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SSRN Electronic Journal
Many devices and objects, from microelectronics to micro uidics, consist of parts made from dissimilar materials, such as different polymers, metals or semiconductors. Techniques for joining such hybrid micro-devices, generally, are based on gluing or thermal processes, which all present some drawbacks. For example, these methods are unable to control the size and shape of the bonded area, and present risks of deterioration and contamination of the substrates. Ultrashort laser bonding is a non-contact and exible technique to precisely join similar and dissimilar materials, used both for joining polymers, and polymers to metallic substrates, but not yet for joining polymers to silicon. We report on direct transmission femtosecond laser bonding of poly(methyl methacrylate) (PMMA) and silicon. The laser process was performed by focusing ultrashort laser pulses at high repetition rate at the interface between the two materials through the PMMA upper layer. The PMMA-Si bond strength was evaluated as a function of different laser processing parameters. A simple, analytical, model was set up and used to determine the temperature of the PMMA during the bonding process. As a proof of concept, the fs-laser bonding of a simple hybrid PMMA-Si micro uidic device has been successfully demonstrated through dynamic leakage tests.
Sensors and Actuators B: Chemical, 2013
Here, we introduce an instantaneous and robust strategy for bonding poly(methylmethacrylate) (PMMA) substrates via ethanol treatment combined with subsequent UV irradiation under ambient conditions, and examine the bonding reversibility by varying the percentage of the ethanolic solution manufactured. Organic solvent such as ethanol can activate the surface of PMMA without sacrificing the optical property of the PMMA substrate, and a subsequent exposure to UV recrosslinks the diffused monomers of acrylate functionalities to realize permanent bonding of two PMMA substrates under mild and ambient experimental conditions, which minimizes the deformation of channel profiles. To achieve robust sealing, two PMMA substrates were immediately placed in direct contact with each other after the treatment with ethanolic solution, and were irradiated under UV. Permanent sealing was realized in less than 1 min. Various bonding analyses were conducted by performing tensile strength measurement, high-throughput leakage test, burst test, and peel test. The highest bonding strength was determined to be approximately 6.17 MPa when 90% ethanolic solution was employed, and the bonding was sufficiently robust to endure intense introduction of liquid whose per-minute injection volume was almost 1200-fold higher than the total internal volume of the microchannel adopted. We also investigated the potential in the manipulation of bonding reversibility, and the critical percentage of ethanolic solution to realize irreversible bonding for PMMA assemblies based on the proposed strategy was determined to be just over 50%.
2010
Abstract Laser direct writing technique is employed to fabricate microstructures, including gratings (buried and surface) and two-dimensional photonic crystal-like structures, in bulk poly (methylmethacrylate)(PMMA) and poly (dimethylsiloxane)(PDMS) using∼ 100 femtosecond (fs) pulses. The variation of structure size with different writing conditions (focussing, speed and energy) was investigated in detail.
IEEE Transactions on Components, Packaging and Manufacturing Technology, 2012
A novel sealing method is proposed for encapsulating devices comprised of glass substrates. This sealing method is based on applying a glass frit paste cord onto the substrate and then using a laser beam to locally supply the necessary energy to allow the formation of a hermetic bonding layer. A detailed description of the laser bonding technique, the necessary equipment and method, and a preliminary study is carried out. The need to apply mechanical pressure during the bonding step is averted, thus facilitating the manufacturing process. The glass bonding cord obtained by the laser-assisted process was found to have an excellent contact with both substrates and no gas inclusions or voids were detected, indicating that an effective sealing was achieved. Preliminary hermeticity tests of the laserbonded cells yielded encouraging results. The developed laserassisted glass frit bonding process is a promising technique for obtaining hermetic sealing of photoelectronic and electrochemical devices, as it allows temperature-sensitive materials to be used inside them.
Sensors and Actuators A: Physical, 2002
A new bonding process for Si-wafer has been developed. The bonding is provided through intermediate layers such as Al or Au forming an eutectic alloy with silicon. A focused laser beam is used to heat up the contact site locally to temperatures well above the eutectic temperature of the corresponding alloys. Depending on the laser wavelength used the bond partner might be Pyrex or silicon. This bonding process is especially suitable for bonding wafers containing devices with low temperature budget. The bonding strength of about 40 MPa is comparable to that of anodic bonding. The presented technique allows for a considerable reduction of the area needed for proper bonding. Furthermore, it provides for electrical contacts between the cap wafer and the device wafer so that new functions can be integrated into the cap.
Applied Optics, 2010
We fabricated several microstructures, such as buried gratings, surface gratings, surface microcraters, and microchannels, in bulk poly(methylmethacrylate) (PMMA) and poly(dimethylsiloxane) (PDMS) using the femtosecond (fs) direct writing technique. A methodical study of the diffraction efficiency (DE) of the achieved gratings was performed as a function of scanning speed, energy, and focal spot size in both PMMA and PDMS. An optimized set of writing parameters has been identified for achieving efficient gratings in both cases. The highest DE recorded in a PDMS grating was ∼10% and ∼34% in a PMMA grating obtained with an 0:65 NA (40X) objective with a single scan. Spectroscopic techniques, including Raman, UV-visible, electron spin resonance (ESR), and physical techniques, such as laser confocal and scanning electron microscopy (SEM), were employed to examine the fs laser-modified regions in an attempt to understand the mechanism responsible for physical changes at the focal volume. Raman spectra collected from the modified regions of PMMA indicated bond softening or stress-related mechanisms responsible for structural changes. We have also observed emission from the fs-modified regions of PMMA and PDMS. An ESR spectrum, recorded a few days after irradiation, from the fs laser-modified regions in PMMA did not reveal any signature of free radicals. However, fs-modified PDMS regions exhibited a single peak in the ESR signal. The probable rationale for the behavior of the ESR spectra in PMMA and PDMS are discussed in the light of free radical formation after fs irradiation. Microchannels within the bulk and surface of PMMA were achieved as well. Microcraters on the surfaces of PMMA and PDMS were also accomplished, and the variation of structure properties with diverse writing conditions has been studied.
Optics Express, 2013
We show that surface swelling is the first step in the interaction of a single femtosecond laser pulse with PMMA. This is followed by perforation of the swollen structure and material ejection. The size of the swelling and the perforated hole increases with pulse energy. After certain energy the swelling disappears and the interaction is dominated by the ablated hole. This behaviour is independent of laser polarization. The threshold energy at which the hole size coincides with size of swelling is 1.5 times that of the threshold for surface swelling. 2D molecular dynamics simulations show surface swelling at low pulse energies along with void formation below the surface within the interaction region. Simulations show that at higher energies, the voids coalesce and grow, and the interaction is dominated by material ejection.
Herein, we present and compare our spectroscopic results on femtosecond (fs) laser irradiated polymers Poly Methyl Methacrylate (PMMA), Poly Di Methyl Siloxane (PDMS) with crystal media such as Lithium Niobate (LiNbO3). Dependence of the structure width with irradiation dose and scan speed is illustrated. Keldysh parameter calculations are highlighted to describe the dominant ionization process. Formation of micro-craters at low irradiation dose and high scan speed is analyzed through minimal pulse to pulse overlap. Formation of defects such as optical and paramagnetic centers in case of polymers is compared with the absence of such defects in crystal media. Confocal micro-Raman studies carried out on polymers and crystal are presented.
2002
Abstract This paper reports the investigation of low-temperature silicon wafer fusion bonding for MEMS applications. A bonding process utilizing annealing temperatures between 400 C and 1100 C was characterized. The silicon-silicon bonded interface was analyzed by Infrared Transmission (IT) and Transmission Electron Microscopy (TEM) and the bond strength was quantified by a four-point bending-delamination technique
2012
Abstract. We have investigated femtosecond-laser-induced microstructures (on the surface and within the bulk), gratings, and craters in four different polymers: polymethyl methacrylate, polydimethylsiloxane, polystyrene, and polyvinyl alcohol. The structures were achieved using a Ti: sapphire laser delivering 100-fs pulses at 800 nm with a repetition rate of 1 kHz and a maximum pulse energy of 1 mJ.
A novel hybrid plasma bonding (HPB) that combines sequential plasma activation (reactive ion etching followed by microwave radicals) with anodic bonding has been developed to achieve void-free and strong silicon/glass bonding at low temperature. The interfacial voids were observed at the silicon/glass interface both in the anodic bonding and in the plasma activated anodic bonding, but the voids were completely disappeared in the HPB method at 200 • C. The bonding strength of the silicon/glass in the HPB was as high as 30 MPa at 200 • C, which was higher than that in the individual treatment of anodic and plasma activated bonding methods. The improved characteristic behavior of the interface in the HPB is attributed to the higher hydrophilicity and smooth surfaces of silicon and glass after sequential plasma activation. These highly reactive and clean surfaces enhance the mobility of alkaline cations from the glass surface across the interface toward the bulk of glass in the HPB. This transportation resulted in a ∼353 nm thick alkaline depletion layer in the glass and enlarged the amorphous SiO 2 across the interface. The void-free strong bonding is attributed to the clean hydrophilic surfaces and the amorphous SiO 2 layer across the interface.
InImpact: The Journal of Innovation Impact, 2014
Joining technologies for incompatible materials are of high interest in many application areas as they allow the combination of the advantages of different materials. This study demonstrates a joining technique for transparent polymers and ceramics using commonly applied materials as examples, namely polymethylmethacrylate (PMMA) and low- temperature co-fired ceramics (LTCC). The concept is to use pre-structured ceramic surfaces with cavities that can be filled with polymeric material locally molten during laser transmission welding. The laser processing used to create appropriate surface textures is described. A variation of the surface pattern was performed and analysed with respect to mechanical bond strength. It was discovered that an increased structure density leads to and increased bond strength reaching a maximum value of 5.2 MPa. Furthermore a technique based on laser transmission welding to replicate surface topographies down to the nanometre scale is described.
MATERIALS TRANSACTIONS, 2013
We succeeded in directly joining Cu with polyethylene terephthalate (PET) using femtosecond laser pulses, which were focused through PET onto the Cu surface which was thermally adhered to PET prior to the laser irradiation. A maximum tensile strength of 5.5 MPa was obtained. X-ray photoelectron spectroscopic spectra of the fractured surface suggested the chemical bonding of Cu with PET. TEM images of the sample showed no voids or no cracks. They also showed the mechanical mixture of Cu with PET around the interface of the joint. We suggest that the ultrashort pulse width of the laser enables the direct joining of these dissimilar materials, thereby avoiding graphitization of the polymeric material.
Tagungsband 1. Symposium Elektronik und Systemintegration ESI 2018: „Von der Sensorik bis zur Aktorik in interdisziplinärer Anwendung“, 2018
We present new micro processing and connecting processes with state-of-the-art ultrashort pulse laser systems with pulse durations in the femtosecond to picosecond timescale. Laser processes like shock-wave induced thin-film delamination (SWIFD), laser patterning of conductive thin films, fabrication of interconnection lines and laser-induced forward transfer (LIFT) of functional materials for the fabrication of microelectronic elements such as interconnects and embedded circuits are discussed in detail. These laser-induced processes and fabrication methods offer new possibilities for the packaging of semiconductor, surface mounted and/or hybrid systems and subsystems. Additionally, processing methods with these laser systems for innovative applications in the microelectronics field like the laser-lift-off for flexible displays and printed circuits, welding of brittle glass materials like sapphire and gorilla glass used in the communication area and micro machining of ceramic substrates with compact workstations equipped with high speed manufacturing tools are also presented.
Laser-Induced Damage in Optical Materials: 2011, 2011
We have investigated femtosecond laser induced microstructures, gratings, and craters in four different polymers: poly methyl methacrylate (PMMA), poly dimethyl siloxane (PDMS), polystyrene (PS) and poly vinyl alcohol (PVA) using Ti:sapphire laser delivering 800 nm, 100 femtosecond (fs) pulses at 1 kHz repetition rate with a maximum pulse energy of 1 mJ. Local chemical modifications leading to the formation of optical centers and peroxide radicals which were studied using UV-Visible absorption and emission, confocal micro-Raman and Electron Spin Resonance (ESR) spectroscopic techniques.
Applied Surface Science
Large-scale microstructures were imprinted on the surface of silicon with dimensions of 1 mm × 1 mm by femtosecond laser line-by-line scanning irradiation. The scanning was made under air and under chlor/hydrogen based liquid layers. Scanning electron microscope investigations evidenced homogeneous surface microstructures, such as: ripples with sub-wavelengths dimensions, Si pillars and directional oriented bacilliform structures. The dependence of the surface morphology on laser energy, scanning speed and irradiation media was analyzed. In air, the microstructure changes from directionalarranged bacilliform structures to well-known ripple structures with a width of about 525 nm. When using the liquid media, we observe ripple structures with a width of about 370 nm and an overlapping of those that evolve in certain regions into Si pillars. The surfaces show interesting gradient topography behaviour which could be used as model scaffolds for the systematic exploration of the role of 3D micro/nano morphology on cell adhesion and growth. By using chlor and hydrogen based liquids we were able to explore the microstructuring of the silicon by line-by-line irradiation process using the femtosecond laser.
Physics Procedia, 2014
Laser transmission joining of dissimilar materials is a novel and promising area of researches on joining technology. However, processes during laser assisted metal plastic (LAMP) joining are not completely explained yet. In the course of this study, the authors investigated the joining process of PMMA plastic and steel by means of laser, as a part of their research on dissimilar material joining. The characteristic process temperature was measured during the joining by different heating conditions, to describe thermal interactions between the polymer and the metal part, and to better understand the mechanism of joining.
Applied Surface Science, 2009
Journal of Materials Processing Technology, 315 (2023)
This study focuses on the influence of surface micropatterns, including uniform and nonuniform grooves fabricated by selective removal of a designed volume from aluminum alloy substrates using a femtosecond laser, on the mode I fracture behavior of adhesively bonded interfaces. The morphology, wettability, chemistry and microstructure of the patterned surfaces have been analyzed. The mode I fracture behavior of adhesive joints was characterized by measuring the fracture resistance using a J-integral approach, and the fracture process in the joint was investigated numerically using a continuum damage model. The results show that the laser patterning has modified the surface roughness, wettability and surface chemistry such that the fracture resistance could be greatly increased. It also reveals the significance of patterning uniformity across the surfaces and the existence of a limiting effective patterning ratio (the ratio of the patterned area to the flat bonding area) on enhancing the fracture resistance. Local plastic deformation that occurred in the adhesive at the patterned structures due to stress concentration was found to be one toughening mechanism although it tended to induce crack growth close to one substrate-adhesive interface.
Laser Pulses - Theory, Technology, and Applications, 2012
Silicon-based integrated systems are actively pursued for sensing and imaging applications. A major challenge to realize highly sensitive systems is the integration of electronic, optical, mechanical and fluidic, all on a common platform. Further, the interface quality between the tiny optoelectronic structures and the substrate for alignment and coupling of the signals significantly impacts the system’s performance. These systems also have to be low-cost, densely integrated and compatible with current and future mainstream technologies for electronic-photonic integration. To address these issues, proper selection of the fabrication, integration and assembly technologies is needed. In this paper, wafer level bonding with advanced features such as surface activation and passive alignment for vertical electrical interconnections are identified as candidate technologies to integrate different electronics, optical and photonic components. Surface activated bonding, superior to other assembly methods, enables low-temperature nanoscaled component integration with high alignment accuracy, low electrical loss and high transparency of the interface. These features are preferred for the hybrid integration of silicon-based micro-opto-electronic systems. In future, new materials and assembly technologies may emerge to enhance the performance of these micro systems and reduce their cost. The article is a detailed review of bonding techniques for electronic, optical and photonic components in silicon-based systems.
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