Latitude Longitude Elevation (m) Density (g cm-3) Shielding correction 10Be concentration (atoms ... more Latitude Longitude Elevation (m) Density (g cm-3) Shielding correction 10Be concentration (atoms g-1) Uncertainty in 10Be concentration (atoms g-1) Name of Be-10 standardization CNR01 53
Metal-salt amended soils (MA, n = 23), and historically-contaminated urban soils from two English... more Metal-salt amended soils (MA, n = 23), and historically-contaminated urban soils from two English 11 cities (Urban, n = 50), were investigated to assess the effects of soil properties and contaminant source on metal lability and solubility. A stable isotope dilution method, with and without a resin purification step, was used to measure the lability of Cd, Cu, Ni, Pb and Zn. For all five metals in MA soils, lability (%E-values) could be reasonably well predicted from soil pH value with a simple logistic equation. However, there was evidence of continuing time-dependent fixation of Cd and Zn in the MA soils, following more than a decade of storage under air-dried conditions, mainly in high pH soils. All five 17
Arable soils are critical resources that support multiple ecosystem services. They are frequently... more Arable soils are critical resources that support multiple ecosystem services. They are frequently threatened, however, by accelerated erosion. Subsequently, policy to ensure their long-term security is an urgent societal priority. Although their long-term security relies upon a balance between the rates of soil loss and formation, there have been few investigations of the formation rates of soils supporting arable agriculture. This paper addresses this knowledge gap by presenting the first isotopically constrained soil formation rates for an arable (Nottinghamshire, UK) and coniferous woodland hillslope (Shropshire, UK). Rates ranged from 0.026 to 0.096 mm yr −1 across the two sites. These rates fall within the range of previously published rates for soils in temperate climates and on sandstone lithologies but significantly differed from those measured in the only other UK-based study. We suggest this is due to the parent material at our sites being more susceptible to weathering. Furthermore, soil formation rates were found to be greatest for aeolian-derived sandstone when compared with fluvially derived lithology raising questions about the extent to which the petrographic composition of the parent material governs rates of soil formation. On the hillslope currently supporting arable agriculture, we utilized cosmogenically derived rates of soil formation and erosion in a first-order lifespan model and found, in a worst-case scenario, that the backslope A horizon could be eroded in 138 years with bedrock exposure occurring in 212 years under the current management regime. These findings represent the first quantitative estimate of cultivated soil lifespans in the UK.
Improving our knowledge of soil formation is critical so that we can better understand the first-... more Improving our knowledge of soil formation is critical so that we can better understand the first-order controls on soil thickness and more effectively inform land management decisions. Cosmogenic radionuclide analysis has allowed soil scientists to more accurately constrain the rates at which soils form from bedrock. In such analysis, the concentration of an isotope, such as Beryllium-10, is measured from a sample of bedrock. Since this concentration is partly governed by the lowering of the bedrock-soil interface, a cosmogenic depth-profile model can be fitted to infer the bedrock and surface lowering rates compatible with the measured concentrations. Given that bedrock-soil interface is shielded by soil, the cosmic rays responsible for the in-situ production of the radionuclide are attenuated, with attenuation rates dependent on the density profile of this soil. Many studies have assumed that soil bulk density is either equal to that of the bedrock or constant with depth. The failure to acknowledge the variations in soil bulk density means that cosmogenically-derived soil formation rates previously published may be under-or overestimates. Here, we deploy a new model called 'CoSOILcal' to a global compilation of cosmogenic analyses of soil formation and, by making use of estimated bulk density profiles, recalculate rates of soil formation to assess the sensitivity to this important parameter. We found that where a soil mantle > 0.25 m overlies the soil-bedrock interface, accounting for the soil bulk density profile brings about a significantly slower rate of soil formation than that previously published. Moreover, the impact of using bulk density profiles on cosmogenically-derived soil This article is protected by copyright. All rights reserved. formation rates increases as soil thickens. These findings call into question the accuracy of our existing soil formation knowledge and we suggest that future cosmogenic radionuclide analysis must consider the bulk density profile of the overlying soil.
Purpose Engineering and dredging strategies to manage sediment, along with river-scouring, can re... more Purpose Engineering and dredging strategies to manage sediment, along with river-scouring, can reveal older sediments. These present a unique opportunity to assess past sources of phosphorus (P) inputs into river sediments. We used the sediment concentrations of P, lead (Pb) and 206/207Pb isotopes to produce ‘first-order’ estimates of the source (diffuse agricultural or sewage treatment) of phosphorus. Materials and methods Sediment cores (n = 30) were collected from the length of the non-tidal River Nene, a lowland river in eastern England. Cores were analysed for sediment elemental concentrations and Pb isotopes. Principal component analysis and linear regression modelling were used to assess the relationships between P, Pb and Pb isotopes. Monte-Carlo simulations and boot-strapping were undertaken to estimate, with 95% confidence intervals, the source of P in these sediments. Results and discussion Analysis of the relationships between PTotal, PbTotal and 206/207Pb isotope ratios...
Cadmium and zinc were added at 3 and 300 mg kg−1, respectively, to 23 soils and incubated at 16°C... more Cadmium and zinc were added at 3 and 300 mg kg−1, respectively, to 23 soils and incubated at 16°C and 80% field capacity for 818 d. Following addition of metal, changes in the radio-labile concentrations of both elements were examined on seven separate sampling occasions over 818 d. At each sample time, soil pore water was extracted using Rhizon soil solution samplers, and concentrations of Cd, Zn, dissolved organic carbon, and major cations and anions were determined. The chemical speciation program WHAM 6 was used to determine free metal ion activity, (M2+). Similar measurements were made on a set of historically contaminated soils from old mining areas, sewage sludge disposal facilities, and industrial sources. The two data sets were combined to give a range of values for p(Cd2+) and p(Zn2+) that covered 5 and 4 log10 units, respectively. A pH-dependent Freundlich model was used to predict Zn2+ and Cd2+ ion activity in soil pore water. Total and radio-labile metal ion concentration in the solid phase was assumed to be adsorbed on the “whole soil,” humus, or free iron oxides to provide alternative model formats. The most successful models assumed that solubility was controlled by adsorption on soil humus. Inclusion of ionic strength as a model variable provided small improvements in model fit. Considering competition with Ca2+ and between Zn2+ and Cd2+ produced no apparent improvement in model fit. Surprisingly, there was little difference between the use of total and labile adsorbed metal as a model determinant. However, this may have been due to a strong correlation between metal lability and pH in the data set used. Values of residual standard deviation for the parameterized models using labile metal adsorbed on humus were 0.26 and 0.28 for prediction of p(Cd2+) and p(Zn2+), respectively. Solubility control by pure Zn and Cd minerals was not indicated from saturation indices. However there may have been fixation of metals to non-radio-labile forms in CaCO3 and Ca-phosphate compounds in the soils in the higher pH range. Independent validation of the Cd model was carried out using an unpublished data set that included measurements of isotopically exchangeable Cd. There was good agreement with the parameterized model.
The NERC and CEH trademarks and logos ('the Trademarks') are registered trademarks of NERC in the... more The NERC and CEH trademarks and logos ('the Trademarks') are registered trademarks of NERC in the UK and other countries, and may not be used without the prior written consent of the Trademark owner.
Soils deliver multiple ecosystem services and their long-term sustainability is fundamentally con... more Soils deliver multiple ecosystem services and their long-term sustainability is fundamentally controlled by the rates at which they form and erode. Our knowledge and understanding of soil formation is not commensurate with that of soil erosion, in part due to the difficulty of measuring the former. However, developments in cosmogenic radionuclide accumulation models have enabled soil scientists to more accurately constrain the rates at which soils form from bedrock. To date, all three major rock typesigneous, sedimentary and metamorphic lithologieshave been examined in such work. Soil formation rates have been measured and compared between these rock types, but the impact of rock characteristics on soil formation rates, such as rock matrices and mineralogy, have seldom been explored. In this UK-based study, we used cosmogenic radionuclide analysis to investigate whether the lithological variability of sandstone governs pedogenesis. Soil formation rates were measured on two arable hillslopes at Woburn and Hilton, which are underlain by different types of arenite sandstone. Rates were faster at Woburn, and we suggest that this is due to the fact that the Woburn sandstone formation is less cemented that that at Hilton. Similarly, rates at Woburn and Hilton were found to be faster than those measured at two other sandstone-based sites in the UK, and faster than those compiled in a global inventory of cosmogenic studies on sandstone-based soils. We suggest that the cementing agents present in matrixabundant wackes studied previously may afford these sandstones greater structural integrity and resistance to weathering. This work points to the importance of factoring bedrock matrices into our understanding of soil formation rates, and the biogeochemical cycles these underpin.
Here we describe and evaluate the success of a multi‐institutional Centre for Doctoral Training (... more Here we describe and evaluate the success of a multi‐institutional Centre for Doctoral Training (CDT), which was established to address a UK skills shortage in Soil Science. The government‐funded ‘STARS’ (Soils Training And Research Studentships) CDT was established in 2015 across a range of universities and research institutes in the UK. It recruited 41 PhD students equitably split across the institutions under four core research themes identified as being central to the national need, namely, (1) Understanding the soil–root interface, (2) Soils and the delivery of ecosystem services, (3) Resilience and response of functions in soil systems and (4) Modelling the soil ecosystem at different spatial and temporal scales. In addition, the STARS CDT provided a diverse skills programme, including: Holistic training in soils, the promotion of collegiality and joint working, strategies to promote science and generate impact, internships with end users (e.g., policymakers, industry), person...
Latitude Longitude Elevation (m) Density (g cm-3) Shielding correction 10Be concentration (atoms ... more Latitude Longitude Elevation (m) Density (g cm-3) Shielding correction 10Be concentration (atoms g-1) Uncertainty in 10Be concentration (atoms g-1) Name of Be-10 standardization CNR01 53
Metal-salt amended soils (MA, n = 23), and historically-contaminated urban soils from two English... more Metal-salt amended soils (MA, n = 23), and historically-contaminated urban soils from two English 11 cities (Urban, n = 50), were investigated to assess the effects of soil properties and contaminant source on metal lability and solubility. A stable isotope dilution method, with and without a resin purification step, was used to measure the lability of Cd, Cu, Ni, Pb and Zn. For all five metals in MA soils, lability (%E-values) could be reasonably well predicted from soil pH value with a simple logistic equation. However, there was evidence of continuing time-dependent fixation of Cd and Zn in the MA soils, following more than a decade of storage under air-dried conditions, mainly in high pH soils. All five 17
Arable soils are critical resources that support multiple ecosystem services. They are frequently... more Arable soils are critical resources that support multiple ecosystem services. They are frequently threatened, however, by accelerated erosion. Subsequently, policy to ensure their long-term security is an urgent societal priority. Although their long-term security relies upon a balance between the rates of soil loss and formation, there have been few investigations of the formation rates of soils supporting arable agriculture. This paper addresses this knowledge gap by presenting the first isotopically constrained soil formation rates for an arable (Nottinghamshire, UK) and coniferous woodland hillslope (Shropshire, UK). Rates ranged from 0.026 to 0.096 mm yr −1 across the two sites. These rates fall within the range of previously published rates for soils in temperate climates and on sandstone lithologies but significantly differed from those measured in the only other UK-based study. We suggest this is due to the parent material at our sites being more susceptible to weathering. Furthermore, soil formation rates were found to be greatest for aeolian-derived sandstone when compared with fluvially derived lithology raising questions about the extent to which the petrographic composition of the parent material governs rates of soil formation. On the hillslope currently supporting arable agriculture, we utilized cosmogenically derived rates of soil formation and erosion in a first-order lifespan model and found, in a worst-case scenario, that the backslope A horizon could be eroded in 138 years with bedrock exposure occurring in 212 years under the current management regime. These findings represent the first quantitative estimate of cultivated soil lifespans in the UK.
Improving our knowledge of soil formation is critical so that we can better understand the first-... more Improving our knowledge of soil formation is critical so that we can better understand the first-order controls on soil thickness and more effectively inform land management decisions. Cosmogenic radionuclide analysis has allowed soil scientists to more accurately constrain the rates at which soils form from bedrock. In such analysis, the concentration of an isotope, such as Beryllium-10, is measured from a sample of bedrock. Since this concentration is partly governed by the lowering of the bedrock-soil interface, a cosmogenic depth-profile model can be fitted to infer the bedrock and surface lowering rates compatible with the measured concentrations. Given that bedrock-soil interface is shielded by soil, the cosmic rays responsible for the in-situ production of the radionuclide are attenuated, with attenuation rates dependent on the density profile of this soil. Many studies have assumed that soil bulk density is either equal to that of the bedrock or constant with depth. The failure to acknowledge the variations in soil bulk density means that cosmogenically-derived soil formation rates previously published may be under-or overestimates. Here, we deploy a new model called 'CoSOILcal' to a global compilation of cosmogenic analyses of soil formation and, by making use of estimated bulk density profiles, recalculate rates of soil formation to assess the sensitivity to this important parameter. We found that where a soil mantle > 0.25 m overlies the soil-bedrock interface, accounting for the soil bulk density profile brings about a significantly slower rate of soil formation than that previously published. Moreover, the impact of using bulk density profiles on cosmogenically-derived soil This article is protected by copyright. All rights reserved. formation rates increases as soil thickens. These findings call into question the accuracy of our existing soil formation knowledge and we suggest that future cosmogenic radionuclide analysis must consider the bulk density profile of the overlying soil.
Purpose Engineering and dredging strategies to manage sediment, along with river-scouring, can re... more Purpose Engineering and dredging strategies to manage sediment, along with river-scouring, can reveal older sediments. These present a unique opportunity to assess past sources of phosphorus (P) inputs into river sediments. We used the sediment concentrations of P, lead (Pb) and 206/207Pb isotopes to produce ‘first-order’ estimates of the source (diffuse agricultural or sewage treatment) of phosphorus. Materials and methods Sediment cores (n = 30) were collected from the length of the non-tidal River Nene, a lowland river in eastern England. Cores were analysed for sediment elemental concentrations and Pb isotopes. Principal component analysis and linear regression modelling were used to assess the relationships between P, Pb and Pb isotopes. Monte-Carlo simulations and boot-strapping were undertaken to estimate, with 95% confidence intervals, the source of P in these sediments. Results and discussion Analysis of the relationships between PTotal, PbTotal and 206/207Pb isotope ratios...
Cadmium and zinc were added at 3 and 300 mg kg−1, respectively, to 23 soils and incubated at 16°C... more Cadmium and zinc were added at 3 and 300 mg kg−1, respectively, to 23 soils and incubated at 16°C and 80% field capacity for 818 d. Following addition of metal, changes in the radio-labile concentrations of both elements were examined on seven separate sampling occasions over 818 d. At each sample time, soil pore water was extracted using Rhizon soil solution samplers, and concentrations of Cd, Zn, dissolved organic carbon, and major cations and anions were determined. The chemical speciation program WHAM 6 was used to determine free metal ion activity, (M2+). Similar measurements were made on a set of historically contaminated soils from old mining areas, sewage sludge disposal facilities, and industrial sources. The two data sets were combined to give a range of values for p(Cd2+) and p(Zn2+) that covered 5 and 4 log10 units, respectively. A pH-dependent Freundlich model was used to predict Zn2+ and Cd2+ ion activity in soil pore water. Total and radio-labile metal ion concentration in the solid phase was assumed to be adsorbed on the “whole soil,” humus, or free iron oxides to provide alternative model formats. The most successful models assumed that solubility was controlled by adsorption on soil humus. Inclusion of ionic strength as a model variable provided small improvements in model fit. Considering competition with Ca2+ and between Zn2+ and Cd2+ produced no apparent improvement in model fit. Surprisingly, there was little difference between the use of total and labile adsorbed metal as a model determinant. However, this may have been due to a strong correlation between metal lability and pH in the data set used. Values of residual standard deviation for the parameterized models using labile metal adsorbed on humus were 0.26 and 0.28 for prediction of p(Cd2+) and p(Zn2+), respectively. Solubility control by pure Zn and Cd minerals was not indicated from saturation indices. However there may have been fixation of metals to non-radio-labile forms in CaCO3 and Ca-phosphate compounds in the soils in the higher pH range. Independent validation of the Cd model was carried out using an unpublished data set that included measurements of isotopically exchangeable Cd. There was good agreement with the parameterized model.
The NERC and CEH trademarks and logos ('the Trademarks') are registered trademarks of NERC in the... more The NERC and CEH trademarks and logos ('the Trademarks') are registered trademarks of NERC in the UK and other countries, and may not be used without the prior written consent of the Trademark owner.
Soils deliver multiple ecosystem services and their long-term sustainability is fundamentally con... more Soils deliver multiple ecosystem services and their long-term sustainability is fundamentally controlled by the rates at which they form and erode. Our knowledge and understanding of soil formation is not commensurate with that of soil erosion, in part due to the difficulty of measuring the former. However, developments in cosmogenic radionuclide accumulation models have enabled soil scientists to more accurately constrain the rates at which soils form from bedrock. To date, all three major rock typesigneous, sedimentary and metamorphic lithologieshave been examined in such work. Soil formation rates have been measured and compared between these rock types, but the impact of rock characteristics on soil formation rates, such as rock matrices and mineralogy, have seldom been explored. In this UK-based study, we used cosmogenic radionuclide analysis to investigate whether the lithological variability of sandstone governs pedogenesis. Soil formation rates were measured on two arable hillslopes at Woburn and Hilton, which are underlain by different types of arenite sandstone. Rates were faster at Woburn, and we suggest that this is due to the fact that the Woburn sandstone formation is less cemented that that at Hilton. Similarly, rates at Woburn and Hilton were found to be faster than those measured at two other sandstone-based sites in the UK, and faster than those compiled in a global inventory of cosmogenic studies on sandstone-based soils. We suggest that the cementing agents present in matrixabundant wackes studied previously may afford these sandstones greater structural integrity and resistance to weathering. This work points to the importance of factoring bedrock matrices into our understanding of soil formation rates, and the biogeochemical cycles these underpin.
Here we describe and evaluate the success of a multi‐institutional Centre for Doctoral Training (... more Here we describe and evaluate the success of a multi‐institutional Centre for Doctoral Training (CDT), which was established to address a UK skills shortage in Soil Science. The government‐funded ‘STARS’ (Soils Training And Research Studentships) CDT was established in 2015 across a range of universities and research institutes in the UK. It recruited 41 PhD students equitably split across the institutions under four core research themes identified as being central to the national need, namely, (1) Understanding the soil–root interface, (2) Soils and the delivery of ecosystem services, (3) Resilience and response of functions in soil systems and (4) Modelling the soil ecosystem at different spatial and temporal scales. In addition, the STARS CDT provided a diverse skills programme, including: Holistic training in soils, the promotion of collegiality and joint working, strategies to promote science and generate impact, internships with end users (e.g., policymakers, industry), person...
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