At least one of your mail servers supports insufficiently secure parameters for Diffie-Hellman key exchange.
I haven't manually changed any Ciphers or DH KEX Parameters, use the defaults the Image generated/ specified, however I use Let's Encrypt (if this matters).
Configuration:
OVERRIDE_HOSTNAME=
DMS_DEBUG=1
ONE_DIR=1
POSTMASTER_ADDRESS=
PERMIT_DOCKER=
# empty => modern
# modern => Enables TLSv1.2 and modern ciphers only. (default)
# intermediate => Enables TLSv1, TLSv1.1 and TLSv1.2 and broad compatibility ciphers.
# old => NOT implemented. If you really need it, then customize the TLS ciphers overriding postfix and dovecot settings
# (https://github.com/tomav/docker-mailserver/wiki/)
TLS_LEVEL=
SPOOF_PROTECTION=1
ENABLE_SRS=0
ENABLE_POP3=
ENABLE_CLAMAV=1
ENABLE_FAIL2BAN=1
ENABLE_MANAGESIEVE=
POSTSCREEN_ACTION=enforce
SMTP_ONLY=
# Please read [the SSL page in the wiki](https://github.com/tomav/docker-mailserver/wiki/Configure-SSL) for more information.
#
# empty => SSL disabled
# letsencrypt => Enables Let's Encrypt certificates
# custom => Enables custom certificates
# manual => Let's you manually specify locations of your SSL certificates for non-standard cases
# self-signed => Enables self-signed certificates
SSL_TYPE=letsencrypt
VIRUSMAILS_DELETE_DELAY=
ENABLE_POSTFIX_VIRTUAL_TRANSPORT=
POSTFIX_DAGENT=
POSTFIX_MAILBOX_SIZE_LIMIT=512000000
POSTFIX_MESSAGE_SIZE_LIMIT=10240000
REPORT_RECIPIENT=0
REPORT_SENDER=
REPORT_INTERVAL=daily
ENABLE_SPAMASSASSIN=1
SA_TAG=2.0
SA_TAG2=6.31
SA_KILL=6.31
SA_SPAM_SUBJECT=***SPAM*****
ENABLE_FETCHMAIL=0
FETCHMAIL_POLL=300
ENABLE_LDAP=
LDAP_START_TLS=
LDAP_SERVER_HOST=
LDAP_SEARCH_BASE=
LDAP_BIND_DN=
LDAP_BIND_PW=
LDAP_QUERY_FILTER_USER=
LDAP_QUERY_FILTER_GROUP=
LDAP_QUERY_FILTER_ALIAS=
LDAP_QUERY_FILTER_DOMAIN=
DOVECOT_TLS=
DOVECOT_USER_FILTER=
DOVECOT_PASS_FILTER=
DOVECOT_MAILBOX_FORMAT=maildir
ENABLE_POSTGREY=1
POSTGREY_DELAY=306
POSTGREY_MAX_AGE=35
POSTGREY_TEXT=Delayed by graylisting
POSTGREY_AUTO_WHITELIST_CLIENTS=5
ENABLE_SASLAUTHD=0
SASLAUTHD_MECHANISMS=
SASLAUTHD_MECH_OPTIONS=
SASLAUTHD_LDAP_SERVER=
SASLAUTHD_LDAP_SSL=
SASLAUTHD_LDAP_BIND_DN=
SASLAUTHD_LDAP_PASSWORD=
SASLAUTHD_LDAP_SEARCH_BASE=
SASLAUTHD_LDAP_FILTER=
SASLAUTHD_LDAP_START_TLS=
SASLAUTHD_LDAP_TLS_CHECK_PEER=
SASL_PASSWD=
SRS_SENDER_CLASSES=envelope_sender
SRS_EXCLUDE_DOMAINS=
SRS_SECRET=
DEFAULT_RELAY_HOST=
RELAY_HOST=
RELAY_PORT=25
RELAY_USER=
RELAY_PASSWORD=
Report result:

I haven't manually changed any Ciphers or DH KEX Parameters, use the defaults the Image generated/ specified, however I use Let's Encrypt (if this matters).
Configuration:
Report result: