letters, 2011
To date, the use of flash evaporation (FE) as a deposition technique for NiMnSb thin films has not yet been reported. In this letter, we report on NiMnSb thin films deposited on heated Si (111) substrates at 300 C via FE. Investigations of the structural characteristics and magnetic and magnetotransport properties of these thin films show typical features of a half-metallic ferromagnetic semi-Heusler alloy. The origin of the film's extraordinary magnetotransport behavior is examined under the perspective of spin-order levels attached to a grain-grain boundary-type structure.
Physical Review B, 2008
We report a detailed theoretical study of the thermal magnetic properties of the Ni sublattice in half-metallic NiMnSb. The study is performed in the temperature interval where the disordering of the Mn sublattice is weak and the properties of the Ni sublattice can play a crucial role. In earlier work it was suggested that the behavior of the Ni sublattice is responsible for the anomalies in the properties of NiMnSb detected experimentally at about 80 K. Because of high Curie temperature T C = 730 K the interval of weak Mn disorder extends up to the technologically important room temperature. We formulate a thermodynamic model where both transversal and longitudinal fluctuations of the magnetic moments are taken into account. The energies of the fluctuations are determined by means of the constrained calculations within the framework of density-functional theory. We show that the half-metallicity is robust with respect to the longitudinal atomic fluctuations in the ground-state ferromagnetic structure. On the other hand the half-metallicity imposes strong restrictions on the longitudinal fluctuations. In contrast to longitudinal fluctuations the transversal fluctuations disturb the half-metallicity. We show that the contributions of the longitudinal and transversal fluctuations to the temperature dependence of the Ni net magnetization compensate, which leads to a very weak variation of the Ni magnetization in a broad temperature interval. This feature is in agreement with experiment. Simultaneously a large amplitude of the fluctuations results in strong decrease in the spin polarization of the Ni DOS at the Fermi level. The calculated temperature dependence of the Ni spin polarization reveals a crossover in the temperature interval between 75 and 100 K that correlates with experimental features in the temperature dependences of the physical properties. Although this crossover cannot be interpreted as the transition from a half-metallic to a non-half-metallic state the half-metallicity of the ground state is an important factor determining the properties of the fluctuations and the temperature properties.
Physical Review B, 2001
From magnetic circular dichroism measurements of the Heusler alloy NiMnSb, in combination with other techniques, we show that a dramatic increase in the Mn and Ni moments occurs below a ''crossover'' transition temperature of about 80-100 K. This phase transition is well below the Curie temperature of NiMnSb ͑ϳ730 K͒. While the spin polarization near the Fermi level, from spin-polarized inverse photoemission, remains very high for k ʈ ϭ0, it is unlikely that NiMnSb is a half-metallic ferromagnet near room temperature.
Journal of Magnetism and Magnetic Materials, 2006
ABSTRACT The half-metallic NiMnSb alloy was tested as a possible fully polarized electrode in a magnetic tunnel junction. For this purpose, epitaxial NiMnSb(0 0 1) and NiMnSb/MgO(0 0 1) systems were grown by molecular beam epitaxy. Spin-polarized photoemission experiments using the synchrotron radiation at the ESRF were performed on both the uncovered NiMnSb(0 0 1) surface and on the NiMnSb/MgO(0 0 1) interface. Starting from a NiMnSb(0 0 1) uncovered surface presenting at room temperature a 40% polarization at the Fermi level measured in the whole Brillouin zone, this polarization was observed to dramatically decrease when a MgO(0 0 1) epitaxial barrier was grown on top of it. On the other hand, the X-ray absorption experiments clearly show some oxidization of Mn after growing the MgO layer. This behavior was confirmed by testing the electronic and chemical properties of a unique atomic plane of Mn grown on a Fe buffer layer, before and after growing a MgO layer on top of it.
IEEE Transactions on Magnetics, 2000
This work involved a study of the reproducibility of the process of combustion synthesis to produce Ni-Zn ferrites. The structural, morphological and magnetic characteristics of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and magnetometry using an alternating gradient magnetometer (AGM). The XRD diffractograms of the samples indicated that they are monophasic, crystalline, with crystallite sizes ranging from 21 to 38 nm, and have a homogeneous morphology consisting of agglomerates of spherical particles. The samples behaved as soft magnetic materials, with magnetization levels ranging from 37 to 47 emu·g -1 .
Applied Physics Letters, 1998
The first-order nature of the magnetic phase transformation at 360°C and the presence of a Bi-rich eutectic at 265°C have inhibited the application of MnBi thin films for high density magneto-optical data storage. It is suggested that partial substitution of Cr for Mn should both lower the Curie temperature, T c , and decouple the lattice and magnetic transitions so as to allow reversible Curie point writing. It is found experimentally that 10% substitution of Cr for Mn reduces the apparent T c to ϳ250°C while retaining a Kerr rotation angle greater than 1°at 633 nm, as measured through the silica glass substrate. Observations of increasing H c with temperature in both MnBi and ͑Mn,Cr͒Bi thin films suggest that the low-temperature phase is ferrimagnetic.
Applied Physics Letters, 2004
Magnetic and magnetocaloric properties of the new rare-earth-transition-metal intermetallic compound Gd3Co29Ge4B10 J. Appl. Phys. 111, 07E333 A less expensive NiMnGa based Heusler alloy for magnetic refrigeration J. Appl. Phys. 111, 07A923 Oscillation of the magnetic moment in modulated martensites in Ni2MnGa studied by ab initio calculations Appl. Phys. Lett. 100, 084106 Structure and exchange bias of Ni50Mn37Sn13 ribbons
Applied Physics Letters, 2008
We report time resolved magneto-optical measurements in InMnSb ferromagnetic films with 2% and 2.8% Mn contents grown by low temperature molecular beam epitaxy. In order to probe a possible interaction between the spins of photoexcited carriers and the Mn ions, we measured spin dynamics before and after aligning the Mn ions by applying an external magnetic field at temperatures above and below the samples’ Curie temperatures. We observed no significant temperature or magnetic field dependence in the relaxation times and attribute the observed dynamics entirely to the relaxation of photoexcited electrons in the conduction band where the s-d coupling with the localized Mn ions is significantly weaker compared to the p-d exchange coupling. We observed several differences in the optical response of our InMnSb samples which could have been influenced mainly by the samples’ growth conditions.
Physical Review B, 2004
The point contact Andreev reflection employing niobium tips was used to determine the degree of transport current spin polarization ͑P t ͒ at the free surface of bulk NiMnSb at 4.2 K. The data was analyzed within the framework of a modified version of the Blonder, Tinkham, and Klapwijk formulism taking into account the two spin polarized channels in the ferromagnet and treating the interface as a planar delta function barrier of height Z between free electron materials. We find that the measured spin polarization is rather insensitive to different surface preparations and magnetic domain structure, and the maximal value of the P t at Z = 0 is 44%, consistent with recent calculations of the surface reconstruction of NiMnSb. Saturation magnetization of the samples was found to be 3.6 B per formula unit indicative of a small amount of atomic disorder.
physica status solidi c
In present work, our research is mainly focused on the electronic structures, optical, and magnetic properties of XMnSb (X = Ni, Cu, Pd), Co2YZ (Y = Ti; Z=Si, Ge, Sn), and Co2YZ (Y =Mn; Z=Al, Ga, Si) Heusler compounds by using ab initio calculations within the generalized gradient approximation. The calculations are performed by using the Vienna ab initio simulation package based on the density functional theory. The band structure of these Heusler alloys for majority spin and minority spin were calculated and the majority spin states cross the Fermi level and thus have the metallic character, while the minority spin states open the band gaps around the Fermi level and thus have the narrow‐band semiconducting nature. We also find that these Heusler compounds have the indirect band gaps in the minority spin channel. The real and imaginary parts of dielectric functions and hence the optical functions such as energy‐loss function, the effective number of valance electrons and the effec...
physica status solidi (a), 2007
In this study we investigated the magneto-transport properties of the ohmic contact between polycrystalline NiMnSb thin films grown by pulsed laser deposition and n-type degenerate InSb (100) substrates. An unusual negative giant magnetoresistance (n-GMR) effect is found when the external magnetic field is parallel to the in-plane current direction. A similar effect is also observed when Ni films are deposited on InSb substrates. On the other hand, no n-GMR effect is displayed when the deposited film is nonmagnetic. Grazing-incidence X-ray reflectometry shows the formation of a low-density NiMnSb layer at the interface. The presence of such a layer coincides with the appearance of the n-GMR.We argue that the n-GMR effect is due to magnetic precipitates formed at the interface during the growth of the magnetic films. We propose that these precipitates align their magnetic moments in the direction of the external magnetic field and thus, the spin dependent scattering of the electrons is reduced. The effect of these precipitates on the magnetoresistance depends on the thermal processing of the system.
Physical Review B, 1997
The magneto-optical ͑MO͒ spectra of 15 ternary ferromagnetic compounds are investigated on the basis of local-density band-structure calculations. The key material of interest in this study is PtMnSb, for which the MO Kerr spectra are unusually large and quite different from that of, e.g., the isoelectronic compounds NiMnSb and PdMnSb. First we show that the spectral differences between NiMnSb, PdMnSb, and PtMnSb can be fully understood from their relativistic electronic structure. Further, we investigate the following ternary ferromagnetic compounds: PtMnSn, PtCrSb, PtFeSb, Pt 2 MnSb, Co 2 HfSn, NiMnAs, PdMnAs, PtMnAs, RuMnAs, PtMnBi, BiMnPt, and PtGdBi. Within the total group of alloys, we study the MO spectra of PtMnSb in relationship to the spin-orbit coupling strength; the magnitude of the 3d-magnetic moment; the degree of hybridization in the bonding; the half-metallic character, or, equivalently, the Fermi-level filling of the band structure; the intraband plasma frequency; and the influence of the crystal structure. We find that these characteristics form a unique combination in PtMnSb leading to its outstanding MO Kerr spectra. None of the other compounds can match up to PtMnSb in this respect. For the compounds NiMnAs, PdMnAs, PtMnAs, and, particularly, RuMnAs, whose MO spectra are not measured as yet, we predict Kerr spectra which look promising for ultraviolet laser light recording applications.
Journal of Applied Physics, 2004
NiMnSb half Heusler alloy films were prepared by molecular beam epitaxy ͑MBE͒ on InP͑001͒. The dc and rf magnetic properties were investigated by ferromagnetic resonance ͑FMR͒. The effective uniaxial anisotropy fields increased with increasing film thickness and reached nonzero asymptotic values. FMR linewidths rapidly increased with the film thickness due to the presence of two magnon scattering. Bulklike uniaxial anisotropies and two magnon scattering were caused by a self-assembled network of lattice defects. Gilbert damping parameter and spectroscopic g factor were found to be 3.1ϫ10 7 and 2.03, respectively, indicating a weak role of spin orbit interaction.
The magneto-optical ͑MO͒ spectra of 15 ternary ferromagnetic compounds are investigated on the basis of local-density band-structure calculations. The key material of interest in this study is PtMnSb, for which the MO Kerr spectra are unusually large and quite different from that of, e.g., the isoelectronic compounds NiMnSb and PdMnSb. First we show that the spectral differences between NiMnSb, PdMnSb, and PtMnSb can be fully understood from their relativistic electronic structure. Further, we investigate the following ternary ferromagnetic compounds: PtMnSn, PtCrSb, PtFeSb, Pt 2 MnSb, Co 2 HfSn, NiMnAs, PdMnAs, PtMnAs, RuMnAs, PtMnBi, BiMnPt, and PtGdBi. Within the total group of alloys, we study the MO spectra of PtMnSb in relationship to the spin-orbit coupling strength; the magnitude of the 3d-magnetic moment; the degree of hybridization in the bonding; the half-metallic character, or, equivalently, the Fermi-level filling of the band structure; the intraband plasma frequency; and the influence of the crystal structure. We find that these characteristics form a unique combination in PtMnSb leading to its outstanding MO Kerr spectra. None of the other compounds can match up to PtMnSb in this respect. For the compounds NiMnAs, PdMnAs, PtMnAs, and, particularly, RuMnAs, whose MO spectra are not measured as yet, we predict Kerr spectra which look promising for ultraviolet laser light recording applications.
Journal of Magnetism and Magnetic Materials, 2005
Andreev reflection in point contacts between a ferromagnet and a superconductor has been developed in recent years as a method to measure the degree of spin polarization P of the ferromagnet. We have developed the method for planar thin-film edge contacts prepared by a seven-step process. Measurements of the conductance of an Nb/Cu edge junction showed the expected doubling of conductance for bias levels in the range 71.1 mV, corresponding to the superconducting energy gap of the Nb film ðT SC ¼ 6:5 KÞ: For Ni, however, the conductance falls to 20% of its normal value within the energy gap. A fit of the data gives P ¼ 70%; which is much greater than the currently accepted value of 46%. Possible explanations for the elevated spin polarization in these planar junctions are d-band narrowing and electron transfer to incorporated oxygen. r
Polarized neutron diffraction on NiMnSb shows a weak polarization on Ni parallel to the Mn moment, and a slight change in structure factors near 80 K which may be related to the loss of half-metallic character.
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