ABSTRACT The reaction of organoiron sulfanes, (μ-Sx)[FeCp(CO)2]2 (x = 3, 4) with LiBEt3H at −97°C gives the anionic species [Cp(CO)2FeSx]− (x = 1, 2 or 3). The solution containing the anionic species reacts with acid chlorides RCOCl to give [FeCp(CO)2(SCOR)], which contain the S-bonded monothiocarboxylate ligand. The same products and [FeCp(CO)2Cl] were obtained from the reaction of (μ-Sx)-[FeCp(CO)2]2 (x = 3,4) and RCOCl at room temperature.
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