Academia.eduAcademia.edu

THE MANUFACTURE OF STEEL

Abstract

Steel refers to any iron-carbon alloy, although steels usually contain other elements as well. In New Zealand steel is made by BHP NZ at Glenbrook, where about 90% of New Zealand's annual steel requirements are produced. Iron occurs mainly as oxide ores, though it is also found in smaller quantities as its sulfide and carbonate. These other ores are usually first roasted to convert them into the oxide. On a world scale the most important ore is haematite (Fe 2 O 3), but in New Zealand the starting materials are magnetite (Fe 3 O 4) and titanomagnetite (Fe 2 TiO 4). The oxides are reduced with carbon from coal, through the intermediate production of carbon monoxide. The carbon initially burns in air to give carbon dioxide and the heat, which is necessary for the process. The carbon dioxide then undergoes an endothermic reaction with more carbon to yield carbon monoxide: C + O 2 → CO 2 ∆H =-393 kJ mol-1 C + CO 2 → 2CO ∆H = +171 kJ mol-1 The oxide ores are then principally reduced by the carbon monoxide produced in this reaction, the reactions involving very small enthalpy changes: Fe 2 O 3 + 3CO → 2Fe + 3CO 2 ∆H =-22 kJ mol-1 Fe 3 O 4 + 4CO → 3Fe + 4CO 2 ∆H =-10 kJ mol-1 In conventional ironmaking this reduction occurs in a blast furnace, whereas in New Zealand a rotary kiln is employed for direct reduction, followed by indirect reduction in an electric melter. This technology is used because the titanium dioxide present in the ore produces a slag which blocks conventional blast furnaces as it has a high melting point. The iron produced in this way always contains high levels of impurities making it very brittle. Steel making is mainly concerned with the removal of these impurities. This is done by oxidising the elements concerned by blowing pure oxygen through a lance inserted into the molten alloy. The KOBM (Klockner Oxygen Blown Maxhutte) used for this in New Zealand is unusual because oxygen is also blown through holes in the base of the converter. The oxides produced are either evolved as gases, or combine with limestone to form an immiscible slag which floats on the surface of the liquid metal and so is easily separated.