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Summary of C&C derivation and support
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Abbreviations: ∆ψ, transmembrane electric potential difference; AAPH, 2,2′ azobis(2 amidinopropane) dihydrochloride; BLM, bilayer planar phospholipid membrane; BSA, bovine serum albumin; CCCP, carbonyl cyanide m chlorophenylhydrazone; CM DCF DA, 5 ( 6) chloromethyl 2′,7′ dichlorodihydrofluorescein diacetate; C 12 TPP, dodecyltriphenylphosphonium; DMQ, demethoxy derivative of CoQ 0 lacking one of the methoxy groups; DPQ, decylplastoquinone; FCCP, carbonyl cyanide p trifluo romethoxyphenylhydrazone; MDA, malondialdehyde; MitoQ, 10 (6′ ubiquinonyl) decyltriphenylphosphonium; NAC, N acetyl cysteine; PQ, plastoquinone; ROS, reactive oxygen species; SF6846, 3,5 di(tert)butyl 4 hydroxybenzylidene malononitrile; SkQ, cationic derivative of plastoquinone or methyl plastoquinone; SkQ1, 10 (6′ plastoquinonyl) decyltriphenylphosphonium; SkQ2, 10 (6′ plastoquinonyl) decylcarnitine; SkQ2M, 10 (6′ plastoquinonyl) decylmethylcarnitine; SkQ3, 10 (6′ methylplasto quinonyl) decyltriphenylphosphonium; SkQ4, 10 (6′ plastoquinonyl) decyltributylammonium; SkQ5, 5 (6′ plastoquinonyl) amyltriphenylphosphonium; SkQR1, 10 (6′ plastoquinonyl) decylrhodamine 19; TMRE, tetramethylrhodamine ethyl ester; TPB, tetraphenylborate; TPP, tetraphenylphosphonium. * This and the following four articles were written by the request of the Editorial Board of Biochemistry (Moscow).
This standard is issued under the fixed designation C 186; the number immediately following the designation indicates the year of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1st ICELL - Proceedings Book
PU Public X PP Restricted to other programme participants (including the Commission Services) RE Restricted to a group specified by the consortium (including the Commission Services) CO Confidential, only for members of the consortium (including the Commission Services)
The molar enthalpies of mixing A mix // m in the liquid NaCl-NdCl 3 , KCl-NdCl 3 , RbCl-NdClj and CsCl-NdCl, binary systems have been measured over the whole composition range at 1124, 1065, 1122 and 1122 K, respectively, with an accuracy of about 6%. The apparatus used was a Calvet-type high-temperature microcalorimeter and mixing of the two liquid components was obtained by the break-off ampoule technique. In the investigated systems, the enthalpies of mixing are negative with minimum values at about -5.7, -16.6, -20.2 and -23.4 kJ mol" 1 , respectively, at X UdC3s = 0.4. These values are almost identical, within the experimental accuracy, to those in other previously investigated MCl-LnCf, mixtures. The molar enthalpies of formation A f // nl {K 3 NdCl 6 ,1, 1065)/kJ mol" 1 , Af/^fRb.NdCl,,!, I122)/kJmoT' and A r // ra (Cs 3 NdCl h , I, 1122)/kJ mol \ according to the reaction 3 MCT(l) + LnCl,(l) = M 3 LnCl ( ,(l), are equal to -55.2, -68.8 and -80.8 kJ mol" 1 , respectively. The least-squares coefficients A, B, C, D, E of the equation for the interaction parameter k = A + Bx + Cx 2 + Dx 3 + Ex* (in kJ mol ') are presented.
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