Papers by Esther Jebakumari
Elsevier eBooks, Dec 31, 2023
The Journal of Physical Chemistry Letters
Biosensors
Two-dimensional nanostructures (2DNS) attract tremendous interest and have emerged as potential m... more Two-dimensional nanostructures (2DNS) attract tremendous interest and have emerged as potential materials for a variety of applications, including biomolecule sensing, due to their high surface-to-volume ratio, tuneable optical and electronic properties. Advancements in the engineering of 2DNS and associated technologies have opened up new opportunities. Surface-enhanced Raman scattering (SERS) is a rapid, highly sensitive, non-destructive analytical technique with exceptional signal amplification potential. Several structurally and chemically engineered 2DNS with added advantages (e.g., π–π* interaction), over plasmonic SERS substrates, have been developed specifically towards biomolecule sensing in a complex matrix, such as biological fluids. This review focuses on the recent developments of 2DNS-SERS substrates for biomolecule sensor applications. The recent advancements in engineered 2DNS, particularly for SERS substrates, have been systematically surveyed. In SERS substrates, 2...
Critical Reviews in Analytical Chemistry, Nov 17, 2021
Transistor-based sensors have been widely recognized to be highly sensitive and reliable for poin... more Transistor-based sensors have been widely recognized to be highly sensitive and reliable for point-of-care/bed-side diagnosis. In this line, a range of cutting-edge technologies has been generated to elevate the role of transistors for biomolecule detection. Detection of a wide range of clinical biomarkers has been reported using various configurations of transistors. The inordinate sensitivity of transistors to the field-effect imparts high sensitivity toward wide range of biomolecules. This overview has gleaned the present achievements with the technological advancements using high performance transistor-based sensors. This review encloses transistors incorporated with a variety of functional nanomaterials and organic elements for their excellence in selectivity and sensitivity. In addition, the technological advancements in fabrication of these microdevices or nanodevices and functionalization of the sensing elements have also been discussed. The technological gap in the realization of sensors in transistor platforms and the resulted scope for research has been discussed. Finally, foreseen technological advancements and future research perspectives are described.
The Journal of Physical Chemistry Letters, 2021
Investigating the behavior of analytes at the electrode surface is crucial in understanding the e... more Investigating the behavior of analytes at the electrode surface is crucial in understanding the electrochemical and electrocatalytic reactions. Although Surface Enhanced Raman Scattering (SERS) is sensitive to minor chemical changes in the analyte, it is not widely used to study the reaction mechanisms on nonplasmonic surfaces because of the interference from plasmonic SERS substrates. In this study, we have investigated the redox reaction of Nile Blue A on a glassy carbon surface using pinhole-free silica-coated silver nanoparticles for Raman signal enhancement. The silver nanostructures were synthesized by a chemical reduction method, and the quality of the silica layer was confirmed using microscopic and electrochemical method. The in situ spectroelectrochemical data reveals the catalytic interference from silver which considerably alters the native reaction mechanism. The pinhole-free silica layer prevents the hot electron transfer and yields an interference-free enhancement to the Raman signals.
Materials Research Bulletin
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Papers by Esther Jebakumari