Papers by Rizwan Ahmed Malik
Crystals, 2020
To enhance the potential application of naturally biodegradable polylactic acid (PLA)-based compo... more To enhance the potential application of naturally biodegradable polylactic acid (PLA)-based composites reinforced with magnesium alloy, anodized coatings between Mg and PLA were fabricated on AZ31 magnesium alloy rods. After anodizing (AO) at four different treatment times, the surface demonstrated a typical porous MgO ceramics morphology, which greatly improved the mechanical properties of composite rods compared to untreated pure Mg. This was attributed to the micro-anchoring effect, which increases interfacial binding forces significantly between the Mg rod and PLA. Additionally, the AO layer can also substantially improve the degradability of composite rods in Hank's solution, due to good corrosion resistance and stronger bonding between PLA and Mg. With a prolonged immersion time of up to 30 days, the porous MgO coating was eventually found to be degraded, evolving to a comparatively smooth surface resulting in a decline in mechanical properties due to a decrease in interfacial bonding strength. According to the current findings, the PLA-clad surface treated Mg composite rod may hold promise for use as a bioresorbable implant material for orthopedic inner fixation.
Lead-free 0.99[(Bi0.5Na0.5)0.935Ba0.065Ti(1–x)NbxO3]–0.01SrZrO3 (BNBTNb100x–SZ, with Nb100x = 0–1... more Lead-free 0.99[(Bi0.5Na0.5)0.935Ba0.065Ti(1–x)NbxO3]–0.01SrZrO3 (BNBTNb100x–SZ, with Nb100x = 0–1) ceramics were prepared by the conventional mixed oxide route. X-ray diffraction and Raman scattering was utilized for the structural evolution of Nb-modified BNBT–SZ ceramics at average and short-scale localized structure. Temperature dependent dielectric properties showed ferroelectric–ergodic relaxor (FE–ER) transition in Nb-modified BNBT–SZ ceramics by producing a significant disruption of the long-range FE order. A giant normalized strain of 825 pm/V at 4 kV/mm was achieved at Nb1.0. Interestingly, at a relatively low applied field of 3 kV/mm, the Nb0.75 sample displayed a large electric field-induced strain (EFIS) response of 0.20%, which is highest value obtained in non-textured lead-free BNT-based ceramics at such low driving field. The structural distortion induced by doping and electric poling is correlated with the dielectric, ferroelectric and EFIS response, and the evolution of giant strain was ascribed to reversible field induced phase transition from ER–FE phase.
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Papers by Rizwan Ahmed Malik