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volcarona may not be considered to be a legendary as it does infact evolve from a Pokemon called larvesta, but the Pokemon volcarona is considered to be a legendary Pokemon.
You can get Volcarona by catching it at Relic Castle or making your Larvesta (if you have one) evolve into Volcarona starting from level 59.
Larvesta evolves into Volcarona.
Yes. You find zekrom in Pokemon white and the white Pokemon in Pokemon black.
You can catch the main white legendary, Kyrugem, Virizion, Cobalion, Terrakion, Thunderous, Victini, Zorua, Zoroark, Volcarona, and Landorus.