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1999, Water Research
ÐThis paper deals with an experimental study describing the treatment of land®ll leachate by means of a pilot-scale reverse osmosis unit. Leachate streams with a CO parameter in the range of 0± 1749 mg l À1 have been adopted. The¯ux rate of the permeate through the membrane decreased linearly with the COD factor. The rejection coecient of COD was practically independent of the COD value, but was signi®cantly aected by the applied pressure. By operating at 53 atm, COD rejection values around 98% were obtained. Finally, the eect of COD on the separation of some heavy metals was investigated. For most metals this in¯uence was negligible. Only the rejection coecient of Zn decreased signi®cantly upon increasing the COD of the leachate stream.
Sanitary landfilling is nowadays the most common way to eliminate municipal solid wastes, although waste management hierarchy considers landfilling as a last option. The resultant leachate produced due to waste transformation and rainfall can be identified by specific characteristics and variables, corresponding to high-strength wastewaters, which generate impacts and risks in the environment. This situation imposes stringently leachate treatment by appropriate and efficient methods and processes. This research analyzes the performance of a municipal waste landfill leachate treatment system applying a membrane processreverse osmosis (RO), for almost a year of operation. The system equipped with disc-tube (DT) membrane modules, and located in the sanitary landfill of the city of Iasi, Romania includes two stages: LEACHATE stage and PERMEATE stage, preceded by a pre-treatment module consisting of sand and cartridge filters. A storage system is included in the flow-sheet, for cleaning agents and various chemicals. Pumping stations provide the necessary operating pressure in the system. A removal efficiency of contaminants (COD, NH 4 + , electrical conductivity etc.) exceeding 90% was achieved. Any variation in permeate flux (14-22 L/m 2 h) and separation efficiency (94-100%) was due to increasing osmotic pressure and fouling, scaling and polarization of concentration. The RO process demonstrated a high rejection rate for both organic and inorganic contaminants dissolved in the leachate, together with a high flexibility alongside the changes in the leachate composition, depending on pressure, temperature, pH feeding flow rate of leachate.
2017
An assessment of the treatment of sanitary landfill leachate with the help of reverse osmosis and potential of treated leachate for reuse was carried out at a sanitary landfill located in Srinagar city of Jammu and Kashmir. The untreated leachate contained high organic and inorganic load having high concentrations of BOD, COD, total nitrogen, ammonia, chloride and trace metals. Treatment plant operating on the principle of reverse osmosis indicated an overall removal efficiency of approx. 90%. Very high rejection rates were obtained for BOD (99.7%), COD (98%) and TDS (94%). The rejection rates of various trace metals ranged from 76% to 99.99%. The results revealed reverse osmosis as a promising technology for the treatment of landfill leachate and also the positive and productive potential of treated leachate for reuse.
DESALINATION AND WATER TREATMENT
This manuscript presents results of research developing efficient techniques to treat landfill leachate of the largest landfill in Europe located 30 km east of the City of Moscow. The leachate constitutes the complicated chemical solute that contains over 4,500 ppm of organics expressed by chemical oxygen demand (COD), over 5,000 ppm of salts expressed as total dissolved solids (TDS), over 2,500 ppm of ammonia expressed as NH 3. Treatment of this leachate requires complex solution unique to the constituents. Reverse osmosis treatment can address reduction of TDS, COD and ammonia to meet discharge criteria; the target was to reach maximum recovery and utilize RO concentrate; to ensure adequate pretreatment of wastewater that enters RO concentrate; to provide adequate post-treatment of product water prior to discharge. Conventional approach for this challenge involves application of three stages of RO to reduce ammonia concentration to the value of 0.2-1.0 ppm. The first stage of RO requires "direct" treatment of high TDS wastewater with "seawater" membranes under high pressure value of 50-60 Bars followed by two stages of RO at low pressure to reduce ammonia concentration. The newly proposed approach is consists from low pressure RO and nanofiltration (NF) membranes to dramatically decrease operational costs and increase system recovery up to 90% and higher using the same total membrane area. The proposed technique is based on results of experimental investigation that evaluated organic fouling and scaling rates in membrane channels and membrane flow and rejection values as functions of recoveries at each stage of membrane treatment.
Catalysts
An integral treatment process for landfill leachate reverse osmosis concentrate (LLROC) is herein designed and assessed aiming to reduce organic matter content and conductivity, as well as to increase its biodegradability. The process consists of three steps. The first one is a coagulation/flocculation treatment, which best results were obtained using a dosage of 5 g L−1 of ferric chloride at an initial pH = 6 (removal of the 76% chemical oxygen demand (COD), 57% specific ultraviolet absorption (SUVA), and 92% color). The second step is a photo-Fenton process, which resulted in an enhanced biodegradability (i.e., the ratio between the biochemical oxygen demand (BOD5) and the COD increased from 0.06 to 0.4), and an extra 43% of the COD was removed at the best trialed reaction conditions of [H2O2]/COD = 1.06, pH = 4 and [H2O2]/[Fe]mol = 45. An ultra violet-A light emitting diode (UVA-LED) lamp was tested and compared to conventional high-pressure mercury vapor lamps, achieving a 16% p...
Facta Universitatis, Series: Working and Living Environmental Protection, 2020
The purpose of this paper is to elaborate a plan for the leachate treatment at the “Zeljkovac” sanitary landfill in Leskovac city. Different processes occur over time at the landfill. The processes of infiltration and transpiration occur continuously, distributing the humidity and affecting the water balance within the body of the landfill. The landfill body acts as a giant sponge, in which water moves, and from which water can be released - both into groundwater and into the atmosphere in the form of water vapour or as a filtrate at the bottom of the landfill. In this paper, particular attention is given to the kind of waterwhich is actually filtrate from a landfill, often called leachate. The efficiency of the most commonly used methods will be presented, depending on the most prevalent pollutants in leachate. As there are many methods for treating this kind of wastewater, the reverse osmosis method will be presented as one of the most widely used . The technological process of ...
Membranes, 2018
Reverse osmosis (RO) and nanofiltration (NF) are among the state-of-the-art technologies for treating landfill leachates. Due to the complexity and variance in the composition of leachates, numerous combinations of multiple technologies are used for their treatment. One process chain for the treatment of raw leachate is RO followed by further concentration of RO-retentate using NF (RO-NF scheme). The aptness of this process train used by some landfill sites around the world (usually with the aim of volume reduction so as to re-inject the concentrate into the landfill) is questionable. This study investigated two schemes RO-NF and NF-RO (nanofiltration of raw leachate followed by reverse osmosis of NF permeate) to identify their merits/demerits. Experiments were conducted in bench scale using commercial membranes: DOW Filmtec NF270 and SW30HR. Filtration trials were performed at different pressures to compare the water and solute transports in the individual stages of the two schemes. Based on the water fluxes and compositions of retentates and permeates; osmotic pressures, energy demands, and other possible operational advantages were discussed. NF-RO offers some advantages and flexibility for leachate treatment besides being energy efficient compared to RO-NF, wherein osmotic pressure steadily increases during operation in turn increasing operation and maintenance costs.
Molecules, 2019
Electrochemical technologies have been broadly applied in wastewaters treatment, but few studies have focused on comparing the performance of the different electrochemical processes, especially when used to treat highly-polluted streams. The electrochemical treatment of a reverse osmosis concentrate of sanitary landfill leachate was performed by means of electrocoagulation (EC), anodic oxidation (AO) and electro-Fenton (EF) processes, and the use of different electrode materials and experimental conditions was assessed. All the studied processes and experimental conditions were effective in organic load removal. The results obtained showed that EC, with stainless steel electrodes, is the cheapest process, although it presents the disadvantage of sludge formation with high iron content. At high applied current intensity, AO presents the best treatment time/energy consumption ratio, especially if the samples’ initial pH is corrected to 3. However, pH correction from natural to 3 deepl...
Waste Management & Research: The Journal for a Sustainable Circular Economy, 2020
The reverse osmosis (RO) process has been increasingly applied to landfill leachate treatment. The published literature reports several studies that investigated the technical feasibility of RO. However, information about process costs is scarce. Also, companies that run leachate treatment plants do not provide actual costs. To fill this gap, this study aimed to evaluate the treatment costs of a full-scale RO for the treatment of landfill leachate located in Rio de Janeiro State, Brazil. A procedure was proposed to estimate the capital expenses (CAPEX), operational expenses (OPEX), and specific total treatment cost, the total cost per m3 of treated leachate, of the leachate treatment by membrane process, and the results obtained are discussed. The CAPEX for this full-scale RO was estimated at MUS$ 1.413, and OPEX ranged from US$ 0.132 to US$ 0.265 m−3 per year. The cost of leachate treatment has been estimated at US$ 8.58 m−3 considering the operation of the RO-unit for 20 years aft...
Waste Management, 2003
In this study, Membrane Filtration (UF+RO), Struvite (MAP) precipitation and ammonia stripping alternatives were studied on biologically pre-treated Landfill Leachate. The results indicated that the system including the Upflow Anaerobic Sludge Blanket Reactor (UASBR) and Membrane Reactors (UF+RO) has been offered as an appropriate treatment alternative for young landfill leachates. This system provided high removals of COD, colour and conductivity ( > 98-99%). For ammonia removal, struvite precipitation was applied at the stoichiometric ratio (Mg:NH 4 :PO 4 =1:1:1) to anaerobically pre-treated raw landfill leachate effluent having an influent ammonium concentration of 2240 mg/l. Maximum ammonium nitrogen removal was observed as 85% at pH of 9.2. In ammonia stripping following 2 h of aeration, the removal was 72% at pH=12 while the removals were around 20% at pH=10 and pH=11. When membrane reactor, and struvite precipitation or ammonia stripping was applied to anaerobically pretreated effluents, the results indicated that each system could be used as an appropriate post-treatment option for young landfill leachates. In economic aspect, ammonia stripping was found as the cheapest alternative with high ammonium removal. However, when both high COD and ammonium removals were to be achieved membrane technology such as UF+RO (SW) could be considered as the most appropriate system due to the fact that COD removal could be obtained very low by ammonia stripping. #
Leachate is created while water penetrates through the waste in a landfill, carrying some forms of pollutants. The aims of this study were the review on physical-chemical methods for landfill leachate treatment. The physical-chemical ways for landfill leachate treatment like Chemical precipitation, Chemical Oxidation, Coagulation-Flocculation, Membrane filtration, Ion exchange, Adsorption and Electrochemical treatment are studied. Chemical precipitation is generally used as pretreatment in order to remove high strength of ammonium nitrogen; fenton oxidation is one of these advanced oxidation processes with high efficiency and low capital costs; coagulation-flocculation has been used for the removal of nonbiodegradable organic compounds and heavy metals from landfill leachate; nanofiltration (NF) is one of membrane filter and it has found a place in the removal of recalcitrant organic compounds and heavy metals from landfill leachate; adsorption is the most widely used technique for the removal of recalcitrant organic compounds from landfill leachate; the ion-exchange method offers a number of benefits containing the ability to handle shock loadings and operate over a wider range of temperatures. The landfill leachate properties, technical applicability and constraints, effluent discharge alternatives, cost-effectiveness, regulatory requirements and environmental impact are important factors to selection of the most suitable treatment technique for landfill leachate treatment.
Revista Virtual de Química
The decomposition of the organic matter in municipal waste from landfills results in a highly polluted and toxic effluent, named sanitary landfill leachate. Due to the potential contamination for soil, groundwater and surface water bodies, the treatment of sanitary landfill leachate is essential to avoid environmental and public health damage. This study aims to evaluate the technical and environmental efficiency of reverse osmosis technology for the treatment of leachate in landfill from the Metropolitan Region of the Rio de Janeiro, Brazil. It was observed that the raw leachate from this landfill has highly polluting, and has chemical and physicochemical characteristics typical of mature landfills, with operation older than 5 years: pH = 7.85; ammonia nitrogen concentrations of 2,473.00 mg L-1 ; BOD 2,545.84 mg L-1 and COD 4,881.81 mg L-1 , respectively. Except for only one sampling, with phenol parameter, reverse osmosis was technically and environmentally efficient in mitigating pollutants present in the raw sanitary landfill leachate with excellent removal rates: E N (%) > 99%; E BOD (%) > 98%, and E COD (%) > 99%. After reverse osmosis treatment, the treated leachate was respecting Brazilian legislation and could be released into the local stream. During reverse osmosis treatment of 120 m 3 day-1 of leachate, prevented 107.84 kg year-1 of N from being released into nature; 110.95 kg year-1 of BOD, and 211.70 kg year-1 of COD, avoiding eutrophication from nearby rivers that inevitably flow into Guanabara Bay. It becomes a promising technology to face the impacts that pressure the Planetary Boundaries in the Anthropocene.
Environmental Chemistry Letters, 2019
Landfill leachates from municipal landfills are usually heavily contaminated and thus require treatments before direct discharge into natural waters. Selecting the appropriate technology for leachate treatment is still a major challenge for operations in municipal landfills. Biodegradation is effective for treating young leachates, whereas old leachates require processes such as chemical oxidation, coagulation-flocculation, chemical precipitation, ozonation, activated carbon adsorption, and reverse osmosis. Recently, the combination of biological pretreatments followed by physico-chemical processes has been shown to be very efficient. Here we review the efficiency of biological treatment in combination with reverse osmosis to clean landfill leachates. We studied in particular processes including a membrane bioreactor, activated sludge, a rotating biological contactor, and up-flow anaerobic sludge blanket treatments, followed by reverse osmosis. We found a 99-99.5% removal of the chemical oxygen demand (COD), and a 99-99.8% removal of N-NH 4 + using reverse osmosis and activated sludge. Using reverse osmosis with a rotating biological contactor, we observed 99% removal of COD, biochemical oxygen demand and N-NH 4 +. The combination of reverse osmosis, activated sludge and rotating biological contactor removed 98-99.2% of Cl − and 99-99.7% of Pb. Total suspended solids are best removed, up to 99%, by either a combination of reverse osmosis with membrane bioreactor, or reverse osmosis with activated sludge.
DESALINATION AND WATER TREATMENT, 2021
The purpose of this article is to develop an effective hybrid method for treating Oum Azza landfill leachate (Rabat, Morocco). The treatment system studied is membrane bioreactor technology (MBR) which consists of biological treatment associated with a unit of ultrafiltration for the retention of the biomass followed by a reverse osmosis (RO) filtration step in order to achieve the Moroccan discharge limits. The performances of RO on the advanced treatment efficiency are investigated in tube pressure configuration mode, in order to achieve high quality of permeate with higher recovery rate and minimization of brine discharges. At the end of this study, it can be concluded that the performance of the MBR can achieve the reduction in 5-day biochemical oxygen demand and chemical oxygen demand of the order of 87% and 76% respectively. The permeate analysis at the outlet reverse osmosis shows that the controlled parameters are below legal standards Moroccan of direct discharge in nature, especially total dissolved solids content.
Journal of Hazardous Materials, 2009
This study presents a configuration for the complete treatment of landfill leachate with high organic and ammonium concentrations. Ammonia stripping is performed to overcome the ammonia toxicity to aerobic microorganisms. By coagulation-flocculation process, COD and suspended solids (SS) were removed 36 and 46%, respectively. After pretreatment, an aerobic/anoxic membrane bioreactor (Aer/An MBR) accomplished the COD and total inorganic nitrogen (total-N i ) removals above 90 and 92%, respectively, at SRT of 30 days. Concentrations of COD and total-N i (not considering organic nitrogen) in the Aer/An MBR effluent decreased to 450 and 40 mg/l, respectively, by significant organic oxidation and nitrification/denitrification processes. As an advanced treatment for the leachate, the reverse osmosis (RO) was applied to the collected Aer/An MBR effluents. Reverse osmosis provided high quality effluent by reducing the effluent COD from MBR to less than 4.0 mg/l at SRT of 30 days.
E3S Web of Conferences
The aim of this work is to study the physicochemical characterization and monitoring of the treatment of leachate generated by the landfilling of household and similar waste in the landfill of Rabat-Salé-Kénitra Region. The analysis of the results showed a high concentration of easily biodegradable organic matter. The pollutant load is of the order of 3,850 mg/L of the chemical oxygen demand (COD), 1.260 mg/L of the biochemical oxygen demand (BOD5), and shows an average content of nitrates (NO3-=56.6 mg/L). This mineral pollution is caused by a high electrical conductivity, which reaches an average value of 15.9 mS/cm, and a low concentration of heavy metals in the raw leachate such as lead (Pb = 1.591 mg/L), copper (Cu = 1.017 mg/L), and cadmium (Cd = 0.109 mg/L). The biological treatment allows for the successive biodegradation of 40% of the BOD5, and 33% of the COD. Moreover, the reverse osmosis filtration in organic membranes achieves a reduction of 98% for BOD5, 97% for COD, 85...
International Journal of Environmental Research, 2012
One of the most important concerns in Tehran municipal landfill is the production of leachate and its potential for water resources pollution, this study was undertaken to examine feasibility of biological and physico/chemical treating of high-strength landfill leachate that was collected from Tehran municipal landfill. Average COD of the leachate in aerobic submerged membrane bioreactor is 68000 mg/L. The reactor with a working volume of 175 L, having membrane module (Hollow fiber) with pore size of 0.1 μm coupled with reverse osmosis with pore size of 0.001 μm was used in this study. The dissolved oxygen (DO) concentration was maintained at 3.2 mg/L and solid retention times (SRTs) and hydraulic retention times (HRT) were controlled at 55 and 15 days respectively. the average Membrane Bioreactor effluent COD was 1733 mg/L with average removal efficiency of 97.46%. The average NH 4 –N removal efficiencies was 99%. On the other hand, an almost complete nitrification was achieved dur...
This paper deals with the application of membrane separation processes for landfill leachate treatment. New methods that have wider usage and yield better results than conventional techniques are now being employed for remediation of contaminated sites. An important aspect to consider in the selection of a new technology is its economy. Among the new technical alternatives available are membrane separation processes. Membrane separation processes found wide use in recent years in many industries and their proliferation into areas dominated by other technologies is expected. These effective separation processes are already utilized in many areas of human endeavor including the removal of landfill leachates. The main focus of this paper is presentation of this worldwide used environmental-friendly technology and demonstration of efficiency on a real samples of czech landfill leachate.
One of the most important problems arising from landfilling solid wastes is the leachate which contains high amount of pollution. Discharge of leachate without treatment causes negative effects on environmental and public health. In this study, parameters of chemical oxygen demand (COD), total nitrogen (TN), ammonia nitrogen (NH 4 -N), and total phosphorus (TP) were examined in the samples taken from the influent and effluent of leachate treatment plant, where Odayeri landfill leachate is treated. Obtained results showed that the treatment plant, which consisted of preanoxic biological treatment system, ultrafiltration (UF) and nanofiltration (NF) units were operating with high efficiency. Among the examined parameters during study, COD, TN, NH 4 -N, and TP were found to be treated at the rate of 99, 94.5, 99, and 93.8%, respectively. Landfilling is increasing rapidly in the world and this consequently brings the need of leachate treatment facilities. Therefore, this study is considered to be a guide for construction and operation stages of proposed new treatment plants.
American Journal of Applied Sciences, 2009
Problem Statement: Sanitary landfilling is the most common way to eliminate solid urban wastes. An important problem associated to landfills is the production of leachates. This study is a review of landfill leachate treatments. Approach: The advantages and disadvantages of the various existing leachate treatments discussed under the items: (i) Leachate channeling (combined treatment with domestic sewage, recycling) (ii) Biological processing (aerobic and anaerobic) (iii) Chemical/physical treatment (flotation, coagulation/flocculation, chemical precipitation, adsorption, ammonium stripping, chemical oxidation, ion exchange and electrochemical treatment) (iv) Membrane filtration (microfiltration, ultrafiltration, nanofiltration and reverse osmosis). Conclusion: The major fraction of old or biologically treated leachate was large recalcitrant organic molecules that are not easy removed during biological treatment. So that, in order to meet strict quality standards for direct discharge of leachate into the surface water, a development of integrated methods of treatment, a combination of biological, chemical, physical and membrane process steps, were required. Today, the use of membrane technologies, more especially Reverse Osmosis (RO), either as a main step in a landfill leachate treatment chain or as single post-treatment step had shown to be an indispensable means of achieving purification.
Research Square (Research Square), 2023
The moisture content of municipal solid waste (MSW) and local precipitation events lead to the leachate generation from MSW land lls. The high concentration of organic pollutants in land ll leachate makes it hazardous, requiring treatment before disposal into the environment. Land ll Leachate is most commonly treated by reverse osmosis (RO), which generates large volumes of wastewater termed as RO reject. This investigation aims to stabilize the RO reject through an inexpensive and effective bioremediation strategy. A bench-scale aerobic suspended growth reactor study was conducted using three commercial conversion agents, namely EM.1, Bokashi powder, and coir pith powder. Overall benchscale e cacy of 63% was achieved in this study. The onsite studies were conducted in 7.5 kL arti cial ponds with 46% e cacy amid atmospheric in uences and constraints. In contrast, the control pond with no conversion agents showed an increase in pollution concentration over the 100 days of retention time. The ndings revealed that the investigated technology had a marginally lower evaporation rate and performed relatively well compared to traditional solar evaporation ponds. Moreover, the technology can be easily scaled-up and readily applied for RO reject treatment in MSW land lls.
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