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2004, Physical Review B
We present the critical theory of a number of zero temperature phase transitions of quantum antiferromagnets and interacting boson systems in two dimensions. The most important example is the transition of the S = 1/2 square lattice antiferromagnet between the Néel state (which breaks spin rotation invariance) and the paramagnetic valence bond solid (which preserves spin rotation invariance but breaks lattice symmetries). We show that these two states are separated by a secondorder quantum phase transition. This conflicts with Landau-Ginzburg-Wilson theory, which predicts that such states with distinct broken symmetries are generically separated either by a first-order transition, or by a phase with co-existing orders. The critical theory of the second-order transition is not expressed in terms of the order parameters characterizing either state, but involves fractionalized degrees of freedom and an emergent, topological, global conservation law. A closely related theory describes the superfluid-insulator transition of bosons at half-filling on a square lattice, in which the insulator has a bond density wave order. Similar considerations are shown to apply to transitions of antiferromagnets between the valence bond solid and the Z2 spin liquid: the critical theory has deconfined excitations interacting with an emergent U(1) gauge force. We comment on the broader implications of our results for the study of quantum criticality in correlated electron systems.
Physical Review Letters, 2012
By means of nuclear spin-lattice relaxation rate T −1 1 , we follow the spin dynamics as a function of the applied magnetic field in two gapped one-dimensional quantum antiferromagnets: the anisotropic spin-chain system NiCl2-4SC(NH2)2 and the spin-ladder system (C5H12N)2CuBr4. In both systems, spin excitations are confirmed to evolve from magnons in the gapped state to spinons in the gapples Tomonaga-Luttinger-liquid state. In between, T −1 1 exhibits a pronounced, continuous variation, which is shown to scale in accordance with quantum criticality. We extract the critical exponent for T −1 1 , compare it to the theory, and show that this behavior is identical in both studied systems, thus demonstrating the universality of quantum critical behavior.
Arxiv preprint cond-mat/0411204, 2004
We show that despite the absence of a Hopf term and zero Berry phase terms, the Nèel ordered phase of 2 + 1 D quantum antiferromagnets have spin 1/2 excitations, i.e. spinons. The spinons are skyrmion excitations of a topological nature. Since skyrmion gap is proportional to the spin stiffness, quantum criticality corresponds to skyrmion gap collapse. We speculate that skyrmions are relevant at criticality and are, perhaps, related to recent suggestions of critical fractionalization.
EPL (Europhysics Letters), 2013
Deconfined quantum criticality of two-dimensional SU (2) quantum antiferromagnets featuring a transition from an antiferromagnetically ordered ground state to a so-called valencebond solid state, is governed by a non-compact CP 1 model with a Maxwell term in 2+1 spacetime dimensions. We introduce a new perspective on deconfined quantum criticality within a fieldtheoretic framework based on an expansion in powers of = 4 − d for fixed number N of complex matter fields. We show that in the allegedly weak first-order transition regime, a so-called conformal phase transition leads to a genuine deconfined quantum critical point. In such a transition, the gap vanishes when the critical point is approached from above and diverges when it is approached from below. We also find that the spin stiffness has a universal jump at the critical point.
EPL (Europhysics Letters), 2008
PACS 64.70.Tg-Quantum phase transitions PACS 71.20.Be-Transition metals and alloys PACS 71.10.-w-Theories and models of many-electron systems Abstract.-Charge, spin, and orbital degrees of freedom underlie the physics of transition metal compounds. Much work has revealed quantum critical points associated with spin and charge degrees of freedom in many of these systems. Here we illustrate that the simplest models that embody the orbital degrees of freedom-the two-and three-dimensional quantum orbital compass models-exhibit an exact quantum critical behavior on diluted square and cubic lattices (with doping δ = 1/4 and δ = 1/2 respectively). This raises the possibility of quantum critical points triggered by the degradation of orbital order upon doping (or applying pressure to) such transition metal systems. We prove the existence of an orbital spin glass in several related systems in which the orbital couplings are made non-uniform. Moreover, a new orbital Larmor precession (i.e., a periodic change in the orbital state) is predicted when uniaxial pressure is applied.
Science, 2004
The theory of second order phase transitions is one of the foundations of modern statistical mechanics and condensed matter theory. A central concept is the observable `order parameter', whose non-zero average value characterizes one or more phases and usually breaks a symmetry of the Hamiltonian. At large distances and long times, fluctuations of the order parameter(s) are described by a continuum field theory, and these dominate the physics near such phase transitions. In this paper we show that near second order quantum phase transitions, subtle quantum interference effects can invalidate this paradigm. We present a theory of quantum critical points in a variety of experimentally relevant two-dimensional antiferromagnets. The critical points separate phases characterized by conventional `confining' order parameters. Nevertheless, the critical theory contains a new emergent gauge field, and `deconfined' degrees of freedom associated with fractionalization of the order parameters. We suggest that this new paradigm for quantum criticality may be the key to resolving a number of experimental puzzles in correlated electron systems.
Science, 2000
Published in Science 288, 475 (2000).
Journal of the Physical Society of Japan
We examine magnetic structures of electron systems on an extended triangular lattice that consists of two types of bond triangles with electron transfer energies t ' and t 0 ' (' = 1, 2, and 3), respectively. We examine the ground state in the mean-field theory when t 1 ¼ t 0 1 , focusing on collinear states with two sublattices. It is shown that when the imbalance of the spatial anisotropies of the two triangles is large, up-up-down-down (uudd) phases are stable, and the most likely ground states of the λ-(BETS) 2 FeCl 4 system are the Néel state with the modulation vector ð=c; =aÞ and a uudd state, where c ¼ a 1 ¼ a 0 1 and a ¼ ða 2 þ a 0 2 Þ=2, with a 1 , a 0 1 , a 2 , and a 0 2 being the lattice constants of the bonds with t 1 , t 0 1 , t 2 , and t 0 2 , respectively. These results are consistent with those from the classical spin system. In addition, this study reveals behaviors near the quantum critical point, which cannot be reproduced in the localized spin model. As the imbalance of the spatial anisotropies increases, the U c of the Néel state increases, and that of the uudd state decreases. In the phase diagrams containing areas of the paramagnetic state, the Néel state with ð=c; =aÞ, and a uudd state, their boundaries terminate at a triple point, near which all the transitions are of the first order. The phase boundary between the antiferromagnetic phases does not depend on U, and the transition is of the first order everywhere on the boundary. By contrast, the transitions from the two antiferromagnetic phases to the paramagnetic phase are of the second order, unless the system is close to the triple point.
We examine the effective field theory of the Bethe ansatz integrable Heisenberg antiferromagnetic spin chains. It shows that the quantum critical theories for the integer spin-S chains should be characterized by the SO(3)level-S Wess-Zumino-Witten model, and classified by the third cohomology group $H^{3}(SO(3),Z)=Z$. Depending on the parity of spin S, this integer classification is further divided into two distinct universality classes, which are associated with two completely different conformal field theories: the even-S chains have gapless bosonic excitations and the odd-S chains have both bosonic and fermionic excitations. We further show that these two classes of critical states correspond to the boundary states of two distinct topological phases in two dimension, which can be described by two-dimensional doubled SO(3) topological Chern-Simons theory and topological spin theory, respectively.
Physica A: Statistical Mechanics and its Applications, 2014
Physical Review B, 2007
We perform a renormalization group analysis of some important effective field theoretic models for deconfined spinons. We show that deconfined spinons are critical for an isotropic SU(N) Heisenberg antiferromagnet, if N is large enough. We argue that nonperturbatively this result should persist down to N = 2 and provide further evidence for the so called deconfined quantum criticality scenario. Deconfined spinons are also shown to be critical for the case describing a transition between quantum spin nematic and dimerized phases. On the other hand, the deconfined quantum criticality scenario is shown to fail for a class of easy-plane models. For the cases where deconfined quantum criticality occurs, we calculate the critical exponent η for the decay of the two-spin correlation function to first-order in ǫ = 4 − d. We also note the scaling relation η = d + 2(1 − ϕ/ν) connecting the exponent η for the decay to the correlation length exponent ν and the crossover exponent ϕ. PACS numbers: 75.30.Kz,64.60.Cn,71.30.+h,
Physical Review B, 2011
The ground-state (GS) phase diagram of the frustrated spins J1-J2-J3 Heisenberg antiferromagnet on the honeycomb lattice is studied using the coupled cluster method implemented to high orders of approximation, for spin quantum numbers s = 1, 3 2 , 2 , 5 2. The model has antiferromagnetic (AFM) nearest-neighbour, next-nearest-neighbour and next-nextnearest-neighbour exchange couplings (with strength J1 > 0, J2 > 0 and J3 > 0, respectively). We specifically study the case J3 = J2 = κJ1, in the range 0 ≤ κ ≤ 1 of the frustration parameter, which includes the point of maximum classical (s → ∞) frustration, viz., the classical critical point at κ cl = 1 2 , which separates the Néel phase for κ < κ cl and the collinear striped AFM phase for κ > κ cl. Results are presented for the GS energy, magnetic order parameter and plaquette valence-bond crystal (PVBC) susceptibility. For all spins s ≥ 3 2 we find a quantum phase diagram very similar to the classical one, with a direct first-order transition between the two collinear AFM states at a value κc(s) which is slightly greater than κ cl [e.g., κc(3 2) ≈ 0.53(1)] and which approaches it monotonically as s → ∞. By contrast, for the case s = 1 the transition is split into two such that the stable GS phases are one with Néel AFM order for κ < κc 1 = 0.485(5) and one with striped AFM order for κ > κc 2 = 0.528(5), just as in the case s = 1 2 (for which κc 1 ≈ 0.47 and κc 2 ≈ 0.60). For both the s = 1 2 and s = 1 models the transition at κc 2 appears to be of first-order type, while that at κc 1 appears to be continuous. However, whereas in the s = 1 2 case the intermediate phase appears to have PVBC order over the entire range κc 1 < κ < κc 2 , in the s = 1 case PVBC ordering either exists only over a very small part of the region or, more likely, is absent everywhere.
Europhysics Letters (EPL), 2006
Recently it was argued that quantum phase transitions can be radically different from classical phase transitions with as a highlight the 'deconfined critical points' exhibiting fractionalization of quantum numbers due to Berry phase effects. Such transitions are supposed to occur in frustrated ('J1-J2') quantum magnets. We have developed a novel renormalization approach for such systems which is fully respecting the underlying lattice structure. According to our findings, another profound phenomenon is around the corner: a fluctuation induced (order-out-of-disorder) first order transition. This has to occur for large spin and we conjecture that it is responsible for the weakly first order behavior recently observed in numerical simulations for frustrated S = 1/2 systems.
Physical Review B, 2010
The spin texture surrounding a non-magnetic impurity in a quantum antiferromagnet is a sensitive probe of the novel physics of a class of quantum phase transitions between a Neel ordered phase and a valence bond solid phase in square lattice S=1/2 antiferromagnets. Using a newly developed T=0 Quantum Monte Carlo technique, we compute this spin texture at these transitions and find that it does not obey the universal scaling form expected at a scale invariant quantum critical point. We also identify the precise logarithmic form of these scaling violations. Our results are expected to yield important clues regarding the probable theory of these unconventional transitions.
Physical Review B, 2011
In certain Mott-insulating dimerized antiferromagnets, triplet excitations of the paramagnetic phase can decay into the two-particle continuum. When such a magnet undergoes a quantum phase transition into a magnetically ordered state, this coupling becomes part of the critical theory provided that the lattice ordering wavevector is zero. One microscopic example is the staggered-dimer antiferromagnet on the square lattice, for which deviations from O(3) universality have been reported in numerical studies. Using both symmetry arguments and microscopic calculations, we show that a non-trivial cubic term arises in the relevant order-parameter quantum field theory, and assess its consequences using a combination of analytical and numerical methods. We also present finite-temperature quantum Monte Carlo data for the staggered-dimer antiferromagnet which complement recently published results. The data can be consistently interpreted in terms of critical exponents identical to that of the standard O(3) universality class, but with anomalously large corrections to scaling. We argue that the two-particle decay of critical triplons, although irrelevant in two spatial dimensions, is responsible for the leading corrections to scaling due to its small scaling dimension.
Communications Physics
In quantum many-body systems with local interactions, the effects of boundary conditions are considered to be negligible, at least for sufficiently large systems. Here we show an example of the opposite. We consider a spin chain with two competing interactions, set on a ring with an odd number of sites. When only the dominant interaction is antiferromagnetic, and thus induces topological frustration, the standard antiferromagnetic order (expressed by the magnetization) is destroyed. When also the second interaction turns from ferro to antiferro, an antiferromagnetic order characterized by a site-dependent magnetization which varies in space with an incommensurate pattern, emerges. This modulation results from a ground state degeneracy, which allows to break the translational invariance. The transition between the two cases is signaled by a discontinuity in the first derivative of the ground state energy and represents a quantum phase transition induced by a special choice of boundar...
2003
Antiferromagnetic Heisenberg integer-spin chains are characterized by a spin-liquid ground state with no long-range order, due to the relevance of quantum fluctuations. Spin anisotropy, however, freezes quantum fluctuations, and the system is magnetized in the presence of a sufficiently large easy-axis anisotropy. We numerically investigate the case S = 1, by means of the density-matrix renormalization group, and find that the freezing of the spin liquid into a Néel spin solid, with increasing easy-axis anisotropy, is a continuous quantum phase transition. Numerical evidence indicates that the transition is not in the two-dimensional Ising universality class. PACS numbers: 75.10.Jm, 75.30.Cr, 75.40.Mg Quantum fluctuations play a crucial role in antiferromagnetic (AFM) Heisenberg spin chains, as they are strong enough to suppress magnetic long-range order at zero temperature. Despite the common absence of a spontaneous staggered magnetization in the ground state, the physical properties are, however, different for integer and half-integer spin S [1]. Indeed, half-integerspin chains are characterized by a gapless excitation spectrum, power-law spin-spin correlations, and a divergent linear response to a staggered magnetic field, and are therefore usually considered as nearly ordered. The spectrum of integer-spin chains is instead gapped in the thermodynamic limit, with a finite linear response to staggered magnetic fields. The ground state is a spin liquid with finite spin-spin correlation length, and the gap to the first excited state is usually called Haldane gap.
150 Years Of Quantum Many-Body Theory - A Festschrift in Honour of the 65th Birthdays of John W Clark, Alpo J Kallio, Manfred L Ristig and Sergio Rosati, 2001
We discuss the influence of strong quantum fluctuations on zero-temperature phase transitions in a two-dimensional spin-half Heisenberg system. Using a high-order coupled cluster treatment, we study competition of magnetic bonds with and without frustration. We find that the coupled cluster treatment is able to describe the zero-temperature transitions in a qualitatively correct way, even if frustration is present and other methods such as quantum Monte Carlo fail.
Journal of Physics: Condensed Matter, 2008
A recent study revealed the dynamics of the charge sector of a one-dimensional quarter-filled electronic system with extended Hubbard interactions to be that of an effective pseudospin transversefield Ising model (TFIM) in the strong coupling limit. With the twin motivations of studying the co-existing charge and spin order found in strongly correlated chain systems and the effects of inter-chain couplings, we investigate the phase diagram of coupled effective (TFIM) systems. A bosonisation and RG analysis for a two-leg TFIM ladder yields a rich phase diagram showing Wigner/Peierls charge order and Neel/dimer spin order. In a broad parameter regime, the orbital antiferromagnetic phase is found to be stable. An intermediate gapless phase of finite width is found to lie in between two charge-ordered gapped phases. Kosterlitz-Thouless transitions are found to lead from the gapless phase to either of the charge-ordered phases. A detailed analysis is also carried out for the dimensional crossover physics when many such pseudospin systems are coupled to one another. Importantly, the analysis reveals the key role of critical quantum fluctuations in driving the strong dispersion in the transverse directions, as well as a T = 0 deconfinement transition. Our work is potentially relevant for a unified description of a class of strongly correlated, quarter-filled chain and ladder systems.
Nuclear Physics B, 2007
It has been proposed that there are new degrees of freedom intrinsic to quantum critical points that contribute to quantum critical physics. We study 2+1 D antiferromagnets in order to explore possible new quantum critical physics arising from nontrivial topological effects. We show that skyrmion excitations are stable at criticality and have nonzero probability at arbitrarily low temperatures. To include quantum critical skyrmion effects, we find a class of exact solutions composed of skyrmion and antiskyrmion superpositions, which we call topolons. We include the topolons in the partition function and renormalize by integrating out small size topolons and short wavelength spin waves. We obtain a correlation length critical exponent ν = 0.9297 and anomalous dimension η = 0.3381.
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