The Early Islamic Glass from Sir Bani Yas, UAE

The medieval port city of Sīrāf (ca. 800–1050 CE) on the north coast of the Persian/Arabian Gulf linked the core lands of the ‘Abbāsid caliphate with India, China, Africa, and beyond. 101 glass fragments recovered from the 1966–1973 excavations at Sīrāf and now at the Corning Museum of Glass were analysed using LA-ICPMS in order to explore the glassmaking raw materials and technology of the objects found within the city, as well as to address issues of the production and trade of glass during the Islamic period. The results indicate that the main groups of glass at Sīrāf likely date to the 9th–early 11th centuries and can be subdivided by the trace elements zirconium and chromium. Chemical matches with some likely Indian glass, and with glass finds from South and Southeast Asia, underline the pivotal role of the Gulf in the eastward movement of Islamic glass via the Indian Ocean trade network, as well as the influx of Indian glass into the Islamic world. Glass bangles and a small number of vessel fragments likely date to the late 11th century or later, and their chemical compositions indicate different production origins.

Journal of Archaeological Science: Reports, 2017

The medieval port city of Sīrāf (ca. 800–1050 CE) on the north coast of the Persian/Arabian Gulf linked the core lands of the ‘Abbāsid caliphate with India, China, Africa, and beyond. 101 glass fragments recovered from the 1966–1973 excavations at Sīrāf and now at the Corning Museum of Glass were analysed using LA-ICPMS in order to explore the glassmaking raw materials and technology of the objects found within the city, as well as to address issues of the production and trade of glass during the Islamic period. The results indicate that the main groups of glass at Sīrāf likely date to the 9th–early 11th centuries and can be subdivided by the trace elements zirconium and chromium. Chemical matches with some likely Indian glass, and with glass finds from South and Southeast Asia, underline the pivotal role of the Gulf in the eastward movement of Islamic glass via the Indian Ocean trade network, as well as the influx of Indian glass into the Islamic world. Glass bangles and a small number of vessel fragments likely date to the late 11th century or later, and their chemical compositions indicate different production origins.

Journal of Archaeological Science: Reports, 2017

The medieval port city of Sīrāf (ca. 800-1050 CE) on the north coast of the Persian/Arabian Gulf linked the core lands of the 'Abbāsid caliphate with India, China, Africa, and beyond. 101 glass fragments recovered from the 1966-1973 excavations at Sīrāf and now at the Corning Museum of Glass were analysed using LA-ICPMS in order to explore the glassmaking raw materials and technology of the objects found within the city, as well as to address issues of the production and trade of glass during the Islamic period. The results indicate that the main groups of glass at Sīrāf likely date to the 9 th-early 11 th centuries and can be subdivided by the trace elements zirconium and chromium. Chemical matches with some likely Indian glass, and with glass finds from South and Southeast Asia, underline the pivotal role of the Gulf in the eastward movement of Islamic glass via the Indian Ocean trade network, as well as the influx of Indian glass into the Islamic world. Glass bangles and a small number of vessel fragments likely date to the late 11 th century or later, and their chemical compositions indicate different production origins. Keywords Sīrāf, Siraf; Iran; Gulf; Islamic glass; bangles; Indian Ocean trade; LA-ICPMS; zirconium; chromium; manganese; high alumina Highlights  90% are plant-ash glasses from 9 th-early 11 th centuries, with subgroups based on zirconium and chromium

Accounts of Chemical Research, 2002

The chemical analysis of excavated glass fragments from dated archaeological contexts in Raqqa, Syria, has provided a detailed picture of the chemical compositions of artefacts deriving from eighth to ninth and 11th century glassmaking and glassworking activities. Evidence for primary glass production has been found at three excavated sites, of eighth to ninth, 11th and 12th century dates; the first two are discussed here. The 2 km long industrial complex at al-Raqqa was associated with an urban landscape consisting of two Islamic cities (al-Raqqa and al-Rafika) and a series of palace complexes. The glass fused and worked there was presumably for local as well as for regional consumption.

Archaeological and Anthropological Sciences, 2014

Glass ornaments such as bangles are widely distributed along trade routes between the East and West, indicating interactions and exchange between manufacturing and consumption sites. In the Persian Gulf region, numerous glass bangles have been excavated from late 2nd millennium CE contexts, but few of these have been studied with scientific analysis. Here, we report data on 56 representative samples from assemblages found at seven coastal sites of northern Qatar that date between the eighteenth and twentieth centuries CE, analysed by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). We identify six different glass compositions and discuss their raw materials and likely provenances, including one group from the Levant, one group from Mesopotamia and another two groups using different plant types as fluxes, with their sand source similar to Sasanian glasses from Central Iraq between the third and seventh centuries CE, and two high-alumina outliers associated with two Indian origins. The paper also compares the Qatar bangles with others from the Islamic world and India to discuss differences and similarities between them.

PLoSONE13(8):e0201749, 2018

Capital of the Abbasid Caliphate between 836 and 892 CE, the palace-city of Samarra offers a precise window into early Islamic art and architecture. Excavations conducted more than 100 years ago are seen as the beginnings of scientific Islamic archaeology, and have yielded an exceptional array of finds including a wealth of glass artefacts. The chemical composition of glass reflects the nature of the raw materials and their geological provenance and can therefore reveal past technologies and economic and cultural interactions. Through high-resolution analysis of a comprehensive glass assemblage from Samarra we have new evidence that points to the existence of an advanced Abbasid glass industry, as well as the import of specific glass objects for the thriving new capital city. Quantitative analytical data of 58 elements by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) show a striking correlation between object types and glass compositions. The compositional profiles of two related plant ash groups of architectural glass point to a local production, destined for the decoration of the famed glass walls of Abbasid palaces. The selective use of objects, materials and colours to create reflective and luminous glass walls are indicative of the great cultural and economic value of glass during the Abbasid period. Our findings thus confirm the veracity of written sources that stipulate the production of glass in the vicinity of Samarra, as well as the import of selected artefacts such as Byzantine mosaic tesserae.

Archaeometry, 2004

The chemical analysis of excavated glass fragments from dated archaeological contexts in Raqqa, Syria, has provided a detailed picture of the chemical compositions of artefacts deriving from eighth to ninth and 11th century glassmaking and glassworking activities. Evidence for primary glass production has been found at three excavated sites, of eighth to ninth, 11th and 12th century dates; the first two are discussed here. The 2 km long industrial complex at al-Raqqa was associated with an urban landscape consisting of two Islamic cities (al-Raqqa and al-Rafika) and a series of palace complexes. The glass fused and worked there was presumably for local as well as for regional consumption.

Levant, 1999

Archaeological excavations of an Islamic industrial complex in northern Syria at al-Raqqa have revealed comprehensive evidence for Abbasid high temperature industries. Amongst the evidence is some for glass production. The evidence included a glass workshop consisting of the remains of three-chambered 'bee-hive' furnaces and a centralised flue system, the debris of casting glass into blocks of three different sizes, glass moils of two diameters (the knock-offs from blowing irons) and discarded lumps of frit, a material produced by the initial stage in glass production. In addition, fragments of a second kind of glass furnace, a tank furnace, were found. Scientific analysis of the products and by-products of this glass industry using electron probe microanalysis has produced an unexpectedly wide range of glass chemical compositions. In some instances discrete compositions are correlated to the function of the glass such as its use to make cast blocks and window panes. In others instances, such as when it is used to make glass vessels, the same apparent degree of specialisation in the deliberate selection of particular glass raw materials is not evident. Scientific analysis of frit has shown that the glass used to make the windows for glazing the al-Raqqa palace complexes was made in al-Raqqa.

Research Square (Research Square), 2023

Glass ornaments such as bangles are widely distributed along trade routes between the East and West, indicating interactions and exchange between manufacturing and consumption sites. In the Persian Gulf region, numerous glass bangles have been excavated from late 2nd millennium CE contexts, but rather few of these have been studied with scienti c analysis. Here, we report data of 56 representative samples from assemblages found at seven coastal sites of northern Qatar that date between the 18th and 20th centuries CE, analysed by laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS). Based on the chemical compositions combined with their respective colours, the assemblage represents six different glass provenances, including one subgroup from the Levant, one subgroup from Mesopotamia, and another two subgroups using different plant types as uxes, with their sand source similar to Sasanian glasses from Central Iraq between the 3rd and 7th centuries CE, and two high-alumina subgroups associated with an Indian origin. The paper also compares the Qatar bangles with others from the Islamic world and India to discuss differences and similarities of them.

Glass manufacturing processes and recipes changed fundamentally after the 8th century CE. The earlier centralised production system diversified, primary production sites multiplied, and the scale of individual productions contracted. Mineral soda was no longer used and instead replaced by plant ash as the main fluxing agent, affecting the chemical composition and properties of the glass. In this work, LA-ICP-MS and Raman spectroscopy were used to investigate the compositional and structural characteristics of 68 glass fragments recovered during recent excavations at Bukhara in Uzbekistan, dating to the 9th to early 11th centuries CE. This is the most extensive systematically collected and studied glass assemblage from Central Asia to date. The glass can be attributed to different origins, confirming on the one hand the diversification of glass production during the early Islamic period and, on the other hand, regional variations in the chemical compositions and network structure of soda-rich plant ash glasses. As clear archaeological evidence for early Islamic glass production sites in Central Asia is rare, regional production groups are distinguished primarily on relative concentrations of Mg, K, P, Cl, Li and Cs in relation to the plant ash component, while variabilities in Al, Ti, Cr, Y, Zr, Th and REEs and their ratios indicate different silica sources. Raman spectra suggest variations in network connectivity and Q n speciation that confirm compositional groupings and suggest structural differences between regional productions of plant ash glass. The results demonstrate a clear dominance of local or regional glass groups, while revealing the importation of Mesopotamian glass, notably a high-end colourless glass type from the region around Samarra in Iraq. The new analytical data allow further separation and characterisation of novel early Islamic plant-ash glass types and their production areas.