Keep going east, then south, toward Pastoria. Around the "Ruin Maniac" Cave, Cynthia will give you the SecretPotion to clear the Psyduck.
You have to have a secret poison. you get the secret poison from cynthia.
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Psyduck evolves into Golduck, starting at level 33.
Psyduck evolves to Golduck at Lv. 33.
Psyduck can be found in the Safari Zone while surfing.
Why isn't there a Psyduck in the pokemon center?