Chemical modeling of exoplanet atmospheres

Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 2020

The detection of habitable exoplanets is an exciting scientific and technical challenge. Owing to the current and most likely long-lasting impossibility of performing in situ exploration of exoplanets, their study and hypotheses regarding their capability to host life will be based on the restricted low-resolution spatial and spectral information of their atmospheres. On the other hand, with the advent of the upcoming exoplanet survey missions and technological improvements, there is a need for preliminary discrimination that can prioritize potential candidates within the fast-growing list of exoplanets. Here we estimate, for the first time and using the kinetic theory of gases, a list of the possible atmospheric species that can be retained in the atmospheres of the known exoplanets. We conclude that, based on our current knowledge of the detected exoplanets, 45 of them are good candidates for habitability studies. These exoplanets could have Earth-like atmospheres and should be ab...

2022

A major goal in the discovery and characterisation of exoplanets is to identify terrestrial-type worlds that are similar to (or otherwise distinct from) our Earth. Recent results have highlighted the importance of applying devolatilisation -- i.e. depletion of volatiles -- to the chemical composition of planet-hosting stars to constrain bulk composition and interiors of terrestrial-type exoplanets. In this work, we apply such an approach to a selected sample of 13 planet-hosting Sun-like stars, for which high-precision photospheric abundances have been determined in the first paper of the series. With the resultant devolatilised stellar composition (i.e. the model planetary bulk composition) as well as other constraints including mass and radius, we model the detailed mineralogy and interior structure of hypothetical, habitable-zone terrestrial planets ("exo-Earths") around these stars. Model output shows that most of these exo-Earths are expected to have broadly Earth-lik...

2021

Thermochemical equilibrium is one of the most commonly used assumptions in current exoplanet retrievals. As the James Webb Space Telescope (JWST) and Ariel launch draw near, assessing the underlying biases and assumptions made when applying self-consistent chemistry into spectral retrievals is crucial. Here we use the flexibility of TauREx 3.1 to cross-compare three state of the art chemical equilibrium codes: ACE, FastChem and GGchem. We simulate JWST spectra for ACE, FastChem, GGchem and GGchem+condensation containing only C, H, O, N elements and spectra for FastChem, GGchem and GGchem+condensation with a more extensive range of elements giving seven simulated JWST spectra in total and then cross-retrieve giving a total of 49 retrievals. Our analysis demonstrates that like-for-like, all chemical codes retrieve the correct parameters to < 1% of the truth. However, retrievals, where the contained elements do not match the truth, parameters such as metallicity deviate by 20% while...

Proceedings of The International Astronomical Union, 2006

Over 150 extrasolar planets are known to orbit sun-like stars. A growing number of them (9 to date) are transiting "hot Jupiters" whose physical characteristics can be measured. Atmospheres of two of these planets have already been detected. We summarize the atmosphere detections and useful upper limits, focusing on the MOST albedo upper limit and H exosphere detection for HD209458b as the most revelant for photochemical models. We describe our photochemical model for hot Jupiters and present a summary explanation of the main results: a low gas-phase abundance of hydrocarbons; an absence of hydrocarbon hazes; and a large reservoir of H atoms in the upper atmospheres of hot Jupiters. We conclude by relating these model results to the relevant observational data.

Journal of Molecular Spectroscopy, 2016

The ExoMol database (www.exomol.com) provides extensive line lists of molecular transitions which are valid over extended temperatures ranges. The status of the current release of the database is reviewed and a new data structure is specified. This structure augments the provision of energy levels (and hence transition frequencies) and Einstein A coefficients with other key properties, including lifetimes of individual states, temperature-dependent cooling functions, Landé g-factors, partition functions, cross sections, k-coefficients and transition dipoles with phase relations. Particular attention is paid to the treatment of pressure broadening parameters. The new data structure includes a definition file which provides the necessary information for utilities accessing ExoMol through its application programming interface (API). Prospects for the inclusion of new species into the database are discussed.

Experimental Astronomy

Thousands of exoplanets have now been discovered with a huge range of masses, sizes and orbits: from rocky Earth-like planets to large gas giants grazing the surface of their host star. However, the essential nature of these exoplanets remains largely mysterious: there is no known, discernible pattern linking the presence, size, or orbital parameters of a planet to the nature of its parent star. We have little idea whether the chemistry of a planet is linked to its formation environment, or whether the type of host star drives the physics and chemistry of the planet's birth, and evolution. ARIEL was conceived to observe a large number (~1000) of transiting planets for statistical understanding, including gas giants, Neptunes, super-Earths and Earth-size planets around a range of host star types using transit spectroscopy in the 1.25-7.8 μm spectral range and multiple narrow-band photometry in the optical. ARIEL will focus on warm and hot planets to take advantage of their well-mixed atmospheres which should show minimal condensation and sequestration of high-Z materials compared to their colder Solar System siblings. Said warm and hot atmospheres are expected to be more representative of the planetary bulk composition. Observations of these warm/hot exoplanets, and in particular of their elemental composition (especially C, O, N, S, Si), will allow the understanding of the early stages of planetary and atmospheric formation during the nebular phase and the following few million years. ARIEL will thus provide a representative picture of the chemical nature of the exoplanets and relate this directly to the type and chemical environment of the host star. ARIEL is designed as a dedicated survey mission for combined-light spectroscopy, capable of observing a large and welldefined planet sample within its 4-year mission lifetime. Transit, eclipse and phasecurve spectroscopy methods, whereby the signal from the star and planet are differentiated using knowledge of the planetary ephemerides, allow us to measure atmospheric signals from the planet at levels of 10-100 part per million (ppm) relative to the star and, given the bright nature of targets, also allows more sophisticated techniques, such as eclipse mapping, to give a deeper insight into the nature of the atmosphere. These types of observations require a stable payload and satellite platform with broad, instantaneous wavelength coverage to detect many molecular species, probe the thermal structure, identify clouds and monitor the stellar activity. The wavelength range proposed covers all the expected major atmospheric gases from e.g. H 2 O, CO 2 , CH 4 NH 3 , HCN, H 2 S through to the more exotic metallic compounds, such as TiO, VO, and condensed species. Simulations of ARIEL performance in conducting exoplanet surveys have been performedusing conservative estimates of mission performance and a

2009

Since planets were first discovered outside our own Solar System in 1992 (around a pulsar) and in 1995 (around a main sequence star), extrasolar planet studies have become one of the most dynamic research fields in astronomy. Now that more than 370 exoplanets have been discovered, focus has moved from finding planets to characterise these alien worlds. As well as detecting the atmospheres of these exoplanets, part of the characterisation process undoubtedly involves the search for extrasolar moons. A review on the current situation of exoplanet characterization is presented in Chapter 3. We focus on the characterization of transiting planets orbiting very close to their parent star since for them we can already probe their atmospheric constituents. By contrast, the second part of the Chapter is dedicated to the search for extraterrestrial life, both within and beyond the Solar System. The characteristics of the Habitable Zone and the markers for the presence of life (biosignatures) ...