2 SS . 13 Kinetic Study of Semi Batch Reactor. Practical A. Objective: To study the performance of semi batch reactor in which two reactants ‘are added Continuously and ty collected as a batch. ' B. Expected Program Outcomes (POs): I. Basic and Discipline specific knowledge: Apply knowledge of basic mathematics, si engineering fundamentals and engineering specialization to solve the Chemical a problems. 2. Problem analysis: Identify and analyse well-defined Chemical engineering problems ust standard methods. ngineering \ ions for ical ef solutions for Chemica ng 3. Design/ development of solutions: Design ices technical problems and assist with the design of systems components or pI needs, ‘ modern Chemical engineer!"1 2 3. 4, J. Safety a CHEMICALS ae 0.05 N Ethyl acetate — Gre ro 10 liter 1.05 N_ Sodium ivi jm (OOSN — 100 ml _ os Oxalic ai ama aan 100 ml woo Ne jiyarochioric acid Fiydrochlorc acid _ ciphihatein indicator Phen‘ nd necessary Precautions followed: Beaker should be placed in well ventilated room. Operating temperature should not exceed the boiling point of liquid, Never mix acid and water at once add acid into water drop by drop. Follow instruction given by laboratory assistant and faculty K. Procedure to be followed: Fill the overhead tanks with 0.05N of sodium hydroxide and 0.0SN of ‘ethylacetate, Do N iol seat yao ee ee Feed the reactor with 0.05N of NaOH and 0.05N of ethyl acetate at a constant andequal flow rate lo (ph) for a period of min. : Artest the reaction by adding 30ml of HCI to the reaction mixture ‘Titrate the mixture against 0.0SN of NaOH and note the volume of NaOH Fequiredfor neutralizing L. Observations and Calculations: STANDARDIZATION OF NaOH Take NaOH in the burette, Pipette out 10 ml (Va) Oxalic acid into 100 ml conical flask [Link]. y cro Burette Reading (ml) | Differenc ee Final (F) (mb) bil ; it Ons N ta Pee OBSERVATION AND CALCULATION 1. Normality of HCL N =_0.05 N 2. Normality of NaOH . Ne hie Stes NT Total Teaction time =_lo min 4. Volumetric low rate of NaOH a halt ales i 5. Voh i Slumetric Now rate of CHsCOOCH, ee 6. Initial Conce; i : - tration of NNO coe O.026 mol/l;yclused to arrest reaction Vo a, Volume of NAOH consumed 9 neutralize the mixture Volume of 1 y - ee mi 10.\olume of HCl consumed while arresting the renction =Vo-Vi ml = 2 kel [Link] of HCl consumed while arresting the reaction (Vom Jt F (ek ae ae we Vo-Vanidlecr © (ie - 12, Moles of NaOH unreacted in the reaction © oles of HA nsumed’ © 2 a Sogo Jos oe yoo =_0:025 Smole we Ww 200 LO EY pies concentration of NaOH a Oe occa ; oa mixture at the time of oe moles of NaH unveacted =Z000 ‘ing the reactiom Volume of reation mixture ce = 209 625 nov r; Ee ‘actional conversion of NaOH. a ae ere : Cao ce 1. Resutt: oe as 0s ‘ale constant for saponification reaction Pets te and sodium hydroxide was found to be es = O72 ——limelmin (Analytical method) ks \ Hol min (Graphical i N-Conetusion 1 Feed! Was found OU t0 by erate with NAOT! "ate constant fr the rection of Eahy! aeete0. Quiz: ‘ f the Semi Batch Reactor, disadvantages of the 1. Write down the advantages and dis 8 DS Disadron* eq, SS Acdwo! i oe 2 > Reggiver coo YEPrest Jory) Suh tewr rrek Cost eo > operating coat ang 2 EY Meaibretnle ary eqs eof vee Wag, =) Higa. Consus} ov of wecrehpe Pe qrelity mor} P. References / Suggestions Vrosrtehye trom wom OPERSaHDbh ee Fin i-Wileveindia Pvt, Lie 1. Octave Levenspiel, Chemical Reaction Engineering, 3rd Edition, Wiley. India Pvt 1d sr F a ice Hall of India Pvt. i 2. H. Scott Fogler, Elements of Chemical Reaction Engineering, 4th Edition, Prentice Q. Assessment-Rubrics:practical No. 14 SOLID - LIQUID NON CATALYTIC REACTOR A. Objective: enzoic acid in sodium hydroxide solution with instantaneous Todetermine the specific rate of sano reaction. B, Expected Program Outcomes (POs): of basic mathematics, science and Apply knowledge ecialization to S fic knowledge: gineering sp Basic and Discipline spec! olve the Chemical engineering engineering fundamentals and en problems. 2 problems using codified Problem analysis: Identify and an standard methods. t of solutions: Design/ developmen st with technical problems and ass needs. Engineering Tools, experimen tat annranriate technique to conrT yw the enhanceme.~. Jae sich cases, it is desirable (0 Kno’ Cement. In st : 3 reaction. solved soli or dia by a dissolved soli ntaneous reaction: due to insta as follows, mass transfer jon taking place is In this study the reaction CyHSCOOH + NaOH Coll cid dissolved and reacted, 0 sCOONa + HzO ne mote of sodium hydroxide is conuney vic a Jn mole of Benz0i ‘Thus for eacl ration rate can therefore be fo en by lowed by determining the fall of NaOH concentration, The 1 lowe dissol | dissolution of Benzoic acid is gt waa - NOOHL y Volume of NaOH R= Time W «the rate of dissolution, [NaOH] & [NaOH are initial and final sodium hydroxide concentaig Where R is the rate of dis i : respectively. The specific rate is then obtained by R’ =R/Aavg where Aavg is the average surface ara it ively s is givenby, 2 ‘Asy=% Dave Lavg + {3/4 (Dave D*2)} HEH ety H. Experimental set up: FRA Y 2S XBEO B 1. Resources/Equipment Required: a (G22? ) i vu APPARATUS Cylindrical mold of Benzoic acid 1No Ane Dissolution set a sir? 250 ml Conical flask 50 ml burette 20 mil pipette CHEMICALS AND REAGENTS Sodium hydroxide as tracer Oxali Phenolphthalein indicator ‘+. Safety and necessary Precautions followed: * Beaker should be placed in well ver lated room. * Operating temper : ' femperature should not exceed the boiling point of liquid. © Never mi "acid and water at once add acid into water drop by drop. © Polly ‘sllow instruction given by laboratory a tant and faculty K. Procedure to be followed: Prepare the soi ; eet he solid Bey : indrical mold with &! mibitecae ‘woic acid by melting the acid and pouring the cylindrical Measure the dimensions of the cylinder Prepare 100 0 ci ee MIOFORN sodium hydroxide and 100 ml of 0.1 N oxalic “sodium hydroxide by titrating against standard oxalic 4°! 4 accurately: id snolphthalein as phet id using0" jum nyaroxide solution in the beaker fix the benzoic acid mold in the setup : is 3 N sol : — ng dissolution to proceed for 15 minutes. canple of the solution and titrate ageinst 0.1 N oxalic acid using of NaOH. ere (0 find final normality rubatei we pe ial gimensions of the cylinder iA sat — and Caleulations: Dpsel : oq with Reaction jssolution ; “ é _ a= NaOH yy ferme seat ssoution of Benzoic acid - a Pee Shea 9 REO pi spose Dissolution rate Ro Aavg st ad * ae ee] ET 8 Result: cific rate of dissolution of Benzoic acid in sodium hydroxide solution withinstantancous reaction The spe was found tbe mol/m’s. Conelusion [Link]: 1. Compare catalytic ‘ atalytic reaction and non catal Pa pow sete tne _Bockdy . ; ms cots Bo si Stas ves ae Opa e ah Pw eee Iowan cof , Sherrer GP tus. vy eaerey ee progreme Of fu veption gute Step prow Wnanieatvoue oo Oe wp The re te meow wp SHO sete ee ee Se Copery pie mrecrcet oh oe ora a to as wb cat we CLOATOW + 7 i aL o 2 te Nos Low Nos, 2 & Ahir ag crucls er pe, veslusction a4 fvor eto tcp Sheek. 3rd Edition, Wiley In ition, PR Refer ences / Suggestions : jon Engineeti"& Engineering, 4 Prentice Hall of India Pvt. Ltd, jon Engineering 1. Octave Levenspiel, Chemical React 2H. Scott Fogler, Elements ‘of Chemical Reacti