Processes that Promote and Deplete the Exosphere of Mercury

It can be assumed that the composition of Mercury's thin gas envelope (exosphere) is related to the composition of the planets crustal materials. If this relationship is true, then inferences regarding the bulk chemistry of the planet might be made from a thorough exospheric study. The most vexing of all unsolved problems is the uncertainty in the source of each component. Historically, it has been believed that H and He come primarily from the solar wind, while Na and K originate from volatilized materials partitioned between Mercury's crust and meteoritic impactors. The processes that eject atoms and molecules into the exosphere of Mercury are generally considered to be thermal vaporization, photonstimulated desorption (PSD), impact vaporization, and ion sputtering. Each of these processes has its own temporal and spatial dependence. The exosphere is strongly influenced by Mercury's highly elliptical orbit and rapid orbital speed. As a consequence the surface undergoes large fluctuations in temperature and experiences differences of insolation with longitude. We will discuss these processes but focus more on the expected surface composition and solar wind particle sputtering which releases material like Ca and other elements from the surface minerals and discuss the relevance of composition modelling.

Icarus, 2008

Chemical processes associated with meteoroid bombardment of Mercury are considered. Meteoroid impacts lead to production of metal atoms as well as metal oxides and hydroxides in the planetary exosphere. By using quenching theory, the abundances of the main Na-, K-, CaFe Fe-, Al-, Mg-, Si-, and Ti-containing species delivered to the exosphere during meteoroid impacts were estimated. Based on a correlation between the solar photo rates and the molecular constants of atmospheric diatomic molecules, photolysis lifetimes of metal oxides and SiO are estimated. Meteoroid impacts lead to the formation of hot metal atoms (0.2-0.4 eV) produced directly during impacts and of very hot metal atoms (1-2 eV) produced by the subsequent photolysis of oxides and hydroxides in the exosphere of Mercury. The concentrations of impact-produced atoms of the main elements in the exosphere are estimated relative to the observed concentrations of Ca, assumed to be produced mostly by ion sputtering. Condensation of dust grains can significantly reduce the concentrations of impact-produced atoms in the exosphere. Na, K, and Fe atoms are delivered to the exosphere directly by impacts while Ca, Al, Mg, Si, and Ti atoms are produced by the photolysis of their oxides and hydroxides. The chemistry of volatile elements such as H, S, C, and N during meteoroid bombardment is also considered. Our conclusions about the temperature and the concentrations of impact-produced atoms in the exosphere of Mercury may be checked by the Messenger spacecraft in the near future and by BepiColombo spacecraft some years later.

Icarus, 2003

Mercury's close orbit around the Sun, its weak intrinsic magnetic field and the absence of an atmosphere (P surface < 1 × 10 −8 Pa) results in a strong direct exposure of the surface to energetic ions, electrons and UV radiation. Thermal processes and particle-surfacecollisions dominate the surface interaction processes leading to surface chemistry and physics, including the formation of an exosphere (N 10 14 cm −2 ) in which gravity is the dominant force affecting the trajectories of exospheric atoms. NASA's Mariner 10 spacecraft observed the existence of H, He, and O in Mercury's exosphere. In addition, the volatile components Na, K, and Ca have been observed by ground based instrumentation in the exosphere. We study the efficiency of several particle surface release processes by calculating stopping cross-sections, sputter yields and exospheric source rates. Our study indicates surface sputter yields for Na between values of about 0.27 and 0.35 in an energy range from 500 eV up to 2 keV if Na + ions are the sputter agents, and about 0.037 and 0.082 at an energy range between 500 eV up to 2 keV when H + are the sputter agents and a surface binding energy of about 2 eV to 2.65 eV. The sputter yields for Ca are about 0.032 to 0.06 and for K atoms between 0.054 to 0.1 in the same energy range. We found a sputter yield for O atoms between 0.025 and 0.04 for a particle energy range between 500 eV up to 2 keV protons. By taking the average solar wind proton surface flux at the open magnetic field line area of about 4 × 10 8 cm −2 s −1 calculated by Massetti et al. (2003, Icarus, in press) the resulting average sputtering flux for O is about 0.8-1.0 × 10 7 cm −2 s −1 and for Na approximately 1.3-1.6 × 10 5 cm −2 s −1 depending on the assumed Na binding energies, regolith content, sputtering agents and solar activity. By using lunar regolith values for K we obtain a sputtering flux of about 1.0-1.4 × 10 4 cm −2 s −1 . By taking an average open magnetic field line area of about 2.8 × 10 16 cm 2 modelled by Massetti et al. (2003, Icarus, in press) we derive an average surface sputter rate for Na of about 4.2 × 10 21 s −1 and for O of about 2.5 × 10 23 s −1 . The particle sputter rate for K atoms is about 3.0 × 10 20 s −1 assuming lunar regolith composition for K. The sputter rates depend on the particle content in the regolith and the open magnetic field line area on Mercury's surface. Further, the surface layer could be depleted in alkali. A UV model has been developed to yield the surface UV irradiance at any time and latitude over a Mercury year. Seasonal and diurnal variations are calculated, and Photon Stimulated Desorption (PSD) fluxes along Mercury's orbit are evaluated. A solar UV hotspot is created towards perihelion, with significant average PSD particle release rates and Na fluxes of about 3.0 × 10 6 cm −2 s −1 . The average source rates for Na particles released by PSD are about 1 × 10 24 s −1 . By using the laboratory obtained data of Madey et al. (1998, J. Geophys. Res. 103, 5873-5887) for the calculation of the PSD flux of K atoms we get fluxes in the order of about 10 4 cm −2 s −1 along Mercury's orbit. However, these values may be to high since they are based on idealized smooth surface conditions in the laboratory and do not include the roughness and porosity of Mercury's regolith. Further, the lack of an ionosphere and Mercury's small, temporally and spatially highly variable magnetosphere can result in a large and rapid increase of exospheric particles, especially Na in Mercury's exosphere. Our study suggests that the average total source rates for the exosphere from solar particle and radiation induced surface processes during quiet solar conditions may be of the same order as particles produced by micrometeoroid vaporization. We also discuss the capability of in situ measurements of Mercury's highly variable particle environment by the proposed NPA-SERENA instrument package on board ESA's BepiColombo Mercury Planetary Orbiter (MPO).

Space Science Reviews, 2007

The existence of a surface-bounded exosphere about Mercury was discovered through the Mariner 10 airglow and occultation experiments. Most of what is currently known or understood about this very tenuous atmosphere, however, comes from groundbased telescopic observations. It is likely that only a subset of the exospheric constituents have been identified, but their variable abundance with location, time, and space weather events demonstrate that Mercury's exosphere is part of a complex system involving the planet's surface, magnetosphere, and the surrounding space environment (the solar wind and interplanetary magnetic field). This paper reviews the current hypotheses and supporting observations concerning the processes that form and support the exosphere. The outstanding questions and issues regarding Mercury's exosphere stem from our current lack of knowledge concerning the surface composition, the magnetic field behavior within the local space environment, and the character of the local space environment.

It can be assumed that the composition of Mercury’s thin gas envelope (exosphere) is related to thecomposition of the planets crustal materials. If this relationship is true, then inferences regarding the bulkchemistry of the planet might be made from a thorough exospheric study. The most vexing of allunsolved problems is the uncertainty in the source of each component. Historically, it has been believedthat H and He come primarily from the solar wind, while Na and K originate from volatilized materialspartitioned between Mercury’s crust and meteoritic impactors. The processes that eject atoms andmolecules into the exosphere of Mercury are generally considered to be thermal vaporization, photonstimulateddesorption (PSD), impact vaporization, and ion sputtering. Each of these processes has its owntemporal and spatial dependence. The exosphere is strongly influenced by Mercury’s highly ellipticalorbit and rapid orbital speed. As a consequence the surface undergoes large fluctuations i...

Icarus, 1987

The discovery of an atomic sodium exosphere at Mercury raises the question of whether Mercury, like I0 at Jupiter, can maintain a heavy ion magnetosphere. We suggest that it does, and that heavy ions (mainly Na ÷) from the exosphere are typically accelerated to keV energies and make important or dominant contributions to the mass (~300 g sec -1) and energy (-3 x 109 W) budget s of the magnetosphere. The sodium supply to the exosphere is largely from within Mercury itself, with external sources like meteoroid infall and the solar wind being relatively unimportant. Therefore Mercury is in the process of losing its semivolatiles. Photosputtering dominates charged particle sputtering and can maintain an adequate rate of Na ejection from the surface.

Space Science Reviews, 2007

The instrument suite on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft is well suited to address several of Mercury's outstanding geochemical problems. A combination of data from the Gamma-Ray and Neutron Spectrometer (GRNS) and X-Ray Spectrometer (XRS) instruments will yield the surface abundances of both volatile (K) and refractory (Al, Ca, and Th) elements, which will test the three competing hypotheses for the origin of Mercury's high bulk metal fraction: aerodynamic drag in the early solar nebula, preferential vaporization of silicates, or giant impact. These same elements, with the addition of Mg, Si, and Fe, will put significant constraints on geochemical processes that have formed the crust and produced any later volcanism. The Neutron Spectrometer sensor on the GRNS instrument will yield estimates of the amount of H in surface materials and may ascertain if the permanently shadowed polar craters have a significant excess of H due to water ice. A comparison of the FeO content of olivine and pyroxene determined by the Mercury Atmospheric and Surface Composition

Icarus, 2014

Mercury, due to its close location to the Sun, is surrounded by an environment whose conditions may be considered as 'extreme' in the entire Solar System. Both solar wind and radiation are stronger with respect to other Solar System bodies, so that their interactions with the planet cause high emission of material from its surface. Moreover, the meteoritic precipitation plays a significant role in surface emission processes. This emitted material is partially lost in space. Although under the present conditions the surface particles loss rate does not seem to be able to produce significant erosion of the planetary mass and volume, the long-term effects over billions of years should be carefully considered to properly understand the evolution of the planet. In the early stages, under even more extreme conditions, some of these processes were much more effective in removing material from the planet's surface. This study attempts to provide a rough estimation of the material loss rate as a function of time, in order to evaluate whether and how this environmental effect can be applied to understand the Hermean surface evolution. We show that the most potentially effective Sun-induced erosion process in early times is a combination of ion sputtering, photon stimulated desorption and enhanced diffusion, which could have caused the loss of a surface layer down to a depth of 20 m, as well as a relevant Na depletion.

Planetary and Space Science, 2007

Mariner 10, the only spacecraft that ever passed close to Mercury, revealed several unexpected characteristics: an intrinsic magnetosphere, the highest mean density of any Solar System terrestrial planet and a very thin non-collisional atmosphere. Mercury's atmosphere is very poorly explored since only three atomic elements, H, He and O, were observed during the three flybys of Mariner 10. The measurements done by radio and solar occultations provided upper limits on the neutral and ion densities. These measurements pointed out the close connection between species in Mercury's exosphere and its surface, which is also the case for the Moon. Mariner 10 observations also characterized the vertical distributions and the day to night contrasts of Mercury's exosphere for its lightest components H and He (

Icarus, 2006

Following the observations of August 2002 [Barbieri, C., Verani, S., Cremonese, G., Sprague, A., Mendillo, M., Cosentino, R., Hunten, D., 2004. Planet. Space Sci. 52, 1169–1175], the high resolution spectrograph of the 3.5-m Galileo National Telescope ...