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2006
Journal of the Institute of Brewing, 2015
The key to optimising alcohol production from cereals is a full understanding the physiology and processing characteristics of different cereals. This study examined the maximum alcohol yields that can be obtained from wheat and maize using different processing technologies. Lower processing temperatures (85 o C) resulted in high alcohol yields from wheat (a temperate crop), whereas higher processing temperatures (142 o C) gave maximum alcohol yields from maize (a tropical crop). Similar trends were also observed when the spent grains from these cereals were subjected to cellulolysis using commercial enzymes. Mill settings were additional factors in influencing alcohol production. Wheat has the potential to produce higher alcohol yields when compared with maize, when residual biomass (i.e. spent grains) saccharification using selected commercial enzymes is taken into account. While this is approach is not applicable for the Scotch whisky industry due to strict legislation forbidding use of exogenous enzymes, this is pertinent for bioethanol production to increase the alcohol yield obtained from both starch and lignocellulosic components of whole cereal grains. Wheat and maize processing temperatures and the use of processing aids are of potential economic benefit to bioethanol producers and to beverage alcohol producers seeking to understand the factors influencing the processing properties of different cereals.
Journal of the Institute of Brewing, 2006
Journal of the Institute of Brewing, 2009
The work reported in this paper showed that whilst grain nitrogen is a key player in determining the alcohol yield obtained from soft winter wheat, other parameters such as grain hardness may also be important. A strong positive correlation was found between grain hardness and grain nitrogen and both parameters affected alcohol yield of processed wheat in a similar way. Although an inverse relationship between alcohol yield and grain nitrogen was observed at each of four growing sites, this relationship was stronger for wheat grown at moderate nitrogen sites than at higher or lower nitrogen sites. A similar inverse relationship, comparable to that obtained for nitrogen, was also found between alcohol yield and grain hardness. Further statistical analysis showed that an improved prediction of alcohol yield can be obtained based on measures of both hardness and total nitrogen, as opposed to total nitrogen alone. Residue viscosity did not appear to directly influence alcohol yield. However, some correlation was observed between both grain nitrogen and hardness and residue viscosity at certain sites. While correlation between nitrogen and residue viscosity was observed at the site with the highest nitrogen content, correlation between hardness and residue viscosity was observed at the two sites where nitrogen content was highest. Finally, scanning electron microscopy revealed that very high protein content was found to result in deformation of the starch structure, limiting access of starch during processing and lowering alcohol yield.
The purpose of this paper is to quantify the economic impact of variation in alcohol yield from wheat grain used as the feedstock in the emerging UK bioethanol industry. Analysis of alcohol yield of 84 Recommended List samples shows that the annual cost saving from high alcohol yield wheat compared with low alcohol yield wheat could exceed ?3 million per annum or ?34 per tonne of wheat processed in a plant with a capacity of 100k tonnes of wheat per year.
Foods
To standardise research activity and determine alcohol yield from native Irish hard wheat grain, a benchmark approach that reflects Irish industry norms is required. The goal of this study was to optimise milling parameters, grain particle size, and grain to liquid ratio towards developing a standard process. Hard wheat (Triticum avestivum cv. Costello) was used in this study. Experiments utilised a response surface method approach. When both 30 and 35 g of flour were used at a particle size of 0.2 mm, alcohol yield was >350 L of alcohol per tonne of grain (LA/tonne), but with a particle size of 0.65 and 1.1 mm, alcohol yield decreased to between 250 and 300 LA/tonne. It was noted that, during response surface study, >300 LA/tonne was achieved when grain amounts were >25 g, at a particle size of 0.2 mm; therefore, a follow-up experiment was conducted to determine whether there was a significant difference in grain amounts ranging from 25 to 35 g. During this experiment, no ...
InTech eBooks, 2011
Economic Effects of Biofuel Production 430 USA) and the most commonly available blended gasoline contains 10% (E10) corn ethanol . Brazil produced approximately 24.5 billion L in 2008 but mandates 20-25% (E20-E25) blend ratios . According to , the European Union (EU) has also set targets of 5.75% for blended gas, as has Argentina (at least 5%). China and India are also following this trend with nationa-wide fuel ethanol programs , as is Canada, which will need to produce 2 billion L of ethanol by 2010 to meet the 5% federal renewable fuel standard recently mandated [CRFA, 2009]. Ethanol has been mandated for incorporation into many countries transportation economies largely in the hopes of addressing rising concern over anthropogenic greenhouse gas emissions, of which 80% is claimed accountable to fossil fuel combustion . The role of ethanol as a blended gasoline product, in ratios of 5 -20% (v/v) ethanol, referred to as gasohol, can be used without major modifications to pre-existing automobile engines and burns cleaner, due to the higher octane rating, reducing harmful emissions . Most researchers agree that a net decrease in GHG emissions of 13 -18% is likely to be observed with the incorporation of ethanol as E10-20 into the fuel supply [Farrel, 2006;. Fuel security, volatility in oil pricing and the development of local, rural economies, have all been cited as additional impetus for many nation's inclusion of biofuels into the energy policy discourse. Billions of Litres USA 34.
Applied Biochemistry and Biotechnology, 2004
Over the past three decades ethanol production in the United States has increased more than 10-fold, to approx 2.9 billion gal/yr (mid-2003), with ethanol production expected to reach 5 billion gal/yr by 2005. The simulta neous coproduction of 7 million t/yr of distiller's grain (DG) may potentially drive down the price of DG as a cattle feed supplement. The sale of residual DG for animal feed is an important part of corn dry-grind ethanol production economics; therefore, dry-grind ethanol producers are seeking ways to improve the quality of DG to increase market penetration and help stabilize prices. One possible improvement is to increase the protein content of DG by converting the residual starch and fiber into ethanol. We have developed methods for steam explosion, SO 2 , and dilute-sulfuric acid pretreatment of DG for evaluation as a feedstock for ethanol production. The highest soluble sugar yields (~77% of available carbohydrate) were obtained by pretreat ment of DG at 140°C for 20 min with 3.27 wt% H 2 SO 4 . Fermentation protocols for pretreated DG were developed at the bench scale and scaled to a working volume of 809 L for production of hydrolyzed distiller's grain (HDG) for feeding trials. The pretreated DG was fermented with Saccharomyces cerevisiae D 5 A, with ethanol yields of 73% of theoretical from available glucans.
Cereal Chemistry Journal, 2009
Cereal Chem. 86(2):145-156 Fermentation performance of eight waxy, seven nonwaxy soft, and 15 nonwaxy hard wheat cultivars was compared in a laboratory dry-grind procedure. With nitrogen supplements in the mash, the range of ethanol yields was 368-447 L/ton. Nonwaxy soft wheat had an average ethanol yield of 433 L/ton, higher than nonwaxy hard and waxy wheat. Conversion efficiencies were 91.3-96.2%. Despite having higher levels of free sugars in grain, waxy wheat had higher conversion efficiency than nonwaxy wheat. Although there was huge variation in the protein content between nonwaxy hard and soft wheat, no difference in conversion efficiency was observed. Waxy cultivars had extremely low peak viscosity during liquefaction. Novel mashing properties of waxy cultivars were related to unique pasting properties of starch granules. With nitrogen supplementation, waxy wheat had a faster fermentation rate than nonwaxy wheat. Fermentation rates for waxy cultivars without nitrogen supplementation and nonwaxy cultivars with nitrogen supplementation were comparable. Ethanol yield was highly related to both total starch and protein content, but total starch was a better predictor of ethanol yield. There were strong negative relationships between total starch content of grain and both yield and protein content of distillers dried grains with solubles (DDGS).
Biomass and Bioenergy, 2012
A feasible crop breeding strategy for straw utilisation in the ethanol industry requires an in-depth study of the interaction between the feedstock and the microbial agents during the production process. This study investigated the ethanol yield potential of the straw from nine wheat cultivars through consolidated bioprocessing by two strains of Fusarium oxysporum. Plant parameters assessed were plant lignin, cellulose and phenolic acid content; fungal parameters analysed were biomass and cellulase/xylanase activity. Wheat cultivars varied significantly in the amount of ethanol produced from straw by F. oxysporum. Ethanol yielded negatively correlated with the hemicellulose and lignin content of the straw, and the amount of the lignin phenolics syringic acid and coniferyl alcohol. Significant positive correlations were observed between ethanol yield and the activity of the fungal enzymes b-glucosidase and b-xylosidase. If crops such as wheat are to be used for multifunctional purposes, i.e. food and fuel, the assessment of lignocellulose composition and biodegradability must be assessed as part of our crop breeding programmes.
2017
NREL prints on paper that contains recycled content.
Biological Engineering, 2010
This study examined the potential of two winter hulless barley varieties, Eve and VA125, as feedstock for ethanol production. Starch and β-glucan contents of the barley samples were analyzed using official analytical techniques. Both wholegrain and flour samples were hydrolyzed by enzymes and heat treatment preceding fermentation experiments. A simultaneous saccharification and fermentation method was used to convert starch to ethanol. Eve variety had higher starch content than that of VA125. The β-glucan content of VA125 was higher than that of Eve. The highest ethanol conversion efficiency, 88.6%, was attained with the mash prepared from whole-grain Eve. This study demonstrated that winter hulless barley can be a viable feedstock for bio-ethanol production with similar starch content to corn. Dry milling can be used to obtain high starch content flour fractions from barley grain. It is possible to produce ethanol from winter barley varieties with acceptable conversion yields. Optimization of dry milling and ethanol conversion process parameters could improve the economic feasibility of barley-to-ethanol conversion operations.
…, 2011
Wheat grain samples from sixteen winter cultivars originated from four localities were evaluated and compared in traits related to ethanol production as grain yield, grain hardness, content of protein, starch and amylose, and α-amylase activity. Results obtained indicate significant differences between cultivars in amylose content, α-amylase activity, and grain hardness compared to grain yield, protein content, and starch content where differences were not significant. The amylose content, α-amylase activity, and grain hardness were affected by cultivar. Both testing methods for starch fermentation-separated hydrolysis and fermentation (SHF) and simultaneous saccharification and fermentation (SSF) revealed difference between cultivars in ethanol yield.
Foods
Barley and maize have dominated the Irish whiskey sector, but in recent years, alternative grains have started to gain traction. Ireland has a high average wheat yield, producing grain that is high in starch but low in protein, offering the potential for use in distillation. To successfully utilise Irish-grown wheat in distillation, cultivars that are suitable to the Irish climate and give high yields of alcohol need to be identified. This necessitates the development of a rapid screening test for grain alcohol yield. This study examined the optimal temperature, time period, α-amylase dose rate, and calcium concentration to be used in the cooking of wheat grain to maximise alcohol yields. It was determined that lower cooking temperatures are more successful in achieving higher alcohol yields, and it was confirmed that temperature is a key variable in the cooking process. By optimising all parameters, alcohol yields of 458 LA/tonne were obtained, demonstrating that the optimum parame...
2017
Environmental sustainability and greenhouse gas (GHG) mitigation are two of the greatest challenges currently facing the global distilled spirits industry. Regulatory bodies around the world are in the process of placing stretching environmental targets upon domestic distilled spirits production. For example, the Scotch Whisky Association’s environmental strategy has placed environmental targets upon the industry as a whole, including GHG mitigation, improved energy efficiency and specific renewable energy utilisation targets of 20% by 2020, rising to 80% by 2050 (Scotch Whisky Association 2012). In light of this, the area of environmental sustainability and renewable energy utilisation is one of intense research interest. There is significant opportunity to contribute to environmental targets through the utilisation of co-products in the generation of bioenergy. This approach has a several potential advantages, those being greenhouse gas (GHG) mitigation through the substitution of...
Chemical Engineering Research & Design, 2009
This study investigated the economic feasibility of co-producing an arabinoxylan (AX) product with ethanol from wheat, in order to establish whether, under plausible scenarios, it was realistic that a commercial source of wheat AX could be established. The possibility of recovering wheat bran via pearling was also investigated, both as an opportunity to have bran bypass the main ethanol production process and enter the distillers dried grain with solubles (DDGS) co-product in a dry state, or as a means of obtaining bran for AX extraction. Process flowsheets describing three scenarios were created using SuperPro Designer: conventional wheat-to-bioethanol production with DDGS as the principal co-product; bioethanol production with co-production of AX using conventional hammer milling and sieving to recover the bran for AX extraction; and the use of pearling technology to recover bran for AX extraction. Full economic analysis of each of the three scenarios, considering all capital and operating costs, was undertaken, basing comparisons on a constant return on investment in order to estimate the production costs of AX.Sending bran removed via pearling directly to DDGS was not economic; the reduced ethanol yield and increased electricity costs more than offset the savings in drying costs. Simulation of the integrated processes indicated that an AX product of 80% purity could be co-produced with ethanol at a cost of around 3.7–4.5£/kg. This is within the range of comparable viscosity-enhancing ingredients used in the food industry, but is towards the top end of the range. In order to establish a market, AX would therefore need to offer some additional functionality. AX production from bran obtained via pearling was more expensive that from bran obtained via hammer milling and sieving; however, whether the functionality of the AX differs needs to be established. The research indicates that creating a market for AX is feasible in terms of production costs if the AX is co-produced with ethanol. On this basis, further research is justified to investigate the functionality of AX from different sources, to optimise the AX extraction process and to establish the potential of AX as a food or pharmaceutical ingredient.
2013
A comparative study was made for production of alcohol from cereals like Rice and Barley and starch rich tuber crop Potato. For this initially all the starches were subjected to gelatinization followed by Liquefaction by (Liquozyme® SC) and Saccharification by Spirizyme® Fuel.Two methods were studied for each sample like Individual Saccharification and Fermentation(ISF) and Simultaneous Saccharification and Fermentaion(SSF).Yield of alcohol and rate of alcohol fermentation were studied for different processes.The sugar depletion rate for each type of
Agronomy Journal, 2013
All rights reserved. No part of this periodical may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, recording, or any information storage and retrieval system, without permission in writing from the publisher. G lobally, fuel ethanol production has now reached 75 billion L yr -1 , and Canada's contribution is approximately 2 billion L yr -1 (Canadian Renewable Fuels Association, 2010;. Some economists have argued that ethanol fuel production from grain feedstocks relies too heavily on government programs to offset what is considered to be an inefficient system incapable of adequately reducing greenhouse gas emission targets . Others have argued that ethanol should only be produced using crop biomass and residues (Canadian Renewable Fuels Association, 2010), considered by many as agricultural waste . However, the dramatic rise in plant construction and output, including seven ethanol plants operating in western Canada with a collective annual output of 0.5 billion L (Canadian Renewable Fuels Association, 2010), suggests that the economics may not be as important as provincial and federal policies targeting energy diversity, agricultural benefits, and rural renewal . Studies also report that >60% of crop residues must be retained to adequately maintain proper C cycling in the soil in wheat production systems . Therefore, if crop residue exports are limited to 40% to maintain soil quality, ethanol production from grain is probably needed at some level to meet the increasing long-term demand for ethanol. Furthermore, grain-based ethanol production provides grain growers the opportunity to sell their grain into dual markets, which enhances marketing options for cereal production. Today, a producer of CWSWS and CPS wheat, which are preferred for wheat ethanol feedstocks, can choose to sell into a milling market or contract the production to an ethanol plant.
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