Papers by Agus Supriyanto
Berkala Fisika Indonesia : Jurnal Ilmiah Fisika, Pembelajaran dan Aplikasinya, 2015
INTERNATIONAL CONFERENCE ON SCIENCE AND APPLIED SCIENCE (ICSAS2020), 2020
Comparison of Nanocomposite ZnO/TiO2 Composition Dye-Sensitized Solar Cell (DSSC) with Natural Dye Leaves of Green Mustard (Brassica rapa)
Journal of Physics: Conference Series, 2021
ZnO and TiO2 are semiconductor materials used to make DSSC. In this research Dye-Sensitized Solar... more ZnO and TiO2 are semiconductor materials used to make DSSC. In this research Dye-Sensitized Solar Cell (DSSC) manufacturing by mixing ZnO and TiO2 materials. ZnO is made by synthesis using the sol-gel method with a mixture of zinc tetrahydrate (Zn(NO3)2.4H2O), ammonium hydroxide (NH4OH) and polyethylene glycol (PEG). In this research, the dye used was extracted leaves of green mustard (Brassica rapa) and nanocomposite ZnO/TiO2 with ratio (1:1, 1:2, 1:3). Fabrication using FTO glass with a work area of 1cm × 1cm obtained the results of the efficiency of nanocomposite ZnO/TiO2 (1:1) with an efficiency (η) of 0.0755%, nanocomposite ZnO/TiO2 (1:2) with an efficiency (η) of 0.1935%, nanocomposite ZnO/TiO2 (1:3) with an efficiency (η) of 0.2098%.
Jurnal Fisika, 2013
Sel surya organic merupakan suatu divais fotovoltaik yang mampu mengubah cahaya matahari menjadi ... more Sel surya organic merupakan suatu divais fotovoltaik yang mampu mengubah cahaya matahari menjadi energi listrik. Sel surya organik adalah sebuah alternatif untuk menggantikan sel surya silikon karena dapat diproduksi dengan teknik yang mudah dan biaya yang murah. Struktur pada penelitian ini adalah TiO2/P3HT/elektrolit/FTO dan TiO2/P3HT/elektrolit/FTO+Grafit. Karakterisasi I-V menunjukkan bahwa penambahan konsentrasi P3HT dapat meningkatkan kinerja sel surya. Penggunaan grafit pensil sebagai elektroda lawan menghasilkan performa DSSC yang lebih baik dibandingkan dengan yang tidak menggunakan grafit pensil. Grafit pensil yang dideposisikan pada kaca konduktif sebagai elektroda lawan mampu menjadi katalis untuk mempercepat reaksi redoks dengan elektrolit. Performa sel surya terbaik dari penelitian ini diperoleh pada sel dengan struktur TiO2/P3HT/elektrolit/FTO+Grafit dengan konsentrasi P3HT 1% dan menggunakan grafit sebagai elektroda lawan, efisiensi yang dihasilkan adalah 2,9×10-3%.
Jurnal Penelitian Fisika dan Aplikasinya (JPFA), 2016
Penelitian ini merupakan penelitian awal untuk mempelajari dan memahami proses pembuatan sel sury... more Penelitian ini merupakan penelitian awal untuk mempelajari dan memahami proses pembuatan sel surya berbasis Dye Sensitized Solar Cell (DSSC) menggunakan Ruthenium (N719). Lapisan fotoelektroda TiO2 menggunakan pasta TiO2 ukuran 21 nm yang dideposisi menggunakan teknik spin coating dan pewarna N719 sebagai dye sensitizer. Counter elektroda Platina dideposisi menggunakan teknik sputtering. Parameter proses yang mempengaruhi karakteristik listrik sel surya dianalisa dan diukur. Karakteristik kurva I-V sel surya diukur menggunakan Kethely dengan variasi intensitas yaitu 100 Watt/m2, 250 Watt/m2, 500 Watt/m2, 750 Watt/m2 dan 1000 Watt/m2.Prototipe sel yang terbaik menghasilkan effisiensi sebesar 0,15%.Uji absorbansi menggunakan Spectrophotometer UV Visible 1601 PC dan uji sifat kelistrikan menggunakan Elkahfi 100/Meter I-V. Hasil menunjukkan bahwa pewarna organik sintesis ruthenium (N719) memiliki absorbansi yang kuat pada panjang gelombang 400-550 nm ini menjadikan dye ruthenium (N719) ...
Dye-sensitized solar cells (DSSCs) play important role to convert lights into electric energy sin... more Dye-sensitized solar cells (DSSCs) play important role to convert lights into electric energy since they are manufactured easily and cheap. However, DSSCs do not fit for long run because of the leakage of liquid electrolytes. This paper reports the manufacturing of DSSCs based on a semi-solid electrolyte. The electrolyte and the working electrode were synthesized by electrospinning method. The solid-state electrolyte was prepared from the solution of NaI/I2/HPA that dropped into fibers electrospun from polyvinyl alcohol (PVA) on the counter electrode. The working electrode was prepared and electrospun from the solution of Zinc acetate (ZnAc)/AlCl3/PVA onto the FTO (fluorine-doped tin oxide) glass. The flow rate of solutions for electrospinning process was adjusted 2, 4, 6 μl/min. The morphology of electrode and electrolyte was tested by scanning electron microscopy (SEM). N719 dye was used as sensitizer. The solar cell performance was examined by Keithley 2602A under illumination of...
Significant efficiency improvement of TiO2:LEG4-Ag layer dye sensitized solar cells by incorporating small concentration of Ag
Optik, 2021
Abstract In the last two decades, Dye-sensitized Solar Cells (DSSCs) have been frequently discuss... more Abstract In the last two decades, Dye-sensitized Solar Cells (DSSCs) have been frequently discussed due to its daily use. Various modifications of the solar cell manufacturing method are currently needed to get high-efficiency magnitudes influenced by several factors. Improvisation by addition variety concentration of Ag metal into the dye using the spin coating method has been carried out in this study. In addition, the strategy has been offered to maximize the function of the dye as a sensitizer. In this study, FESEM characterization was carried out to observe the morphology of the material surfaces. The presence of TiO2 and Ag are evaluated by EDX and XRD analysis. The Absorbances have been measured by UV–vis spectroscopy, and photovoltaic performance has been analyzed by IV-Meter (solar simulator) and IPCE. The highest efficiency magnitude is 6.30 % obtained in the smallest concentration of Ag addition, denoted as TiO2:LEG4-Ag1. Therefore, the addition of Ag with small concentration considerably impacted on improving DSSC's performance.
Journal of Physics: Theories and Applications, 2019
The natural dye extracted from Amaranthus dye and Carica Papaya dye which has been prepared in et... more The natural dye extracted from Amaranthus dye and Carica Papaya dye which has been prepared in ethanol solution as a sensitizer on DSSC. The Spin coating method is used so that the deposition on TiO2 gets a homogeneous thin layer on the active area of the FTO substrate. The dye solution was tested for characterization using the Elkahfi I-V Meter and UV-Vis 1601 while the FTO structure substrate that had been prepared as a sandwich was tested using Keithley I-V type 2602A. The result of absorbance of dye is at a wavelength of 400 nm - 800 nm and there is also a shift in wavelength and peak absorption of the dye. The greatest efficiency was obtained from chlorophyll amaranthus which is 0.730% while chlorophyll Carica papaya obtained an efficiency of 0.432%. In the combination of Amaranthus dye and Carica papaya dye, the efficiency was 0.526%. High efficiency on TiO2 electrodes shows good performance on Dye-sensitized solar cells.
Journal of Physics: Theories and Applications, 2019
Dye-Sensitized Solar Cell (DSSC) is a solar cell made from organic material that works with an el... more Dye-Sensitized Solar Cell (DSSC) is a solar cell made from organic material that works with an electrochemical photo system to convert solar energy into electrical energy. The components of DSSC consist of transparent conductive substrates, dyes, semiconductors, electrolytes and counter electrodes. Dye as a sensitizer is has an important role in DSSC performance improvement. This study aims to obtain optical characterization such as absorbance spectrum and transmittance from DSSC using dye DN-F01 with concentration 2x10-3 M. Optical characterization has been tested using a UV-VIS Spectrophotometer Shimadzu UV-1800. The test results show that the absorbance spectrum of the dye is at a wavelength of 400-500 nm. Band gap energy of DN-F01 has obtained from its absorbance and transmittance value is about 2,46 eV.
Journal of Physics: Theories and Applications, 2019
This research studied the effect of adding synthetic dye DN-F05 (red dye) to electrical and optic... more This research studied the effect of adding synthetic dye DN-F05 (red dye) to electrical and optical properties. Dye-Sensitized Solar Cell (DSSC) sandwich components are consist of FTO/TiO2-Dye-elektrolit-Platina/FTO. In this study, the working electrodes were made by Titanium dioxide (TiO2) which was deposited on FTO glass and then annealed at 450oC for 30 minutes. The dye concentration DN-F05 was made with a mass of 0.001 gr, then will be stirred for 2 hours into 5 ml of ethanol at a temperature of 40oC. In this study the spin coating method is used with a rotational speed of 1000 rpm for 20 seconds. Characterization of optical properties was carried out using a UV-VIS spectrophotometer to determine the absorbance curve of dye and to get Gap energy. The peak absorbance value was obtained at wavelengths between 400-700 nm. This proved that the addition of DN-F05 dye concentration has a major influence on the optical properties.
INTERNATIONAL CONFERENCE ON SCIENCE AND APPLIED SCIENCE (ICSAS) 2019, 2019
Effect of concentration dyenamo yellow (DN-F01) as photosensitizer in dye-sensitized solar cells ... more Effect of concentration dyenamo yellow (DN-F01) as photosensitizer in dye-sensitized solar cells (DSSC) transparent
Jurnal Fisika dan Aplikasinya, 2018
Penelitian ini dilakukan untuk mengkaji pengaruh pH terhadap ikatan kimia dye klorofil pada TiO2 ... more Penelitian ini dilakukan untuk mengkaji pengaruh pH terhadap ikatan kimia dye klorofil pada TiO2 untuk aplikasi DSSC.Variasi pH yang digunakan dalam penelitian ini, yaitu kondisi tanpa penambahan buffer, asam, netral, dan basa. Absorpsi dye klorofil dan TiO2 dikarakterisasi menggunakan spektrofotometer UV-Vis. Ikatan kimia yang terkandung dalam TiO2/ dye klorofil dikarakterisasi menggunakan spektrofotometer FTIR. Efisiensi DSSC dihitung menggunakan I-V meter. Hasil karakterisasi menunjukkan bahwa pada pH asam memiliki absorbansi tertinggi pada rentang panjang gelombang 400-480 nm dan 600-680 nm. Efisiensi konversi tertinggi sebesar 0,013% dengan transmitansi sebesar 89,3% pada bilangan gelombang 3417 cm −1 .
Jurnal Kewirausahaan dan Bisnis, 2019
Application of on-grid PLTS on the effort of catfish enlargement aims to reduce the cost for the ... more Application of on-grid PLTS on the effort of catfish enlargement aims to reduce the cost for the fulfillment of electrical energy, increase knowledge and train the skills to assemble PLTS on grid. Farmers catfish use electrical energy to power the water pump. PLTS on grid enables saving on electricity costs. The use of on-grid PLTS does not require an electric storage battery. The overproduction of electricity from PLTS allows it to be sold to PLN. If there is a shortage of electricity, then electricity is purchased from PLN. Public knowledge about PLTS can be introduced in theory and practice of PLTS installation scale 2000 WP (watt peak). The use of 2000 WP can produce 9.2 KWH / day in sunny conditions.e
Journal of Physics: Theories and Applications, 2017
Copper (Cu) is a conductive metal. Insertion of copper on a TiO2 active layer is the right choice... more Copper (Cu) is a conductive metal. Insertion of copper on a TiO2 active layer is the right choice in the effort to improve Dye-Sensitized Solar Cell (DSSC) performance. Electroplating methods were used in this study to insert copper in the TiO2 layer. The device of DSSC used in this study is natural dye Moringa Oleifera, TiO2-Cu electrode, the counter electrode of Pt and electrolyte from NaI. The peak absorbance of dye is at wavelength 415 nm and maximum efficiency is 0,093% from the time variation electroplating of 25 s. There is increase efficiency from TiO2 to TiO2-Cu electrode with time variation of electroplating. It is shown that insertion of copper in the TiO2 nanoparticles layer improves the performance of DSSC.
Journal of Physics: Conference Series, 2017
Anthocyanin and chlorophyll dyes have been blended as the photosensitizer of Dye-Sensitized Solar... more Anthocyanin and chlorophyll dyes have been blended as the photosensitizer of Dye-Sensitized Solar Cell (DSSC). The results study showed the effect of chemical bond dyes on TiO 2 and the efficiency of DSSC. Ratio blend of the anthocyanin and chlorophyll dyes are 1:1. The absorbance of dyes and TiO 2 were characterized using UV-Vis Spectrophotometer. The chemical bonds contained in TiO 2-dyes were characterized using FT-IR spectrophotometer. The efficiency of DSSC was calculated using I-V meter. The absorption spectra of chlorophyll: anthocyanin blend dye solutions and TiO 2 films can increase after the dye adsorption. Absorbance characterization of anthocyanin and chlorophyll dye blend solutions showed three peaks at the wavelength of 412 nm; 535.5 nm; and 656.5 nm. Absorbance characterization of spinach before being blend with anthocyanin dyes solutions showed two peaks at the wavelength of 431 nm and 665.5 nm. The absorption spectra of TiO 2 films can increase after the dyes adsorption at the wavelength of 400 nm. FT-IR spectra of TiO 2 founded the functional groups C-Br, C=C, and O-H. The functional groups founded in anthocyanin: chlorophyll dye blended on the surface of TiO 2 are C-Br, CO , O-H, C-H, C=C, C=O, and O-H. The result showed that the greatest efficiency of 0.0544% at dye red cabbage-spinach. Adsorption blends of anthocyanin and chlorophyll dyes on the surface of TiO 2 can be used as the photosensitizer for DSSC.
AIP Conference Proceedings, 2017
Zinc Oxide (ZnO) is a semiconductor material that is used in addition to Titanium Dioxide (TiO 2)... more Zinc Oxide (ZnO) is a semiconductor material that is used in addition to Titanium Dioxide (TiO 2) used in the manufacture of Dye-Sensitized Solar Cell (DSSC). ZnO synthesized by using sol-gel mixture of zinc nitrate tetrahydrate (Zn (NO 3) 2 .4H 2 O), ammonium hydroxide (NH 4 OH) and polyethylene glycol (PEG). In this study, the dye was extracted from the leaves of grass jelly (Cyclea barbata). Nanocomposite ZnO/TiO 2 (mixture between ZnO and TiO 2) was obtained by adding the results of the synthesis of ZnO and TiO 2. From fabrication deposited one layer on the FTO glass with a spacious work area 1cm x 1cm obtained increase in conversion efficiency (η) on nanocomposite ZnO/TiO 2 compared with ZnO and TiO 2 , with efficiency (η) TiO 2 0.0130%, ZnO 0.0011% and nanocomposite ZnO/TiO 2 0.0696%.
IOP Conference Series: Materials Science and Engineering, 2017
Organic solar cells have been made using the material poly (3hexylthiophene)(P3HT), [6, 6]-phenyl... more Organic solar cells have been made using the material poly (3hexylthiophene)(P3HT), [6, 6]-phenyl-C61-butyric acid methyl ester (PCBM), and Chlorophyll-a with blend metods. Active layer of P3HT:PCBM:Chlorophyll-a are deposited using spin coating with rotary speed of 2500 rpm for 10 seconds and subsequently heated at 100 0 C for 10 min. Mass of chlorophyll-a are 0.1 mg, 0.2 mg, and 0.3 mg. Thin layers are characterized by UV-Visible Spectrometer Lamda 25 for optical properties and Keithley 2602 for electrical properties. From the UV-Vis showed that absorbance of P3HT:PCBM:Chlorophyll-a are 400-614nm and 620-700 nm. Efficiency of P3HT:PCBM:Chlorophyll-a for mass chlorophyll 0.1 mg, 0.2 mg, and 0.3 mg are 2.68 x 10-2 %, 3.93 x 10-2 %, and 8.79 x 10-2 % respectively.
INDONESIAN JOURNAL OF APPLIED PHYSICS, 2017
Dye-sensitized Solar Cells (DSSC) is photochemical cell comprising photoelektrode, dye, electroly... more Dye-sensitized Solar Cells (DSSC) is photochemical cell comprising photoelektrode, dye, electrolyte and counter electrode. This article discusses the influence of electrode thickness to the electrical properties. The working electrode was deposited by screen printing methods. Screen is used T-49 type. TiO2 deposited on the FTO with variation of the layers number to obtain thickness variation. The TiO2 layer thickness is determined by Scanning Electron Microscopy (SEM), absorbance characterization by UV Visible Lambda 25 and characterization of current-voltage (I-V) used Measurenment Keithley 2602A. The results showed thickness of TiO2 electrode was (1.5 ± 0.2) μm, (2.9 ± 0.5) μm, (3.5 ± 0.6) μm, and (4.5 ± 0.8) μm. Maximum absorbance and highest efficiency value contained in thickness (4.5 ± 0.8) μm. Highest efficiency value is 2.41%.
Journal of Physics: Conference Series, 2017
Dye-sensitized solar cell (DSSC) is a device that converts solar energy into electrical energy. T... more Dye-sensitized solar cell (DSSC) is a device that converts solar energy into electrical energy. The magnitude of the efficiency of DSSC is mainly based on the amount of dye absorbed by the surface of TiO 2. In this work, used natural dye extracted from leaves Rhoeo spathacea. The dye partially used to immerse of TiO 2 as working electrodes, and the rest are directly mixed TiO 2 paste to obtain dye titanium dioxide.The paste TiO 2 and dye titanium dioxide coated onto the fluorine-doped tin oxide (FTO) glass plate by spin coating method. The absorbance spectra of the dye, dye titanium dioxide and TiO 2 were obtained by UV-Vis spectroscopy. The conductivity of the dye, dye titanium dioxide, and TiO 2 was measured by two point probe El-Kahfi 100. The DSSC based on dye titanium dioxide that stirring for 5 hours the highest efficiency of 0,0520 % whereas those based on TiO 2 immersed for 36 hours showed achieved 0,0501 % obtained from I-V characterization.
The effect of Cu doping intoOriza sativa L. indicadye as photosensitizer for dye sensitized solar cell (DSSC)
Journal of Physics: Conference Series, 2016
The aims of the research to are know the effect of Cu doping into natural dye in increasing the e... more The aims of the research to are know the effect of Cu doping into natural dye in increasing the efficiency of DSCC, to determine of the optical and electrical characteristic of natural dye Cu doping. Sandwich structures formed in the sample consisted of working electrode pair Titanium Oxide (TiO2) and the counter electrode Platina (Pt). Absorbance test is measure by using UV-Visible spectrophotometer Lambda 25, conductivity test by using a two- point probe El Kahfi/I-V Meter, and characterization of current and voltage (I-V) by using a Keithley 2602A. The Cu doping into dye was increasing the efficiency of 71%.
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Papers by Agus Supriyanto